• Title/Summary/Keyword: Average chloride diffusion coefficient

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Evaluation of Diffusion Property of Latex Modified Concrete (LMC(Latex Modified Concrete)의 염소이온 확산 특성)

  • Park, Sung-Ki;Won, Jong-Pil;Park, Chan-Gi
    • Journal of The Korean Society of Agricultural Engineers
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    • v.50 no.4
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    • pp.27-37
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    • 2008
  • It is most serious problem which is various occurs from the agricultural concrete structure and off shore concrete structure the problem which it comes to think is deterioration of the concrete which is caused with the corrosion of the reinforcing steel which is caused by with permeation of the water and the sea water. Specially the off shore concrete structure has been deteriorated by the steel reinforcement corrosion. The latex modified concrete(LMC) was adds latex in the plain concrete as the latex has increase the durability of concrete. This study were accomplished to the estimate the diffusion coefficient of LMC, and the time dependent constants of diffusion. The average chloride diffusion coefficient was estimated. Also, the average chloride diffusion coefficient was compared with diffusion coefficient test results of 28 curing days. The test results indicated that the average chloride diffusion coefficient could closely estimate the test results of the diffusion coefficient test results of 28 curing days.

Prediction of Corrosion Threshold Reached at Steel Reinforcement Embedded in Latex Modified Concrete with Mix Proportion Factor (배합변수에 따른 라텍스 개질 콘크리트 내에 정착된 보강철근의 부식개시시기 예측)

  • Park, Seung-Ki;Won, Jong-Pil;Park, Chan-Gi;Kim, Jong-Ok
    • Journal of The Korean Society of Agricultural Engineers
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    • v.50 no.6
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    • pp.49-60
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    • 2008
  • This study were predicted the corrosion threshold reached at steel reinforcement in latex modified concrete(LMC) which were applied the agricultural hydraulic concrete structures. Accelerated testing was accomplished to the evaluate the diffusion coefficient of LMC mix, and the time dependent constants of diffusion. Also, the average chloride diffusion coefficient was estimated. From the average chloride ion diffusion coefficient, the time which critical chloride contents at depth of reinforcement steel was estimated. Test results indicated that the corrosion threshold reached at reinforcement in LMC were effected on the mix proportion factor including cement contents, latex content, and water-cement ratio. Especially, the average chloride diffusion coefficient, the corrosion threshold reached at reinforcement in LMC were affected by the all mix proportion factor.

Chloride Diffusion Coefficient Model Considering the Initiation Time of Exposure to Chloride Environment (염소이온 노출개시시기를 고려한 기존 확산계수 모델 수정제안)

  • Kim, Ki-Hyun;Cha, Soo-Won
    • Journal of the Korea Concrete Institute
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    • v.21 no.3
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    • pp.377-386
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    • 2009
  • A reference diffusion coefficient model from ACI life-365 is drawn from test results by NT build 443. This test method gives a time-averaged diffusion coefficient during immersion period, thus the ACI model uses the time-averaged diffusion coefficient as a reference value. ACI model needs to be revised, considering the difference between the time-average value and reference value at specified time. In this study, firstly the analytic solutions of diffusion equation are derived considering the initiation time and period of exposure to chloride, and secondly the time-averaged diffusion coefficient from NT build 443 is converted into the diffusion coefficient at reference time. From this study, the reference diffusion coefficient of ACI model should be modified to be about 10% larger values than those of present ACI model. For convenient design of service life, previous relationship between the chloride diffusion coefficient from NT build 443 and that from NT build 492 is also modified. To compare the chloride diffusion coefficients of ACI and JCI models, the reference chloride diffusion coefficient with respect to the JCI model is drawn in the similar form of ACI model's, and service life prediction by ACI life-365 method is confirmed to give a conservative result.

