• Title/Summary/Keyword: B-SiC

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Thick Film Type duster in Mg2SiO4/Glass composite ceramics for Anion Generation (Mg2SiO4/Glass Composite계 세라믹스를 이용한 음이온 발생용 후막형 클러스터)

  • Yeo, Dong-Hun;Shin, Hyo-Soon;Hong, Youn-Woo
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.23 no.2
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    • pp.118-123
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    • 2010
  • The eco-friendly technologies have been extended as matter of international concern due to various diseases and syndromes according to an environmental pollution. In this study, we have manufactured a ceramic cluster with thick film type for anion generation equipment which is maximized anion but minimized ozone contents generated. To develop the formulation of ceramic cluster, we conducted the $Mg_2SiO_4$ powders doped with 10 vol% glass frits as Na-Zn-B-O system and sintered at $1050^{\circ}C$ for 2 hours in air for starting materials and investigated the matching properties between the Ag-Pd electrode and the starting materials. The sintered sample for the composition of cluster has 6.7 of dielectric constant and 32 kV/mm of withstand voltage. The yield of anions was measured according to an electrode pattering, discharge gap between electrode, and thickness of electrode protective layer in the cluster of thick film type. We have manufactured the ceramic clusters with optimized thick film structure that have an anion over a hundred particles and the ozone of 0.6 ppb generated.

Effect of Heat Treatment on Microstructures and Magnetic Properties of Rapidly Solidified Fe-6.5wt % Si sheet (급속응고된 Fe-6.5wt% Si 강판의 미세조직과 자기적 특성에 미치는 열처리의 영향)

  • Hwang, D.H.;Lee, K.H.;Lee, T.H.;Koo, J.M.
    • Journal of the Korean Society for Heat Treatment
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    • v.8 no.2
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    • pp.149-154
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    • 1995
  • The alloying of 6.5wt % Silicon in iron decreases the magnetization and the anisotropy and minimizes the iron loss noticeably. But it is very difficult to make thin sheets because of its poor ductility which is due to an ordering reaction (body centered cubic to CsCI type crystal structure). However the ordering reaction can be suppressed by rapid solidification method. The cooling rate of rapidly solidified Fe-6.5wt % Si alloy is about $10^3K/s$ and rapidly solidified structure are fine structure, cellular structure, dendrite and equiaxed grain from surface. The precipitates of $DO_3$ Phase emerges on $B_2$ matrix and the coercive force was 0.51 Oe (50cycle, 15KGauss) in Fe-6.5wt% Si alloy which was processed by heat treatment of $1150^{\circ}C$ for 1hr in high vacuum.

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Magnetic Properties of Fe-6.0 wt%Si Alloy Dust Cores Prepared with Phosphate-coated Powders (인산염 피막처리 분말을 사용한 Fe-6.0 wt%Si 합금 압분자심의 자기적 특성)

  • Jang, D.H.;Noh, T.H.;Kim, K.Y.;Choi, G.B.
    • Journal of the Korean Magnetics Society
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    • v.15 no.5
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    • pp.270-275
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    • 2005
  • Dust cores (compressed powder cores) of $Fe-6.0wt\%Si$ alloy with a size of $35\~180\;{\mu}m$ in diameter have been prepared by phosphate coatings and annealings at $600\~900^{\circ}C$ for 1 h in nitrogen atmosphere. Further the magnetic and mechanical properties of the powder cores were investigated. As a general trends, the compressive strength and core loss decreased with the increase in annealing temperature. When annealed at $800^{\circ}C$, the compressive strength was 15 kgf, the permeability and quality factor were 74 and 26, respectively. Moreover the core loss at 50 kHz and 0.1 T induction was $750\;mW/cm^3$, and the percent permeability under the static field of 50 Oe was estimated to be about 78. In addition, the cut-off frequency in the cure representing the frequency dependence of effective permeability was measured to be around 200 kHz. These properties of the $Fe-6.0wt\%Si$ alloy dust cores could be considered to be due to the good insulation effect of iron-phosphate coats, the decrease in magnetocrystalline anisotropy and saturation magnetostriction and the increase in electric resistivity.

Relations between Composition, Temperature and Electrical Conductivity of (60-xSiO2-40Na2O-xCaO(x=0∼15wt%) Glass System ((60-x)SiO2-40Na2O-xCaO(x=0∼15wt%)조성유리계의 조성, 온도 및 전기전도도간의 상관특성)

