• Journal of Environmental Science International
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• v.24 no.12
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• pp.1569-1582
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• 2015

The analytical method for 16 organophosphorus pesticides was developed in this study. The 16 organophosphorus pesticides were analyzed by liquid chromatography-tandem mass spectrometry (LC/MS/MS) using on-line solid phase extraction (on-line SPE) with PLRP- S cartridge. Analysis of all analytes in the MS/MS was processed in the electrospray ioni-zation (ESI) positive mode. They are Azinphos ethyl, Chlorfenvinphos, Ethion, Famphur, Phosmet, Phosphamidon, Terbufos, Aspon, Chlorpyrifos-methyl, Crotoxyphos, Dichlofenthi-on, Dicrotophos, Fonofos, Thionazin, Dimethoate and Iprobenfos. Limits of detection (LODs) and Limits of quantification(LOQs) were obtained as 0.8~2.0 ng/L and 2.6~6.4 ng/L, respectively. All compounds were not detected at the 8 sampling points of the raw water and clean water.

• Journal of the Korean Society of Marine Environment & Safety
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• v.15 no.1
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• pp.1-9
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• 2009

Distribution characteristics of organophosphorous pesticides (OPs) were studied over the period from May to September, 2006 in Asan Bay, Korea. During the study period, 28 kinds of organophosphorous pesticides dissolved in surface water and adsorbed on suspended particle were measured. In the surface water, the dominant OPs were IBP and DDVP, and the concentration were in the ranges from not detected to 2014.4 ng/L for IBP and 3.2 to 696.3 ng/L for DDVP. The highest concentrations of OPs in the surface waters in Asan Bay appeared in July and August showing that seasonal distributions of OPs depend on application time and precipitation. The concentrations of OPs generally decreased with the increase of distance from the mouth of Asan Bay, implying progressive dilution of pesticides in the estuarine system. OPs residue in Asan Bay was relatively higher than in other area of Korea. The concentrations of the observed OPs concentrations did not exceed the seawater quality standard of Korea. DDVP, IBP, Diazinon, Phorate, Azinphos ethyl and Chlorfenvinfos had higher adsorption capacity onto suspended particle than the other OPs. In the study area, adsorption coefficients $(K_d)$ of OPs were closely related to the Log $K_ow$ of each compound.

• Ocean and Polar Research
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• v.32 no.3
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• pp.203-212
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• 2010

Distribution of organophosphorous pesticides (OPs) was studied from February to September 2008 in the seawater of Asan Bay, Korea. Among the 29 types of OPs detected during the study period, IBP(S-benzyl O,O-diisopropyl phosphorothioate), ranging from <1 ng/l to 377 ng/l, was the most abundant. Other commonly observed OPs concentrations in the study area included diazinon (Diethyl 2-isopropyl-4-methyl-6-pyrimidinyl phosphorothionate; <1~307 ng/l), azinphos ethyl (3,4-Dihydro-4-oxo-3-benzotriazinylmethyl O,O-diethyl phosphorodithioate; <1~1997 ng/l), malathion (1,2-Di(ethoxycarbonyl)ethyl O,Odimethyl phosphordithioates; <1~3013 ng/l), demeton-O (Diethyl 2-(ethylthio)ethyl phosphorothionate; <1~2403 ng/l), and DDVP (2,2-dichlorovinyl dimethyl phosphate; <1~283 ng/l). Seasonal distribution of OPs in seawater is dependent on the OP application period. In August, OPs concentrations were generally decreased with the increased salinity of seawater, implying progressive dilution of pesticides in the estuarine system. OPs were deposited into Asan Bay from Asan and Sabkyo Lakes as well as surrounding tributaries. Ten OPs, including diazinon, were detected in the suspended particles of Asan Bay.