Effect of Pore-Characteristics of Concrete on the Diffusion Coefficient of Chloride Using the Accelerating Test Methods (콘크리트 중의 공극 특성에 따른 전위차 염소이온 확산계수)

  • 문한영;김홍삼;최두선;오세민
    • Proceedings of the Korea Concrete Institute Conference
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    • 2003.05a
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    • pp.711-714
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    • 2003
  • Factors causing deterioration of concrete structures under marine environment are various, especially penetration and diffusion of chloride ion, carbon dioxide, and water through pore effects on the durability of concrete as well as mechanical properties of concrete. Pore of porous materials like concrete can be classified as micro-, meso-, and macro-pore. And pore of cement matrix is classified as pore which occupied by water, air void, and ITZ between cement paste and aggregates. In this study, to verify the relationship between pore of cement matrix and the property of chloride ion diffusivity, the regression analysis is producted. From the result of regression analysis, the average pore diameter more than total pore volume effects on the diffusivity of chloride ion.

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Effect of Latex on Corrosion Resistance of Steel Rebar in Concrete (콘크리트 내에서 보강철근의 부식저항성에 미치는 라텍스의 효과)

  • Park, Sung-Ki;Won, Jong-Pil;Sung, Sang-Kyung;Park, Chan-Gi
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.11a
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    • pp.409-412
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    • 2008
  • This study were evaluated the corrosion threshold reached at steel reinforcement in latex modified concrete(LMC). Accelerated testing was accomplished to the evalate the diffusion coefficient of LMC mix, and the time dependent constants of diffusion. Also, average chloride diffusion coefficient was estimated. From the average chloride ion diffusion coefficient, the time which critical chloride contents at depth of reinforcement steel was estimated. Test results indicated that the corrosion threshold reached at reinforcement in LMC are effected on the mix proportion factor including latex content, and water-cement ratio.

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Research on chloride ion diffusivity of concrete subjected to CO2 environment

  • Zhang, Shiping;Zhao, Binghua
    • Computers and Concrete
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    • v.10 no.3
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    • pp.219-229
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    • 2012
  • Carbonation is a widespread degradation of concrete and may be coupled with more severe degradations. An experimental investigation was carried out to study the effect of carbonation on chloride ion diffusion of concrete. The characteristic of concrete after carbonation was measured, such as carbonation depth, strength and pore structure. Results indicated that carbonation depth has a good linear relation with square root of carbonate time, and carbonation can improve compressive strength, but lower flexural strength. Results about pore structure of concrete before and after carbonation have shown that carbonation could cause a redistribution of the pore sizes and increase the proportion of small pores. It also can decrease porosities, most probable pore size and average pore diameters. Chloride ion diffusion of concrete after carbonation was studied through natural diffusion method and steady state migration testing method respectively. It is supposed that the chloride ion concentration of carbonation region is higher than that of the sound region because of the separation of fixed salts, and chloride ion diffusion coefficient was increased due to carbonation action evidently.

Chloride Penetration Resistance of Concrete Mixed with High Volume Blast Furnace Slag (고르슬래그미분말을 다량 혼입한 콘크리트의 염분침투저항성)

  • Park, Ki-Cheol;Kim, Dong-Hun;Park, Shin;Lim, Nam-Gi
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2014.11a
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    • pp.40-41
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    • 2014
  • As a result of strength test on BFS concrete, those mixed with 30% and 50% of BFS8000, respectively, showed higher or equivalent strength compare to OPC. As a result of test of chloride penetration on BFS, diffusion coefficients of concrete mixed with 30% FA4000 and FA5000, respectively, showed to restrain average 6.5% of diffusion coefficient compared to OPC. And in case of BFS concrete, those mixed with BFS6000 and BFS8000, restrained diffusion of chloride ions 253% and 336%, respectively, compared to OPC. Therefore, Mixing 50% of BFS was most efficient in order to maximize restraint of chloride penetration according to metathesis of large amount. In this study, when mixing BFS to concrete for long-run durability and restraint against chloride penetration, for BFS, as fineness was higher and mixing it to concrete with less or equivalent 50% of replacement rate, there were results of higher strength compared to OPC and more efficient restraint of chloride ions.

