• Title/Summary/Keyword: Atmospheric sampling

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Comparison of PM2.5 Concentrations by Measurement Method (측정 방법에 따른 PM2.5 농도 비교)

  • Ghim, Young Sung;Choi, Yongjoo;Park, Jisoo;Kim, Pilho;Han, Yu Kyung
    • Journal of Korean Society for Atmospheric Environment
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    • v.33 no.5
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    • pp.515-520
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    • 2017
  • $PM_{2.5}$ concentrations were measured using a cyclone, impactor (the U.S. Environmental Protection Agency well impactor ninety-six, WINS) and optical particle counter (OPC) at a campus site located in Yongin for the period August 2014 through March 2017. The concentrations from cyclone (Y) were generally higher than those from impactor(X); the best-fit line was Y=1.22X+5.64. The ratios of $PM_{2.5}/PM_{10}$ ranged from 0.61 to 0.66 when $PM_{2.5}$ concentrations from cyclones in selected studies were converted into those from impactors using a regression equation in this study. The slope of the best-fit line between OPC and impactor was close to 1 at 0.95, while that between OPC and cyclone was 0.72. After sampling, the flow rate in the low-volume air sampler with cyclone decreased by 3% on average, which did not have a significant effect on measured concentrations.

A Study on the Volatilization of Particulate Nitrate (NO3-) During Fine Particle (PM2.5) Measurement (미세입자(PM2.5) 측정시 발생되는 질산염(NO3-) 휘발에 관한 연구)

  • 강병욱;이학성
    • Journal of Korean Society for Atmospheric Environment
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    • v.18 no.4
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    • pp.297-303
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    • 2002
  • Fine particles (d$_{p}$ < 2.5 $\mu$m) were measured using an annular denuder system (ADS) in Chongju. The data set was collected on fifty-eight different days with a 24-hr sampling period from October 27, 1995 through August 25, 1996. Particulate nitrate in the ADS was also measured on teflon and nylon filters in series behind denuders to collect HNO$_3$, HNO$_2$, SO$_2$and NH$_3$. From this study. the mean concentration of particulate nitrate of PM$_{2.5}$ in the ADS were seen with the following order: winter (5.05) >fall (4.36) >spring (3.92) > summer (1.10 $\mu\textrm{g}$/㎥). Nitrate losses, which calculated from the ratio of nylon filter nitrate to the sum of teflon and nylon filter nitrates, varied in the following manner summer (72.2%) > spring (42.6%) > fall (23.5%)> winter (0.4%). Especially, gaseous nitric acid was dominant at temperature higher than 8$^{\circ}C$ while particulate nitrate was major species in total nitrate below that temperature. This indicates the particulate nitrate loss is strongly correlated rather with ambient temperature.e.e.

Development of Polymeric Water Absorbent Film(PWAF) for the Collection of Size-classified Fog Droplets

  • Ma, Chang-Jin;Mikilo-kasahara;Park, Kum-Chan
    • Journal of Korean Society for Atmospheric Environment
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    • v.17 no.E1
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    • pp.17-24
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    • 2001
  • For the purpose of collecting fog droplets as a function of size a new sampling method was developed in this study. Formation of 100$\pm$10㎛ thickness of polymeric water absorbent film (PWAF) on a nuclepore filter could be successfully realized. Also applicability of particle induced X-ray emission (PIXE) method to the chemical analysis of size-segregated fog droplets collected on PWAF was examined experimentally with synthetic fog droplets generated from a nebulizer. Absorption capacity of S-PAAS polymeric water absorbent shows marked decreases in the range less than 1 wt% and slight decrease between 1 and 3.5 wt% of every salt concentration. Dependency of absorption capacity on pH shows the maximum at pH 7. No apparent peak which can influence the quantitative analysis of elements dissolved and suspended in fog droplets was found at PIXE spectrum of PWAF blank. PWAF kept the original shape without rupture under the PIXE analytical conditions of beam intensity for 10 to 60 nA and irradiation time of 4∼5 min. It should be said that the proposed new technique in the work is helpful to get more detailed information of fog droplets, to clarify the fog formation processes, and to develop a model of acid deposition process.

Analysis of Indoor Air Pollutants from Elementary School Classrooms with Different Environment in Ulsan, Korea (울산광역시 초등학교 실내공기오염물질의 환경적 특성에 따른 농도 분석)

  • Lee, Chi-Hyeon;Lee, Byeong-Kyu;Kim, Yang-Ho;Lee, Ji-Ho;Oh, In-Bo
    • Journal of Korean Society for Atmospheric Environment
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    • v.27 no.1
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    • pp.97-116
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    • 2011
  • This study analyzed indoor air pollutants from elementary school with different environment. Air sampling and measurement were carried out from classrooms and hallways from three target elementary schools in the fall and winter seasons. The winter average concentrations of $PM_{10}$, $CO_2$, CO, aldehydes and ketones, and benzene were higher than the fall ones. The fall average concentrations of $O_3$ and $NO_2$ were higher than the winter ones. The concentrations of $PM_{10}$ and $CO_2$ at the schools near the heavy traffic areas and having poor ventilation were higher than those from the other elementary school. The average concentration of CO at the school having heavy traffic volume was highest. The concentrations of $O_3$, $NO_2$, aldehydes and ketones, and VOCs at the school near the shipbuilding industries were highest among the three elementary schools.

