• 제목/요약/키워드: Atomic parameters

검색결과 838건 처리시간 0.028초

INDUCTION PLASMA DEPOSITION TECHNOLOGY FOR NUCLEAR FUEL FABRICATION

  • I. H. Jung;K. K. Bae;Lee, J. W.;Kim, T. K.;M. S. Yang
    • 한국원자력학회:학술대회논문집
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    • 한국원자력학회 1998년도 춘계학술발표회논문집(2)
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    • pp.216-221
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    • 1998
  • A study on induction plasma deposition with ceramic materials, yttria-stabilized-zirconia ZrO$_2$-Y$_2$O$_3$ (m.p 264O $^{\circ}C$), was conducted with a view developing a new method for nuclear fuel fabrication Before making dense pellets more than 96%TD., the spraying condition was optimized through the process parameters, such as chamber pressure, plasma plate power powder spraying distance, sheath gas composition, probe position, particle size and powders different morphology. The results with a 5mm thick deposit on rectangular planar graphite substrates showed a 97.11% theoretical density when the sheath gas flow rate was Ar/H$_2$120/20 l/min, probe position 8cm, particle size -75 ${\mu}{\textrm}{m}$ and spraying distance 22cm by AMDRY146 powder. The degree of influence of the main effects on density were powder morphology. particle size, sheath gas composition, plate power and spraying distance, in that order. Among the two parameter interactions, the sheath gas composition and chamber pressure affects density greatly. By using the multi-pellets mold wheel type, the pellet density did not exceed 94%T.D., owing to the spraying angle.

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방사성폐기물의 화학처리공정에 사용되는 유동관식 장치의 해석 : 물질전달 수율에 미치는 매개변수들의 민감도 (Analysis of the Behavior of Tubular-Type Equipment for Nuclear Waste Treatment : Sensitivities of the Parameters Affecting Mass Transfer Yield)

  • 유재형;이병직;심준보;김응호
    • 방사성폐기물학회지
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    • 제5권1호
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    • pp.91-99
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    • 2007
  • 본 연구에서는 방사성폐기물의 화학처리공정에 자주 사용되는 유동관식 장치 중 튜브형 반응기, 다단식 용매추출 장치, 흡착탑 등 물질전달이 수반되는 장치에 있어 각종 매개변수들이 반응수율이나 물질전달수율에 미치는 영향과 민감도를 살펴보았다. 먼저 각 장치에 대한 거동을 묘사하기 위하여 수학적 모델링을 수행하였고 전산모사를 통하여 해당 장치의 거동을 예측하였다. 그리고 그 결과로부터 해당 공정의 고유한 매개변수들이 반응수율 또는 물질전달수율에 미치는 영향과 민감도를 분석하였다. 튜브형 반응기에서는 확산계수, 반응속도상수 등이 반응수율에 미치는 영향을, 다단식 용매추출 장치에서는 연속상과 분산상의 분배계수, 연속상 흐름의 역혼합 등이 추출수율 및 장치 내 농도 분포에 미치는 영향을 고찰하였다. 또 흡착탑에 있어서는 흡착평형상수 및 유체-흡착재간 물질전달계수 등이 흡착 속도에 미치는 영향을 조사하였다.

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중성자에 조사된 Mn-Mo-Ni 저합금강의 기계적 및 자기적 성질 변화 (Changes in Mechanical Properties and Magnetic Parameters of Neutron Irradiated Mn-Mo-Ni Low Alloy Steels)