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Comparison of Correlation between Chloride Diffusion and Pores Characteristics in Concrete Cured under Extreme Condition (가혹 조건에서 양생된 콘크리트의 염화물 확산과 공극 특성의 상관관계 비교 )

  • So Yeong Choi;Seong Joon Yang;Il Sun Kim;Eun Ik Yang
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.27 no.4
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    • pp.54-61
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    • 2023
  • In this paper, the compressive strength, pore characteristics, and chloride diffusion coefficient were measured at 28 days of age in order to examine the influence of curing conditions for the chloride diffusion and pores in concrete cured under extreme condition. According to the test results, the compressive strength was improved as the relative humidity increased. Additionally, higher compressive strength was observed when the specimens were cured at 35℃. However, the compressive strength of specimens cured at 45℃ was decreased. Meanwhile, the chloride diffusion coefficient decreased with an increase in curing temperature and relative humidity, indicating a difference compared to the trend observed for compressive strength. On the other hand, the excellent correlation showed between compressive strength and chloride diffusion coefficient, porosity and chloride diffusion coefficient when the concrete cured under water. However, when the concrete cured under extreme condition, this correlation was significantly reduced compared to the water curing case. In contrast, it has been determined that there is no significant correlation between the average pore size and chloride diffusion coefficient, regardless of the curing conditions.

Chloride Ion Penetration Properties of Normal Strength High-Fluidity Concrete Using Lime Stone Powder (석회석 미분말을 활용한 보통강도 고유동 콘크리트의 염소이온 침투특성)

  • Choi, Yun-Wang;Moon, Jae-Heum;Eom, Joo-Han
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.14 no.4
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    • pp.160-168
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    • 2010
  • Recently, there are a lot of researches related to the high-fluidity concrete (HFC) with field applications. However, most applications and studies are with concretes with high strength level so there are little studies about durability evaluations such as chloride ion penetration properties with normal strength concrete. Therefore, to evaluate the durability of HFC with normal strength level, this study performed the chloride ion penetration test and observed the micro pore distribution with normal strength HFC which contains limestone powder. Experimental results showed that most micro-pores have diameters between 0.005 to 0.05 ${\mu}m$ with HFCs using limestone powder and the average diameter becomes larger with the increase of limestone powder content. Also, it was shown that, with the increase of the limestone powder content, penetration depth and diffusion coefficient of chloride ion increased and diffusion coefficient had good relationships with compressive strength and average pore diameter with the coefficient of determination over 0.90.

Study on Optimum Mixture Design for Service Life of RC Structure subjected to Chloride Attack - Genetic Algorithm Application (염해에 노출된 콘크리트의 내구수명 확보를 위한 최적 배합 도출에 대한 연구 - 유전자 알고리즘의 적용)

  • Kwon, Seung-Jun;Lee, Sung Chil
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.30 no.5A
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    • pp.433-442
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    • 2010
  • A control of chloride diffusion coefficient is very essential for service life of reinforced concrete (RC) structures exposed to chloride attack so that much studies have been focused on this work. The purpose of this study is to derive the intended diffusion coefficient which satisfies intended service life and propose a technique for optimum concrete mixture through genetic algorithm(GA). For this study, 30 data with mixture proportions and related diffusion coefficients are analyzed. Utilizing 27 data, fitness function for diffusion coefficient is obtained with variables of water to binder ratio(W/B), weight of cement, mineral admixture(slag, flay ash, and silica fume), sand, and coarse aggregate. 3 data are used for verification of the results from GA. Average error from fitness function is observed to 18.7% for 27 data for diffusion coefficient with 16.0% of coefficient of variance. For the verification using 3 data, a range of error for mixture proportions through GA is evaluated to 0.3~9.3% in 3 given diffusion coefficients. Assuming the durability design parameters like intended service life, cover depth, surface chloride content, and replacement ratio of mineral admixture, target diffusion coefficient, where exterior conditions like relative humidity(R.H.) and temperature, is derived and optimum design mixtures for concrete are proposed. In this paper, applicability of GA is attempted for durability mixture design and the proposed technique would be improved with enhancement of comprehensive data set including wider range of diffusion coefficients.