• Resources Recycling
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• v.14 no.6 s.68
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• pp.37-43
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• 2005

[ $LiCoO_{2}$ ] nanoparticles were synthesized from leach liquor of lithium ion battery waste using flame spray pyrolysis. Electrode Materials containing lithium and cobalt could be concentrated with thermal and mechanical treatment. After dissolution of used cathode materials of the lithium battery with nitric acid, the molar ratio of Li/Co in the leach liquor was adjusted at 1.0 by adding a fresh $LiNO_{3}$ solution. The nanoparticles synthesized by the flame spray pyrolysis showed clear crystallinity and were nearly spherical, and their average primary particle diameters ranged from 11 to 35 nm. The average particle diameter increased with an increase in the molar concentration of the precursor. Raising the maximum flame temperature by controlling the gas flow rates also led to an increase in the average diameter of the particles. The $LiCoO_{2}$ powder was proved to have good characteristics as cathode active materials in charge/discharge capacity and cyclic performance.

• Economic and Environmental Geology
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• v.51 no.1
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• pp.1-13
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• 2018

The radon concentration in soil varies with environmental factors such as atmospheric temperature and pressure, rainfall and soil temperature. The effects of these factors, therefore, should be differentiate in order to analyzed the anomalous radon variation caused by earthquake events. For these reasons, a comparative analysis between the radon variations with environmental factors and the anomalous variations caused by Gyeong-ju earthquake occurred in September 12, 2016 has been conducted. Radon concentration in soil and environmental factors were continuously measured at a monitoring ste located in 58Km away from earthquake epicenter from January 01, 2014 to May 31, 2017. The co-relationships between radon concentration and environmental factors were analyzed. The seasonal average radon concentration(n) and the standard variation(${\rho}$) was calculated, and the regions of ${\pm}1{\rho}$ and ${\pm}2{\rho}$ deviations from seasonal average concentration were investigated to find the anomalous radon variation related to Gyeong-ju earthquake. Earthquake effectiveness and q-factor were also calculated. The radon concentration indicated the seasonal variation pattern, showing high in summer and low in winter. It increases with increasing air temperature and soil temperature, and has the positive co-relationships of $R^2=0.9136$ and $R^2=0.8496$, respectively. The radon concentration decreases with increasing atmospheric pressure, and has the negative co-relationships of $R^2=0.7825$. Four regions of ${\pm}2{\rho}$ deviation from average seasonal concentration (A1: 7/3~7/5, A2: 7/18, A3: 8/4~8/5, A4: 10/17~10/20) were detected before and after Gyeong-ju earthquake. A1, A2, A3 were determined as the anomalous radon variation caused by the earthquake from co-relationship analyses with environmental factors, earthquake effectiveness and q-factor. During the period of anomalous radon variation, correlation coefficients between radon concentration and environmental factors were significantly lowered compared to other periods such as air temperature ($R^2=0.2314$), soil temperature ($R^2=0.1138$) and atmospheric pressure ($R^2=0.0475$). Annual average radon concentration was also highest at 2016, the year of Gyeong-ju earthquake.

• Journal of Adhesion and Interface
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• v.13 no.3
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• pp.101-108
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• 2012

Narrowly dispersed poly(BMA-co-MMA) and PBMA latices (PSD : 1.002~1.008) were synthesized successfully by surfactant-free emulsion polymerization with 2,2' azobis(2-methyl-propionamidine) dihydrochloride (AIBA) and $K_2S_2O_8$ (KPS). The number average particle diameter and the number average molecule weight were found to be 160~494 nm and (1.25~7.55) ${\times}10^4$, respectively. The influences of BMA/MMA ratio, monomer and initiator concentrations, addition of DVB/EGDMA crosslink agent, and polymerization temperature on the polymerization rates and on the particle size and molecular weight were studied. The rate of polymerization increased with increasing MMA concentration in BMA/MMA weight ratio. The particle diameter as well as the polymer molecular weight could be controlled easily by controlling the BMA/MMA weight ratio, monomer concentration, AIBA and KPS concentration, and polymerization temperature.