  • Jung, Y.J.;Lee, K.H.;Kim, T.H.;Kim, Y.S.;Chin, H.J.;Ryu, B.K.
    • Korean Journal of Materials Research
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    • v.17 no.8
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    • pp.414-419
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    • 2007
  • We report the electrical conductivity of the mixed alkali silicate glasses in the system (60-x)$SiO_2-40Na_2O-xCaO(x=0\sim15wt%)$ in the temperature range from $150^{\circ}C$ to $620^{\circ}C$. In the range from $150^{\circ}C$ to glass transition temperature$(T_g)$, the electrical conductivities of glass samples had a tendency to be proportion with temperature. The glasses of containing over 7.5wt% CaO showed lower conductivities than the glasses of containing 0 and 5wt% CaO because two kinds of alkali ions$(Na^+,\;Ca^{2+})$ were obstructed each other. On the other hand, in the range from $T_g$ to $620^{\circ}C$, the electrical conductivity of glasses($7.5{\leq}x{\leq}12.5$) was unstable and decreased in some region. From XRD results, the $Na_4Ca(SiO_3)_3$ phase were observed in these glasses. This means the alkali ions didn't behave as carrier, it seems that this caused the conductivities decrease. In case of glass of containing 15wt% CaO, any crystal phase were not observed. This means the alkali ions behaved as carrier, it consequently seems the conductivity increased.

AFM Study and Magnetic Properties of Nanocrystalline Fe73.5-xCrxSi13.5B9Nb3Au1 (x=1~5) Alloys

  • Le, Anh-Than;Chau Nguyen;Cuong Nguyen Duy;The Ngo Duc;Kim, Chong-Oh;Rhee, Jang-Roh;Lee, Hee-Bok
    • Journal of Magnetics
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    • v.11 no.1
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    • pp.43-50
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    • 2006
  • In this paper, the influences of microstructural and surface morphological developments on the soft magnetic properties and giant magneto-impedance (GMI) effect of the $Fe_{73.5-x}Cr_{x}Si_{13.5}B_{9}Nb_{3}Au_1$ (x = 1, 2, 3, 4, 5) alloys have been presented. It was found that the Cr addition slightly decreased the mean grain size of $\alpha-Fe(Si)$ grains. AFM results indicate a large variation of surface morphology of density and size of protrusions along the ribbon plane due to microstructural changes caused by thermal annealing with increasing Cr content. Ultrasoft magnetic properties of the nanocrystallized samples were noticeably enhanced by properly heat treatments at $T_a=540^{\circ}C$ such as an increase of the magnetic permeability and the decrease of coercivity, which is likely due to the formation of nanoscale $\alpha-Fe(Si)$ phase which reduced the magnetoelastic anisotropy of samples. Accordingly, the GMI effect was observed in the annealed samples. The correlation between the microstructure, surface morphology, and soft magnetic properties were explained by nucleation and growth model.

Poly Si Buffer-layer 도입에 의한 실리콘 양자점층 두께 증가에 따른 실리콘 양자점 태양전지 효율 향상

  • Baek, Hyeon-Jeong;Park, Jae-Hui;Kim, Tae-Un;Kim, Gyeong-Jung
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.08a
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    • pp.354-354
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    • 2012
  • 실리콘 양자점 태양전지는 실리콘이 nm 크기의 양자점으로 될 경우 밴드갭이 증가하여 태양광 중의 가시광선을 광전변환에 활용함으로써 효율을 향상시키는 차세대 태양전지이다. 그러나 실리콘 양자점이 SiO2 매질 내에 분포하므로 양자점층의 두께가 증가할 경우 박막의 직렬저항이 증가하여 일정 두께 이상이 되면 효율이 감소하는 결과를 가져온다. 본 연구에서는 두께증가에 따른 효율저하 문제를 해결하기 위해 다결정 실리콘으로 이루어진 완충층을 도입 하였다. 이를 위해 본 연구에서는 두 가지 형태의 실리콘 양자점 태양전지를 제작하여 광전변환 특성을 비교하였다. 첫 번재 구조는 B이 도핑된 단일 실리콘 양자점층 태양전지이다. 양자점층은 2 nm SiOx 층과 2 nm SiO2 층을 적층한 후 $1,100^{\circ}C$에서 20분간 질소 분위기에서 급속 열처리하여 제작하였다. 실리콘 양자점 층의 두께를 40 nm에서 200 nm까지 변화시키면서 효율을 측정한 결과 100 nm 정도에서 효율이 감소하기 시작하였다. 이러한 효율감소는 양자점층의 저항 증가에 따른 전류감소에 의함이 확인되었다. 이와는 대조적으로 실리콘 양자점 층의 저항을 줄이기 위해 실리콘 양자점층 내에 50 nm 간격으로 10 nm 두께의 B이 도핑된 다결정 실리콘층을 배치하는 실리콘 양자점 태양전지를 개발하였다. 이러한 실리콘 양자점 층의 두께를 증가시킬 경우 효율이 지속적으로 증가함을 관찰하였다. 이러한 두 가지 형태의 양자점층을 이차이온질량분석법으로 분석한 결과 단일 실리콘 양자점층의 경우 두께가 약 70 nm 정도부터 이온빔 스퍼터링에 의한 저항증가에 따른 대전현상 (charging)이 관찰되었으나 다결정 실리콘 층이 배치된 실리콘 양자점층에서는 전혀 대전현상이 발생하지 않았다. 이는 다결정 실리콘 층이 캐리어를 이동시키는 매개체 역할을 하는 것으로 해석될 수 있다.

