• Journal of Nuclear Fuel Cycle and Waste Technology
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• v.1 no.1
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• pp.57-63
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• 2013

Natural green rust (GR) can retard the migration of anions through geological media because it has a Layer Double Hydroxyl (LDH) structure with a positive charge. In this study, the sorption behaviors of anions such as selenite ($Se(IV)O{_3}^{2-}$), selenate ($Se(VI)O{_4}^{2-}$), and iodide ($I^-$) onto green rusts with different structures, i.e., GR($Cl^-$) and GR($CO{_3}^{2-}$), were investigated by conducting batch sorption experiments in an anoxic condition. Experimental results showed that selenite was mostly sorbed onto GR($CO{_3}^{2-}$) and then partly reduced to metal selenium, Se(0). However, little selenate and iodide was sorbed onto GR($CO{_3}^{2-}$) while some iodide was sorbed onto GR($Cl^-$). It is presumed from the experimental results that the major sorption mechanism of $SeO{_3}^{2-}$ and $I^-$ onto green rusts is the anion exchange reaction with the anions existing in the interlayer of the rusts. Green rust, therefore, can play an important role in the retardation of anions migrating through deep geological environments owing to its LDH structure with a high anion exchange capacity.

• Nuclear Engineering and Technology
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• v.49 no.3
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• pp.541-548
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• 2017

Uranium metal used for fabrication of fuel for research reactors in India is generally produced by magnesio-thermic reduction of $UF_4$. Performance of magnesio-thermic reaction and recovery and quality of uranium largely depends on properties of $UF_4$. As ammonium diuranate (ADU) is first product in powder form in the process flow-sheet, properties of $UF_4$ depend on properties of ADU. ADU is generally produced from uranyl nitrate solution (UNS) for natural uranium metal production and from uranyl fluoride solution (UFS) for low enriched uranium metal production. In present paper, ADU has been produced via both the routes. Variation of uranium recovery and crystal structure and composition of ADU with progress in precipitation reaction has been studied with special attention on first appearance of the precipitate Further, ADU produced by two routes have been calcined to $UO_3$, then reduced to $UO_2$ and hydroflorinated to $UF_4$. Effect of two different process routes of ADU precipitation on the characteristics of ADU, $UO_3$, $UO_2$ and $UF_4$ were studied here.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.21 no.2
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• pp.283-294
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• 2023

APro, developed in KAERI for the process-based total system performance assessment (TSPA) of deep geological disposal systems, performs finite element method (FEM)-based multiphysics analysis. In the FEM-based analysis, the mesh element quality influences the numerical solution accuracy, memory requirement, and computation time. Therefore, an appropriate mesh structure should be constructed before the mesh stability analysis to achieve an accurate and efficient process-based TSPA. A generic reference case of DECOVALEX-2023 Task F, which has been proposed for simulating stationary groundwater flow and time-dependent conservative transport of two tracers, was used in this study for mesh stability analysis. The relative differences in tracer concentration varying mesh structures were determined by comparing with the results for the finest mesh structure. For calculation efficiency, the memory requirements and computation time were compared. Based on the mesh stability analysis, an approach based on adaptive mesh refinement was developed to resolve the error in the early stage of the simulation time-period. It was observed that the relative difference in the tracer concentration significantly decreased with high calculation efficiency.

• Journal of the Korean institute of surface engineering
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• v.53 no.4
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• pp.169-181
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• 2020

The ferroelectricity in emerging fluorite-structure oxides such as HfO₂ and ZrO₂ has attracted increasing interest since 2011. Different from conventional ferroelectrics, the fluorite-structure ferroelectrics could be reliably scaled down below 10 nm thickness with established atomic layer deposition technique. However, defects such as carbon, hydrogen, and nitrogen atoms in fluorite-structure ferroelectrics are reported to strongly affect the nanoscale polymorphism and resulting ferroelectricity. The characteristic nanoscale polymorphism and resulting ferroelectricity in fluorite-structure oxides have been reported to be influenced by defect concentration. Moreover, the conduction of charge carriers through fluorite-structure ferroelectrics is affected by impurities. In this review, the origin and effects of various kinds of defects are reviewed based on existing literature.

