• Title/Summary/Keyword: Azo계 염료

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Characterization of Aerobic Decolorization of Remazol Black B by White Rot Fungi (Remazol Black B의 호기성 탈색을 위한 백색부후균의 분해 특성 분석)

  • 이재화;이은열
    • Journal of Life Science
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    • v.13 no.4
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    • pp.511-515
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    • 2003
  • White rot fungi, Phanerochaete sp. EJ-31L, was evaluated for its ability to decolorize Remazol Black B, an azo dye that is a widespread pollutant in the wastewater of textile industry. It was observed that extent of decolorization by Phanerochaete sp. EJ-31L was dependent on the concentrations of co-carbon and nitrogen source. Effects of agitation and aeration were studied, and agitated culture at aeration condition resulted in greater extent of decolorization than static culture. Remazol Black B was readily decolorized up to 95% within 64 hr by Phanerochaete sp. EJ-31L.

Comparison of Azo-dye Removal Based on the Enzymatic Differences in T. versicolor and P. chrysosporium (T. versicolor와 P. chrysosporium의 효소발현 특성에 따른 Azo계 염료(Orange II) 제거 특성 비교)

  • Kim, Hak-Yoon;Oh, Je-Ill
    • Journal of Korean Society of Environmental Engineers
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    • v.27 no.7
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    • pp.712-718
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    • 2005
  • Stepwise reductions of glucose and Orange II concentration were observed from the experiment of both white-rot fungi such as T. versicolor and P. chrysosporium. As a result, typical removal patterns in those dual substrate system were categorized through several distinctive steps: initial lag period, primary and secondary carbon consumption periods. Also, based on the total removal amounts of Orange II, COD and Color during the experimental period, similar removal extent were observed from both species experiments, within the maximal error range of 5%. However, it was refereed that the internal steps of Orange II removal on enzymatic level should be different between two species: Enzyme Lac showed good affinity for Orange II removal in T. versicolor, however in P. chrysosporium enzyme LiP represented more close affinity to the similar experimental condition. Thus, even though the superficial removal amount of calcitrant Orange II at different fungal species was merely similar, removal pathway of enzymatic levels and intermediates produced during the fungal decomposition would be different.

Batch Decolorization of Reactive Dye Waste Water by a Newly Isolated Comamonas sp. AEBL-85. (반응성 염료폐수 처리를 위한 Comamonas sp. AEBL-85 분리 및 회분식 탈색)

  • 이은열
    • Journal of Life Science
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    • v.14 no.4
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    • pp.577-581
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    • 2004
  • Comamonas sp. AEBL-85 was isolated from microbial granules in an activated sludge process of long-term operated for the treatment of reactive azo dye, and characterized its capability to decolorize Reactive Black 5. The effects of adding carbon source and nitrogen source on the extent of decol-orization were analyzed to develop an optimal medium. The optimum initial pH and temperature wire 6.0 and 35$^{\circ}C$, respectively. Reactive Black 5 of 50 mg/l was readily decolorized up to 95% within 40 hr by Comamonas sp. AEBL-85.

Synthetic aromatic dye degradation by white rot fungus, Pleurotus eryngii (큰느타리(Pleurotus eryngii)의 방향족 합성염료 분해 특성)

  • Im, Kyung-Hoan;Baek, Seung-A;Lee, Tae Soo
    • Journal of Mushroom
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    • v.20 no.2
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    • pp.86-91
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    • 2022
  • Pleurotus eryngii, a white rot fungus, produces two extracellular lignin-degrading enzymes, laccase and manganese peroxidase (MnP). Owing to these enzymes, P. eryngii efficiently degrades synthetic chemicals such as azo, phthalocyanine, and triphenyl methane dyes. In this study, we investigated the degradation processes of four aromatic dyes, congo red (CR), methylene blue (MB), crystal violet (CV), and malachite green (MG), by P. eryngii under solid and liquid culture conditions. CR and MG were the most quickly degraded under solid and liquid culture conditions, respectively. However, compared to CR, CV, and MG, MB was not degraded well under both culture conditions. The activities of ligninolytic enzymes (laccase and MnP) were also investigated. Laccase was identified to be the major enzyme for dye degradation. A positive relationship between decolorization and enzyme activity was observed for CR, MB, and CV degradation. In contrast, decolorization of MG ensued after high enzyme activity. These results indicate that the degradation process differs between MG and the other aromatic dyes. Therefore, P. eryngii could be a potential tool for the bioremediation of synthetic aromatic dye effluent.