  • 장기옥;지세환;박승식;김병철;김종오
    • 한국재료학회지
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    • 제8권11호
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    • pp.1020-1025
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    • 1998
  • Mn-Mo-Ni 저합금강의 중성자 조사에 따른 기계적(미세경도, 인장, 샤피충격시험) 및 자기적(포화자화, 보자력, 잔류자화, Barkhausen Noise(BN)진폭, BN에너지) 성질 변화를 측정하여 이들의 상관관계를 고찰하였다. 기계적 성질시험 결과, 중성자 조사로 인하여 항복강도, 인장강도, 미세경도 및 천이온도($T_{41J}$)는 증가하였고 최대흡수에너지(USE)는 감소하였으며, 인장 시험의 경우 용접금속에서는 모재와 비교했을 때 큰 변화가 없었다. 자기적 성질을 측정한 결과, 잔류자화, BN진폭, BN에너지는 감소하였고 보자력은 급격히 증가하는 것으로 나타났다. 기계적.자기적 성질변화의 상관관계에서 자기적성질인 보자력 증가에 따라 천이온도, 항복강도, 경도는 증가하고 USE는 감소하였고, BN진폭의 경우는 보자력과 반대의 경향을 보였다. 본 실험에서 중성자조사로 인한 기계적.자기적 성질변화가 일관성 있는 상관관계가 있음을 확인하였고, 이들의 변화를 통해 조사손상을 평가하는 데 이용 가능하다.

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Atomic layer deposition of In-Sb-Te Thin Films for PRAM Application

  • Lee, Eui-Bok;Ju, Byeong-Kwon;Kim, Yong-Tae
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2011년도 제40회 동계학술대회 초록집
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    • pp.132-132
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    • 2011
  • For the programming volume of PRAM, Ge2Sb2Te5(GST) thin films have been dominantly used and prepared by physical vapor deposition (PVD), chemical vapor deposition (CVD), atomic layer deposition (ALD). Among these methods, ALD is particularly considered as the most promising technique for the integration of PRAM because the ALD offers a superior conformality to PVD and CVD methods and a digital thickness control precisely to the atomic level since the film is deposited one atomic layer at a time. Meanwhile, although the IST has been already known as an optical data storage material, recently, it is known that the IST benefits multistate switching behavior, meaning that the IST-PRAM can be used for mutli-level coding, which is quite different and unique performance compared with the GST-PRAM. Therefore, it is necessary to investigate a possibility of the IST materials for the application of PRAM. So far there are many attempts to deposit the IST with MOCVD and PVD. However, it has not been reported that the IST can be deposited with the ALD method since the ALD reaction mechanism of metal organic precursors and the deposition parameters related with the ALD window are rarely known. Therefore, the main aim of this work is to demonstrate the ALD process for IST films with various precursors and the conformal filling of a nano size programming volume structure with the ALD?IST film for the integration. InSbTe (IST) thin films were deposited by ALD method with different precursors and deposition parameters and demonstrated conformal filling of the nano size programmable volume of cell structure for the integration of phase change random access memory (PRAM). The deposition rate and incubation time are 1.98 A/cycle and 25 cycle, respectively. The complete filling of nano size volume will be useful to fabricate the bottom contact type PRAM.

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접촉한 두 평면과 균열한 틈새에서의 유동마찰계수 비교 (Comparison of the Friction-Loss Coefficient for the Gap of Two Contact Surfaces and a Crack)

  • 남호윤;최병해;김종범;이용범
    • 대한기계학회논문집B
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    • 제35권10호
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    • pp.1075-1081
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    • 2011
  • 이중벽관 증기발생기에서 전열관의 내관과 외관 사이의 틈새에 채워진 헬륨가스의 압력변동으로 전열관의 파손을 감지하는 방법이 개발되고 있다. 이 현상을 모사하기 위해 압력으로 밀착된 두 평판사이의 미세한 틈새에서의 누설률을 측정하여 실험식을 개발하였다. 이 실험식에서는 틈새의 간격과 유동마찰계수가 표면조도에 의해 상호 결합된 형태로 기술되는데, 간단한 평판접촉 모델을 사용하여 유동마찰계수 식을 분리하였다. 이 실험식과 균열에서의 누설률 예측에 사용되고 있는 기존의 유동마찰계수 관련 실험식들을 상호 비교하였다. 레이놀즈 수의 적용범위가 상이함에도 불구하고 개발한 실험식이 0.1~0.35 에서는 레이놀즈 수가 높은 경우에 적용되는 실험식들과 유사한 값을 보였다.