• Applied Chemistry for Engineering
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• v.31 no.1
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• pp.97-102
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• 2020

Recently, various degradation mechanisms of lithium secondary battery cathode materials have been revealed. As a result, many studies on overcoming the limitation of cathode materials and realizing new electrochemical properties by controlling the degradation mechanism have been reported. Li-rich layered oxide is one of the most promising cathode materials due to its high reversible capacity. However, the utilization of Li-rich layered oxide has been restricted, because it undergoes a unique atomic structure change during the cycle, in turn resulting in unwanted electrochemical degradations. To understand an atomic structure deterioration mechanism and suggest a research direction of Li-rich layered oxide, we deeply evaluated the atomic structure of 0.4Li₂MnO₃_0.6LiNi_1/3Co_1/3Mn_1/3O₂ Li-rich layered oxide during electrochemical cycles, by using an atomic-resolution analysis tool. During a charge process, Li-rich materials undergo a cation migration of transition metal ions from transition metal slab to lithium slab due to the structural instability from lithium vacancies. As a result, the partial structural degradation leads to discharge voltage drop, which is the biggest drawback of Li-rich materials.

• Proceedings of the Korean Radioactive Waste Society Conference
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• 2004.06a
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• pp.319-329
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• 2004

The electrorefining experiments with an anode composed of U, Y, Gd, Nd and Ce (or U, Gd, Dy and Ce) were carried out in the KC1-LiCl eutectic melt at $500^{\circ}C$, Uranium was the major component in the cathode deposits at the high initial uranium concentration, and the separation factors of the uranium with respect to the rare earths (REs) were calculated according to the applied voltage and the uranium concentration in the molten salt. The current efficiency was inversely in proportion to the applied voltage in the range of 1.0 V to 1, 9 V (vs. STS304L). The dependency of the applied voltage on the current efficiency as well as the deposition rate was discussed in terms of the microstructural feature and crystal structure of the deposit.

• Proceedings of the Korean Nuclear Society Conference
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• 1996.11a
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• pp.85-90
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• 1996

In this paper, the self-organizing fuzzy logic controller is developed for water level control of steam generator. In comparison with conventional fuzzy logic controllers, this controller performs control task with no control rules at initial and creates control rules as control behavior goes on, and also modifies its control structure when uncertain disturbance is suspected. Selected parameters in the fuzzy logic controller are updated on-line by the gradient descent loaming algorithm based on the performance cost function. This control algorithm is applied to water level control of steam generator model developed by Lee, et al. The computer simulation results confirm good performance of this control algorithm in all power ranges. This control algorithm can be expected to be used for automatic control of feedwater control system in the nuclear power plant with digital instrumentation and control systems.

• Proceedings of the KSRS Conference
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• 2005.10a
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• pp.656-658
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• 2005

KAERI (Korea Atomic Energy Research Institute) has been performing the project named PEFP (proton engineering frontier project). PEFP has been performing the project of a high power proton accelerator. Control system for 20 MeV proton accelerating structure has developed. We use the EPICS(Experimental Physics and Industrial Control System) tool kit as a foundation of the control system. EPICS is adopted for control systems which have OPI(OPerator Interface) and IOqlnput Output Controller). We have performed the PEPF control system on SUN workstation host computer. In this paper, we present the vacuum monitor, RFQ, and DTL Turbo pump control system.

• Journal of the Korean Institute of Telematics and Electronics
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• v.26 no.8
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• pp.1203-1210
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• 1989

A cross-sectional transmission electorn microscopy study of the MBE grown GaAs/Al0.3 Ga0.7As layers was carried out at high-resolution so that the atomic arrangement of the well, barrier and the interface could be understood on an atomic level. Results show that the images reveal directly the atomic structure of the GaAs, Al0.3Ga0.3 Ga0.7 As interface is sharply defined but is not smooth on the atomic scale. The roughness arises from the presence of hills with heights of several{002} GaAs interplanar spacings. The atomic arrangement at the interface is almost completely coherent without any structural disorder. Alloy clustering at the interface was not observed.

• Proceedings of the Korean Nuclear Society Conference
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• 1997.10a
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• pp.191-196
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• 1997

As a part of International Criticality Safety Benchmark Evaluation Project (ICSBEP), SAXTON critical experiments were reevaluated. The effects on $K_{eff}$ of the uncertainties in experiment parameters, fuel rod characterization, soluble boron, critical water level, core structure, $^{241}$ Am and $^{241}$ Pu isotope number densities, random pitch error, duplicated experiment, axial fuel position, model simplification, etc., were evaluated and added in benchmark-model $k_{eff}$. In addition to detailed model, the simplified model for Saxton critical experiments was constructed by omitting the top, middle, and bottom grids and ignoring the fuel above water.r.r.