• Title/Summary/Keyword: Atomic vapor

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Determination of Inorganic Mercury in Urine and Airborne by Cold Vapor Atomic Absorption Spectrophotometry (냉각증기 원자흡수분광법에 의한 뇨 및 공기중의 무기수은 정량에 관한 연구)

  • Oh, Doe Suk;Oh, Se Min
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.1 no.2
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    • pp.136-143
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    • 1991
  • Inorganic mercury in urine and airborne was determined by cold vapor atomic absorption spectrophotometry. Detailed sampling methods and analylical results are as follows : 1. 100~200ml of urine for each person was taken in 250 ml borosilicate bottle and $K_2S_2O_8$ (0.1g/100ml urine) was added to prevent bacterial contamination. About 1001 air of workingplace was absorbed in l0ml of absorbing solution. Urine samples and absorbing solution tubes were stored at $4^{\circ}C$. Dillution solution to prepare standard solution used deionized water (D.W) for urine and absorbing solution (A.S) for air. 2. 1n this procedure deteclion limit was 1ng/ml and mercury contents of blank reagent solution was 1~2ng/ml. 3. Calibration range was $0.02{\sim}0.1{\mu}g/ml$ and in this range r.s.d for each calibration curve in D.W and A.S and ${\pm}7.9%$ and ${\pm}3.7%$, respectively. 4. Repeatability (n=5 times, conc. $0.05{\mu}g/ml$) was ${\pm}5.8%$, in D.W. and ${\pm}4.4%$ in A.S, respectively. 5. Recovery for urine adding spiked concentration ($0.05{\mu}g/ml$) was about 90%. 6. Analytical result of samples was $1{\sim}139{\mu}g/l$ in urine and ${\sim}0.127mg/m^3$ in airborne.

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Preparation of $Yb_2O_3$ Film by MOCVD Method (MOCVD 공정을 이용한 $Yb_2O_3$ 박막 제조)

  • Jung, Woo-Young;Jun, Byung-Hyuk;Park, Hai-Woong;Hong, Gye-Won;Kim, Chan-Joong
    • Progress in Superconductivity
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    • v.8 no.1
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    • pp.75-80
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    • 2006
  • [ $Yb_2O_3$ ] films were successfully deposited on a cube-textured Ni and(100) $SrTiO_3$(STO) single crystal substrates by metal organic chemical vapor deposition(MOCVD) method using $H_2O$ vapor as an oxidant. $H_2O$ vapor was used in order to avoid the oxidation of Ni substrate. The working pressure and Ar flow rate were 10 Ton and 600 sccm, respectively. $Yb_2O_3$ films on STO were formed at high temperatures above $900^{\circ}C$. While XRD peaks from $Yb_2O_3$ were hardly detected at $900^{\circ}C$, the $Yb_2O_3$(400) texture was developed fur the films grown at deposition temperatures above $950^{\circ}C$. The AEM surface roughness of $Yb_2O_3$ film, grown on STO, was in the range of $6{\sim}10nm$ for the film deposited at $950^{\circ}C$ with a $H_2O$ vapor partial pressure of 5.5 Ton and deposition times of 3 and 5 mins. For cube-textured Ni substrate, both $Yb_2O_3$(222) and $Yb_2O_3$ (400) textures were developed textures at deposition temperatures above $850^{\circ}C$.

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TFWT and OBT Concentrations in Rice Plants Exposed to HTO Vapor during Daytime and Nighttime at Different Seed-Developing Stages (벼의 종실 발육단계에 따른 주간 및 야간 HTO 증기 피폭시 TFWT 및 OBT 농도)

  • Choi, Yong-Ho;Lim, Kwang-Muk;Lee, Won-Yun;Kang, Hee-Suk;Choi, Heui-Joo;Lee, Han-Soo;Diabate, Silvia;Strack, Siegfried
    • Journal of Radiation Protection and Research
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    • v.28 no.1
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    • pp.9-18
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    • 2003
  • Rice plants at different seed-developing stages were exposed to HTO vapor in an exposure box for 1 h during daytime and nighttime to investigate the levels of tissue free water $^3H$ (TFWT) and organically bound $^3H$ (OBT) in different plant parts. In the daytime experiment, TFWT concentrations in leaves at the end of exposure $(h_0)$ were around 100% of the 1 hour mean HTO concentrations in air moisture whereas in the nighttime experiment, they were as low as $30{\sim}40%$ of the air concentration. TFWT concentrations in both experiments decreased very rapidly in the beginning but much mote slowly later and those at harvest were hundreds to hundred thousands times lower than those at $h_0$. OBT concentrations varied with time in different manners depending on plant parts and exposure times and differed between at $h_0$ and at harvest by factors of less than 10 on the whole. Even during nighttime exposures, OBT was produced at about a third the rate for daytime exposures. The degree of the conversion of airborne HTO into OBT in mature rice seeds, being several times higher in the daytime experiment than in the nighttime experiment, was highest after the exposure peformed at the most actively seed-developing stage for both experiments. It is estimated that OBT would contribute much more to the ingestion radiation dose than TFWT if rice plants are exposed to HTO vapor for the seed-developing period.