Material Integrity Assessment for a Ni Electrodeposit inside a Tube

  • Kim, Dong-Jin;Kim, Myong Jin;Kim, Joung Soo;Kim, Hong Pyo
    • Corrosion Science and Technology
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    • 제6권5호
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    • pp.233-238
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    • 2007
  • Due to the occasional occurrence of a localizedcorrosion such as a SCC and pitting in steam generator tubing(Alloy 600), leading to a significant economical loss, an effective repair technology is needed. For a successful electrodeposition inside a tube, many processes should be developed. Among these processes, an anode to be installed inside a tube, a degreasing condition to remove any dirt and grease, an activation condition for a surface oxide elimination, a strike layer forming condition which needs to be adhered tightly between an electroforming layer and a parent tube and a condition for an electroforming layer should be established. Through a combination of these various process condition parameters, the desired material properties can be acquired. Among these process parameters, various material properties including a mechanical property and its variation along with the height of the electrodeposit inside a tube as well as its thermal stability and SCC resistance should be assessed for an application in a plant. This work deals with the material properties of the Ni electrodeposits formed inside a tube by using the anode developed in this study such as the current efficiency, hardness, tensile property, thermal stability and SCC behavior of the electrodeposit in a 40wt% NaOH solution at $315^{\circ}C$. It was found that a variation of the material properties within the entire length of the electrodeposit was quite acceptable and the Ni electrodeposit showed an excellent SCC resistance.

Effect of pH, Redox Potential (Eh) and Carbonate Concentration on Actinides Solubility in a Deep Groundwater of Korea

  • Keum Dong-Kwon;Lee Han-Soo;Lee Chang-Woo
    • Nuclear Engineering and Technology
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    • 제36권2호
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    • pp.196-202
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    • 2004
  • KAERI (Korea Atomic Energy Research Institute) is at present preparing a preliminary performance assessment to set up the HLW disposal concept of Korea. The solubility of the radionuclides contained in HLW is necessary as a source term in order to predict their potential migration in both the near and far fields. The solubility of actinides (Th, Am, U, Np and Pu) for a reference deep groundwater of Korea has been calculated using a geochemical code with thermodynamic data selected by a peer review of existing thermodynamic databases and literature. The solubilities from the experimental study and/or field observations from natural analogue studies are compared. The sensitivity of solubility to the variability of three main parameters of groundwater (pH, Eh, and carbonate concentration) is also investigated. The results of the sensitivity analysis show that the solubility of actinides strongly depends on the parameters considered. Within the range of parameter values studied (pH=7 to 10, Eh=-0.4 to -0.1V, and carbonate concentration=1.E-5 to 1.E-2 mol/L), the solubility of each actinide exists between 1.4E-10 and 1.6E-6 mol/L for Am, 4.9E-9 and 2.8E-6 mol/L for Th, 3.2E-9 and 5.7E-4 mol/L for U, 1.1E-9 and 1.0E-7 mol/L for Np, and 4.0E-11 and 2.8E-6 mol/L for Pu, respectively.