• Journal of Environmental Health Sciences
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• v.41 no.6
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• pp.389-396
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• 2015

Objectives: A hospital is a complex building that serves many different purposes. It has a major impact on patient's well-being as well as on the work efficiency of the hospital staff. Thermal comfort is one of the major factors in indoor comfort. The purpose of this study was to determine thermal comfort in various locations in a hospital. Methods: Various indoor environmental conditions in a general hospital were measured in February 2014. The predicted mean vote (PMV) and carbon dioxide ($CO_2$) concentration were measured simultaneously in the lobby, office, restaurant, and ward. Results: The ward was the most thermally comfortable location (PMV=0.44) and the lobby was the most uncomfortable (PMV = -1.39). However, the $CO_2$ concentration was the highest in the ward (896 ppm) and the lowest in the lobby (572 ppm). The average PMV value was the most comfortable in the ward and the lowest in the lobby. In contrast, for concentration of carbon dioxide, the highest average was in the ward and the lowest in the lobby. Due to air conditioner operation, during operating hours the PMV showed values close to 0 compared to the non-operating time. Correlation between PMV and $CO_2$ differed by location. Conclusion: The PMV and concentration of carbon dioxide of the hospital lobby, office, restaurant and ward varied. The relationship between PMV and carbon dioxide differed by location. Consideration of how to apply PMV and carbon dioxide is needed when evaluating indoor comfort.

• Journal of the Korean Ceramic Society
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• v.51 no.2
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• pp.107-114
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• 2014

In the present work, we report a novel microstructure of scalenohedral calcite synthesized without any additives by a simple and ecofriendly carbonation process carried out in a liquid-gas system as well as the effects of experimental conditions on the crystal growth of the scalenohedral calcite phase. Various process parameters, pH, temperature, $Ca(OH)_2$ concentration, $CO_2$ flow rates, and the total volume concentration, were investigated to enhance the sensitivity of the process. The highest average length of the scalenohedral calcite was obtained at pH 6.0, temperature of $45^{\circ}C$, $Ca(OH)_2$ concentration of 0.2M, $CO_2$ flow rate of 80mL/min, and total volume of 1L. The synthesized calcite was characterized by XRD, SEM, and FTIR to identify the phases and surface morphology.

• Journal of Hydrogen and New Energy
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• v.25 no.2
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• pp.209-217
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• 2014

To enhance the performance of SEWGS system by holding the WGS catalyst in a SEWGS reactor, a spring type bed insert was developed. In this study, effects of operating variables such as steam/CO ratio, gas velocity, syngas concentration on CO conversion were investigated in a fluidized bed reactor using the spring type bed insert to hold the WGS catalyst as tablet shape. CO conversion increased initially as the steam/CO ratio increased. But further increment of the steam/CO ratio caused decreasing of CO conversion because of increment of gas velocity and decrement of syngas concentration. Moreover, CO conversion decreased as the gas velocity increased and the syngas concentration decreased at the same steam/CO ratio. Continuous operation up to 48 hours (2 days) was carried out to check reactivity decay of WGS catalyst supported by spring type bed insert. The average CO conversion was 99.04% and we could conclude that the WGS reactivity at those conditions was maintained up to 48 hours.

• Journal of Bio-Environment Control
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• v.32 no.4
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• pp.416-422
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• 2023

This study was aimed to determine the changes in CO₂ concentration according to the temperatures of daytime and nighttime in the CO₂ supplemental greenhouse, and to compare calculated supplementary CO₂ concentration during winter and spring cultivation seasons. CO₂ concentrations in experimental greenhouses were analyzed by selecting representative days with different average temperatures due to differences in integrated solar radiation at the growth stage of leaf area index (LAI) 2.0 during the winter season of 2022 and 2023 years. The CO₂ concentration was 459, 299, 275, and 239 µmol·mol^-1, respectively at 1, 2, 3, and 4 p.m. after the CO₂ supplementary time (10:00-13:00) under the higher temperature (HT, > 18℃ daytime temp. avg. 31.7, 26.8, 23.8, and 22.4℃, respectively), while it was 500, 368, 366, 364 µmol·mol^-1, respectively under the lower temperature (LT, < 18℃ daytime temp. avg. 22.0, 18.9, 15.0, and 13.7℃, respectively), indicating the CO₂ reduction was significantly higher in the HT than that of LT. During the nighttime, the concentration of CO₂ gradually increased from 6 p.m. (346 µmol·mol^-1) to 3 a.m. (454 µmol·mol^-1) in the HT with a rate of 11 µmol·mol^-1 per hour (240 tomatoes, leaf area 330m²), while the increase was very lesser under the LT. During the spring season, the CO₂ concentration measured just before the start of CO₂ fertilization (7:30 a.m.) in the CO₂ enrichment greenhouse was 3-4 times higher in the HT (>15℃ nighttime temperature avg.) than that of LT (< 15℃ nighttime temperature avg.), and the calculated amount of CO₂ fertilization on the day was also lower in HT. All the integrated results indicate that CO₂ concentrations during the nighttime varies depending on the temperature, and the increased CO₂ is a major source of CO₂ for photosynthesis after sunrise, and it is necessary to develop a model formula for CO₂ supplement considering the nighttime CO₂ concentration.