An Assessment of Reactor Vessel Integrity Under In-Vessel Vapor Explosion Loads

  • Bang, Kwang-Hyun;Cho, Jong-Rae;Park, Soo-Yong
    • Nuclear Engineering and Technology
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    • v.32 no.4
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    • pp.299-308
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    • 2000
  • A safety assessment of reactor vessel lower head integrity under in-vessel vapor explosion loads has been performed. The core melt relocation parameters were chosen within the ranges of physically realizable bounds. The premixing and explosion calculations were performed using TRACER-II code. Using the calculated explosion pressures imposed on the lower head inner wall, strain calculations were peformed using ANSYS code. Then, the calculated strain results and the established failure criteria were used in determining the failure probability of the lower head, In the explosion analyses, it is shown that the explosion impulses are not altered significantly by the uncertain parameters of triggering location and time, fuel and vapor volume fractions in uniform premixture bounding calculations. Strain analyses show that the vapor explosion-induced lower head failure is not possible under the present framework of assessment. The result of static analysis using the conservative explosion-end pressure of 50 MPa also supports the conclusion. It is recommended, however, that an assessment of fracture mechanics for preexisting cracks be also considered to obtain a more concrete conclusion.

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Design of a High Temperature Oven for Measuring the Saturation Intensity of Samarium atom by using Two Wave Mixing

  • Ko, Kwang-Hoon;Moon, Hee-Jong;Park, Hyun-Min;Lee, Jong-Min;Lee, Won-Kyu;Lee, Jai-Hyung;Chang, Joon-Sung
    • Journal of the Optical Society of Korea
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    • v.4 no.2
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    • pp.75-78
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    • 2000
  • We design a high temperature oven for measuring the saturation intensity of the transition line $4f^ 6/6s^{2 7}7F_0 ↔ 4f^6/6s6p $^1$P(J = 1)$ of the samarium atom. We first constructed a high temperature oven to generate the samarium vapor column and study the thermal characteristics of the oven. The oven is able to operate at a temperature up to about 1400 $^{\circ}C$ and the operation is tested by using several metals with high melting points. We describe two wave mixing experiment with the samarium vapor generated in the high temperature oven and obtain the saturation intensity by analyzing the first diffraction signal.

Fracture Behaviors of SiCf/SiC Composites Prepared by Hybrid Processes of CVI and PIP (화학침착법과 고분자함침 열분해법의 복합공정으로 제조한 SiCf/SiC 복합체의 제조 공정에 따른 파괴거동)

  • Park, Ji Yeon;Han, Jangwon;Kim, Daejong;Kim, Weon-Ju;Lee, Sea Hoon
    • Journal of the Korean Ceramic Society
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    • v.51 no.5
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    • pp.430-434
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    • 2014
  • $SiC_f$/SiC composites were prepared using the hybrid process of chemical vapor infiltration (CVI) and polymer impregnation and pyrolysis (PIP). Before the application of PIP, partially matrix-filled preform composites with different densities were fabricated by control of chemical vapor infiltration time and temperature. The changes of the final density of the $SiC_f$/SiC composites had a tendency similar to that of preform composites partially filled by CVI. Composites with lower density after the CVI process had a larger increment of density during the PIP process. Three types of microstructures were observed on the fractured surface of the composite: 1) well pulled-out fibers and lower density, 2) slightly pulled-out fibers and higher density, and 3) only bulk SiC. The different fractions and distributions of the microstructures could have an effect on the mechanical properties of the composites. In this study, $SiC_f$/SiC composites prepared using a hybrid process of CVI and PIP had density values in the range of $1.05{\sim}1.44g/cm^3$, tensile strength values in the range of 76.4 ~ 130.7 MPa, and fracture toughness values in the range of $11.2{\sim}13.5MPa{\cdot}m^{1/2}$.

Water Vapor Permeation Properties of Al2O3/TiO2 Passivation Layer Deposited by Atomic Layer Deposition (원자층 증착법을 이용한 Al2O3/TiO2 보호막의 수분 보호 특성)

  • Kwon, Tae-Suk;Moon, Yeon-Keon;Kim, Woong-Sun;Moon, Dae-Yong;Kim, Kyung-Taek;Shin, Sae-Young;Han, Dong-Suk;Park, Jae-Gun;Park, Jong-Wan
    • Journal of the Korean Vacuum Society
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    • v.19 no.6
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    • pp.495-500
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    • 2010
  • In this study, $Al_2O_3$ and $TiO_2$ films was deposited on to PES (poly(ethersulfon) substrate by using atomic layer deposition as functions of deposition temperature and plasma power. The density and carbon contents of $Al_2O_3$ and $TiO_2$ films was changed by varying process conditions. High density thin films was achieved through optimizing the process conditions. Buffer layer was deposited prior to the processing of upper thin films to avoid PES surface destruction during the high power plasma process and to enhances the tortuous path for water vapor permeation for the defect decoupling effect. The water vapor transmission rate by using MOCON test was investigated to analyze the effect. Water vaper permeation properties was improved by using the inorganic multi-layer passivation layer and activation energy of the water vapor permeation was increased.