Transport Parameters of 99Tc, 137Cs, 90Sr, and 239+240Pu for Soils in Korea

  • Keum, D.K.;Kim, B.H.;Jun, I.;Lim, K.M.;Choi, Y.H.
    • Journal of Nuclear Fuel Cycle and Waste Technology
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    • 제1권1호
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    • pp.49-55
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    • 2013
  • To characterize quantitatively the transport of $^{99}Tc$ and the global fallout ($^{137}Cs$, $^{90}Sr$, and $^{239+240}Pu$) for soils in Korea, the transport parameters of a convective-dispersion model, apparent migration velocity, and apparent dispersion coefficient were estimated from the vertical depth profiles of the radionuclides in soils. The vertical profiles of $^{99}Tc$ were measured from a pot experiment for paddy soil that had been sampled from a rice-field around the Gyeongju radioactive waste repository in Korea, and the vertical depth distributions of the global fallout $^{137}Cs$, $^{90}Sr$, and $^{239+240}Pu$ were measured from the soil samples that were taken from local areas in Korea. The front edge of the $^{99}Tc$ profiles reached a depth of about 12 cm in 138 days, indicating a faster movement than the fallout radionuclides. A weak adsorption of $^{99}Tc$ on the soil particles by the formation of Tc(VII) and a high water infiltration velocity seemed to have controlled the migration of $^{99}Tc$. The apparent migration velocity and dispersion coefficient of $^{99}Tc$ for the disturbed paddy soil were 2.88 cm/y and 6.3 $cm^2/y$, respectively. The majority of the global fallout $^{137}Cs$, $^{90}Sr$, and $^{239+240}Pu$ were found in the top 20 cm of the soils even after a transport of about 30 years. The transport parameters for the global fallout radionuclides were 0.01-0.1cm/y ($^{137}Cs$), 0.09-0.13cm/y ($^{90}Sr$), and 0.09-0.18cm/y ($^{239+240}Pu$) for the apparent migration velocity: 0.21-1.09 $cm^2/y$ ($^{137}Cs$), 0.12-0.7$cm^2/y$ ($^{90}Sr$), and 0.09-0.36$cm^2/y$ ($^{239+240}Pu$) for the apparent dispersion coefficient.

The status of NORMs in natural environment adjacent to the Rooppur nuclear power plant of Bangladesh

  • Haydar, Md Abu;Hasan, Md Mehade;Jahan, Imrose;Fatema, Kanij;Ali, Md Idris;Paul, Debasish;Khandaker, Mayeen Uddin
    • Nuclear Engineering and Technology
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    • 제53권12호
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    • pp.4114-4121
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    • 2021
  • The Rooppur Nuclear Power Plant (RNPP), the first nuclear power plant in Bangladesh with a capacity of 2.4 GWe, is under construction on the bank of the river Padma, at Rooppur in Bangladesh. Measurement of background radioactivity in the natural environment adjacent to RNPP finds great importance for future perspectives. Soil and sediment samples collected from upstream and downstream positions of the Padma River (adjacent to RNPP) were collected and analyzed by HPGe gamma-ray spectrometry for primordial radionuclides. The average activity concentrations (in Bqkg-1) of 226Ra, 232Th and 40K radionuclides in soil samples were found to be 44.99 ± 3.89, 66.28 ± 6.55 and 553 ± 82.17 respectively. Respective values in sediment samples were found to be 44.59 ± 4.58, 67.64 ± 7.93, 782 ± 108. Relevant radiation hazard indices and dosimetric parameters were calculated and compared with the world average data recommended by US-EPA. Analytical results show non-negligible radiation hazards to the surrounding populace. Measured data will be useful to monitor any change of background radioactivity in the surrounding environment of RNPP following its operation for the generation of nuclear energy.

MNSR transient analysis using the RELAP5/Mod3.2 code

  • Dawahra, S.;Khattab, K.;Alhabit, F.
    • Nuclear Engineering and Technology
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    • 제52권9호
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    • pp.1990-1997
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    • 2020
  • To support the safe operation of the Miniature Neutron Source Reactor (MNSR), a thermo-hydraulic transient model using the RELAP5/Mod3.2 code was simulated. The model was verified by comparing the results with the measured and the previously calculated data. The comparisons consisted of comparing the MNSR parameters under normal constant power operation and reactivity insertion transients. Reactivity Insertion Accident (RIA) for three different initial reactivity values of 3.6, 6.0, and 6.53 mk have been simulated. The calculated peaks of the reactor power, fuel, clad and coolant temperatures in hot channel were calculated in this model. The reactor power peaks were: 103 kW at 240 s, 174 kW at 160 s and 195 kW at 140 s, respectively. The fuel temperature reached its maximum value of 116 ℃ at 240 s, 124 ℃ at 160 s and 126 ℃ at 140 s respectively. These calculation results ensured the high inherently safety features of the MNSR under all phases of the RIAs.