Dyeability of Nylon Fabrics with Dyestuff for Supercritical Fluid Dyeing (1) : C.I. Disperse Red 167, C.I. Disperse Violet 93 (초임계 유체 염색용 염료에 따른 Nylon 섬유의 염색 특성 (1) : C.I. Disperse Red 167, C.I. Disperse Violet 93 Azo계 염료)

  • Choi, Hyunseuk;Park, Shin;Kim, Taeyoung
    • Textile Coloration and Finishing
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    • v.32 no.4
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    • pp.217-225
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    • 2020
  • In this study, the dyeing characteristics of nylon fabric which is dyed with supercritical fluid were investigated. There were two dyes used in the dyeing experiment: C.I. Disperse Red 167 and C.I. Disperse Violet 93. Dyeing temperature, pressure, and leveling time were fixed at 110℃, 250bar, 60minutes, and the experiment was conducted with dyeing concentration of 0.1, 0.3, 0.5, and 0.85% o.w.f. The analysis of the experimental results was found out through the measurement of washing fastness and color coordinate. In addition, the calibration curve of each dye was drawn up and the amount of remaining dye was checked by measuring the absorbance of the residual dye. As a result of color difference measurement, as the concentration increased, the L⁎ value decreased and the K/S value increased. However, the increase in K/S value compared to the amount of input decreased as the concentration increased. The comparative experiment on the amount of residual dye(C.I. Disperse Red 167) in the pot showed that 99.14% of the amount was dyed at the concentration of 0.1% o.w.f, while it rapidly decreased to 77% at 0.85% o.w.f. C.I. Disperse Violet 93 dye also decreased from 0.5% o.w.f to 93.91%. In the washing fastness experiment of both dyes, the level of washing fastness began to decrease from samples dyed at 0.5% o.w.f. It may be because the simply absorbed dye was produced instead of completely being fixed in the amorphous region of the nylon fiber.

Optimization of Ultrafiltration Process using $MIEX^{(R)}$+Coagulation Process ($MIEX^{(R)}$+응집공정을 이용한 한외여과 공정의 최적화 : 다양한 전처리 공정의 적용에 따른 막 오염 현상 규명)

  • Son, Hee-Jong;Hwang, Young-Do;Roh, Jae-Soon;Jung, Chul-Woo;Kang, Lim-Seok
    • Journal of Korean Society of Environmental Engineers
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    • v.27 no.7
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    • pp.753-761
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    • 2005
  • In this study, pretreatment of organic matters with $MIEX^{(R)}$ was evaluated using bench-scale experimental procedures on four organic matters to determine its effect on subsequent UF membrane filtration. For comparison, coagulation process was also used as a pretreatment of UF membrane filtration. Moreover, the membrane fouling potential was identified using different fractions and molecular weights of organic matters. From the removal property of MW organic matters by coagulation process for the sample water NOM and AOM, the removal efficiency of high MW organic matters were much higher than those of low MW organic matters. It was shown that the removal efficiency of high MW organic matter more than 10 kDa was lower than that of low MW organic matter for $MIEX^{(R)}$ process. For the change of permeate flux by the pretreatment process, $MIEX^{(R)}$+UF process showed high removal efficiency of organic matter as compared with coagulation-UF processes, but high reduction rate of permeate flux was presented through the reduction of removal efficiency of high MW organic matter. From sequential filtration test results in order to examine the effect of MW of organic matter on membrane fouling, it was found that the membrane foulant was occurred by high MW organic matter, and the DOC of organic matter less than 0.5 mg/L was working as the membrane foulant. In the case of sample water composed of low MW organic matter less than 10 kDa, since the low MW organic matter less than 10 kDa has high removal efficiency by $MIEX^{(R)}$, low reduction rate of permeate flux is obtained as compared with coagulation-UF processes. In summary, it is required to conduct the research on physical/chemical characteristic of original water before pretreatment process of membrane process is selected, and a pertinent pre-treatment process should be employed based on the physical/chemical characteristic of original water.