• Journal of Korean Society for Atmospheric Environment
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• v.19 no.2
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• pp.167-177
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• 2003

The number size distribution of urban aerosols ranging from 0.02 to 20 ${\mu}{\textrm}{m}$ in diameter was measured by using a scanning mobility particle sizer (SMPS) system and an aerodynamic particle sizer spectrometer (APS) at Seoul from November 30,2001 to January 14, 2002. The gaseous species such as CO, NO, NO$_2$, and $O_3$ were also continuously monitored. The daily average concentration of urban aerosols sorted into three groups (0.02~0.1 ${\mu}{\textrm}{m}$, 0.1~1 ${\mu}{\textrm}{m}$ and 1~10 ${\mu}{\textrm}{m}$) and the typical number, surface, and volume distributions of urban aerosols were discussed in this paper. The weekly variation of aerosol concentration was compared with those of gaseous concentrations. relative humidity, and visibility. The results showed that the particle number concentration seemed to increase in the morning and the number concentration of fine particles less than 1 fm in diameter seemed to increase when the concentrations of CO, NO, and NO$_2$ were high. The number concentration of fine particles was relatively high when the relative humidity was greater than 70％ during the increasing period of relative humidity. The visibility was weakly correlated with the concentration of aerosols ranging 0.1 to 1 ${\mu}{\textrm}{m}$, and the number size distribution for high visibility episode was apparently different from that for low visibility episode.

• Journal of Korean Society for Atmospheric Environment
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• v.2 no.3
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• pp.45-51
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• 1986

The simple and precise model for the estimation of rain acidity from the ambient air quality was developed using the theory of wet scrubber and the chemical equilibria of $SO_2, CO_2, and H_2O$ system. From the measured mixing height, and from the developed relationship between NTU (=number of transfer units) and the concentration of $SO_2$(aq) in rain drops, the HTU (= height equivalent to one transfer unit, i.e. mass transfer resistance) was estimated, and validated with the field-measured data. In Seoul, Korea where the effect of $SO_2$ on rainfall acidity is as high as 84% and the average mixing height is 1 km, the average HTU of $SO_2$ system was found to be 191.5m. The important parameters affecting HTU were identified as rainfall intensity and initial ambient concentration of $SO_2$, and their effects on the value of overall volumetric mass transfer coefficient were quantified.

• Korean Journal of Ecology and Environment
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• v.38 no.spc
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• pp.8-11
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• 2005

Carbon stable isotope ratios of producers varied in lake ecosystems. In tile present study, we tried to estimate the seasonal variations of carbon isotope ratios of phytoplankton and benthic diatoms in a strongly acidic lake ecosystem. Lake Katanuma is a volcanic, strongly acidic lake (average pH of 2.2), located in Miyagi, Japan. Only two algal species dominate in Lake Katanuma; Pinnularia acidojaponica as a benthic diatom, and Chlamydomonas acidophila as a green alga. Carbon isotope values of P. acidojaponica varied seasonally, while those of particulate organic matter, which were mainly composed of C. acidophila remained fairly stable. The differences suggested that $CO_2$ gas was more frequently limited for P. acidojaponica than C. acidophila, since high density patches of benthic diatoms were sometimes observed on the lake sediment. Generally, carbon concentration mechanisms (CCMs)of microalgae can fix bicarbonate in lakes, and affect the carbon isotope values of microalgae. While, in Lake Katanuma, CCMs of the microalgae may scarcely function because of high $CO_2$ gas concentration and low pH. This is the reason for low seasonal amplitude of carbon isotope values of phytoplankton relative to those in other lakes.