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Fabrication and Characterization of High-Performance Thin-Film Encapsulation for Organic Electronics (유기반도체용 고성능 박막 봉지재의 제조 및 평가)

  • Kim, Nam-Su;Graham, Samuel
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.36 no.10
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    • pp.1049-1054
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    • 2012
  • Continued advancements in organic materials have led to the development of organic devices that are thin, flexible, and lightweight and that can potentially be used as low-cost energy-conversion devices. While these devices have many advantages, the environmentally induced degradation of the active materials and the low-work-function electrodes remain a valid concern. Hence, many vacuum deposition processes have been applied to develop low-permeation barrier coatings. In this work, we present the results pertaining to the developed thin-film encapsulation. Multilayer encapsulation involves the use of $SiO_x$ or $SiN_x$ with parylene. The effective water vapor transmission rates were investigated using a Ca-corrosion test. The integration of the developed barrier layers was demonstrated by encapsulating pentacene/$C_{60}$ solar cells, and the results are presented.

A STUDY OF RESIDUAL IMAGE IN CHARGED-COUPLED DEVICE (CCD 잔존영상 분석)

  • Jin, Ho;Lee, C.U.;Kim, S.L.;Kang, Y.B.;Goo, J.L.;Han, W.
    • Journal of Astronomy and Space Sciences
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    • v.22 no.4
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    • pp.483-490
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    • 2005
  • For an image sensor CCD, electrons can be trapped at the front-side $Si-SiO_2$ surface interface in a case of exceeding the full well by bright source. Residual images can be made by the electrons remaining in the interface. These residual images are seen in the font-side-illuminated CCDs especially. It is not easy to find a quantitative analysis for this phenomenon in the domestic reports, although it is able to contaminate observation data. In this study, we find residual images iB dark frames which were obtained from the front-side-illuminated CCD at Mt. Lemmon Optical Astronomy Observatory (LOAO), and analyze the effect to contaminated observation data by residual charges.

Effect of Ag on microstructural behaviour of Nanocrystalline $Fe_{87-x}Zr_7B_6Ag_x$($0{\leq}x_{Ag}{\leq}4$) Magnetic Thin Films Materials

  • Lee, W.J.;Min, B.K.;Song, J.S.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.04a
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    • pp.3-6
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    • 2002
  • Effect of Ag additive element on microstructure of $Fe_{87-x}Zr_7B_6Ag_x$, magnetic thin films on Si(001) substrates has been investigated using Transmission Electron Microscopy(TEM) and X-ray Diffraction(XRD). All samples with additive Ag element were made by DC-sputtering and subjected to annealing treatments of $300^{\circ}C{\siim}600^{\circ}C$ for 1 hr. TEM and XRD showed that perfectly amorphous state in Ag-free Fe-based films was observed in as-deposited condition. The as-deposited Fe-based films with the presence of Ag constituent have a mixture of Fe-based amorphous and nano-sized Ag crystalline phases. In this case, additive element, Ag was soluted into Fe-based matrix. With the increase in additive element, Ag, insoluble nano-crystalline Ag particles were dispersed in the Fe-based amorphous matrix. Crystallization of Fe-based amorphous phase in the matrix of $Fe_{82}Zr_7B_6Ag_5$ thin films occurred at an annealing temperature of $400^{\circ}C$. Upon annealing, the amorphous-Ag crystalline state of Fe-Zr-B-Ag films was transformed into the mixture of Ag crystalline phase + Fe-based amorphous phase + ${\alpha}$-Fe cluster followed by the crystallization process of ${\alpha}$-Fe nanocrystalline + Ag crystalline phases.

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Preparation of Machinable Ceramics Using Domestic Pyrophyllite (국내산 납석을 이용한 Machinable Ceramics의 제조)

  • 정창주;정회준;양삼열
    • Journal of the Korean Ceramic Society
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    • v.28 no.7
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    • pp.531-540
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    • 1991
  • In this study, high quality machinable ceramics was prepared from the K2O-MgO-Al2O3-SiO2-B2O3-F glass system using domestic pyrophyllite. The mixture of pyrophyllite and additives was melted at 1450$^{\circ}C$ for 1 hour and formed in a graphite mold. The base glass was heat-treated at 600$^{\circ}C$ to 1200$^{\circ}C$ with interval of 50$^{\circ}C$ for 3 hours identified by XRD. Crystalline phase were confirmed by XRD and their microstructure was observed by SEM. The glass ceramics which was prepared by heat treatment of base glass at 1150$^{\circ}C$ for short time has good physical, mechanical, thermal, chemical properties and machinability.

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