The Relative Importance of Indoor and Outdoor Sources for Determining Indoor Pollution Concentrations in Homes in Seoul, South Korea

  • Lee, Jae Young;Kim, Kyunghwan;Ryu, Sung Hee;Kim, Chang Hyeok;Bae, Gwi-Nam
    • Asian Journal of Atmospheric Environment
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    • v.12 no.2
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    • pp.127-138
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    • 2018
  • This study measured indoor and outdoor levels of hydrocarbon volatile organic compounds (VOCs), such as benzene, toluene, ethylbenzene, and xylene isomers (collectively referred to as BTEX), as well as 13 carbonyl compounds, at 20 homes in Seoul, South Korea. Along with the sampling of BTEX and carbonyls, indoor concentrations of the air pollutants nitrogen oxide (NO) and carbon dioxide ($CO_2$) were also measured at each home. These measurements were used to understand the characteristics of BTEX and carbonyls by calculating the various ratios and correlation coefficients between measured contaminant levels. We found that carbonyls were mostly originated from indoor sources, while BTEX were originated from both indoor and outdoor sources. A high correlation between indoor levels of NO and BTEX indicated that traffic emissions were also an important sources of BTEX.

An Analysis of Wind Field around the Air Quality Monitoring Station in the Urban Area by Using the Envi-met Model (Envi-met 모델을 이용한 도심지역 대기오염측정망 주변의 바람장 분석)

  • Kim, Min-Kyoung;Lee, Hwa Woon;Dou, Woo-Gon;Jung, Woo-Sik
    • Journal of Environmental Science International
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    • v.18 no.9
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    • pp.941-952
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    • 2009
  • The urban microscale wind field around the air quality monitoring station was investigated in order to check how a building complex influences it. For this study as the high density areas Jwa-dong and Yeonsan-dong monitoring sites in Busan were chosen. As the direction of inflow which is perpendicular to the building of the monitoring station was expected to cause the considerable variation of the wind field, that direction was selected. The model Envi-met was used as the diagnostic numerical model for this study. It is suitable for this investigation because Envi-met has the microscale resolution. After simulating it, on the leeward side around a building complex the decrease of flow velocity and some of vortexes or circulation area were discovered. In addition, on the edge of the top at the building and at the back of the building the upward flow was developed. If the sampling hole of monitoring site were located in this upward flow, it would be under the influence of upward flow from the near street.

Mass Size Distribution of Atmospheric Aerosol Particles Collected at 865 m High of Jirisan National Park (지리산 국립공원 해발 865 m 지점에서 대기에어로졸입자의 입경별 질량농도 특성)

  • Ryu, Hye-Ji;Park, Jeong-Ho
    • Journal of Environmental Science International
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    • v.26 no.1
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    • pp.29-36
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    • 2017
  • Aerosol mass size distributions were investigated at 865 m high the of Jirisan national park. A nanosampler cascade impactor was used to collect aerosols. The atmospheric aerosol particles had a unimodal mass size distribution, which peaked at $0.5-1.0{\mu}m$, and a mass aerodynamic diameter of $1.13{\mu}m$. The annual average concentrations of TSP, $PM_{10}$, $PM_{2.5}$, $PM_1$, $PM_{0.5}$ and $PM_{0.1}$ were $20.9{\mu}g/m^3$, $19.3{\mu}g/m^3$, $14.9{\mu}g/m^3$, $10.7{\mu}g/m^3$, $5.3{\mu}g/m^3$, $1.2{\mu}g/m^3$, respectively. TSP concentrations were below $30{\mu}g/m^3$ during the sampling period. On average $PM_{10}$, $PM_{2.5}$, $PM_1$, $PM_{0.5}$ and $PM_{0.1}$ made up 0.91, 0.70, 0.41, 0.19 and 0.07 of TSP, respectively. The annual average of PM2.5/PM10 ratio was 0.77.

Characteristics of Acidic Air Pollutants in Pusan Area Using an Annular Denuder System (Annular Denuder System을 이용한 부산시 대기 중 산성오염물질의 특성)

  • 정장표;정창용;이학성
    • Journal of Korean Society for Atmospheric Environment
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    • v.13 no.5
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    • pp.397-410
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    • 1997
  • An annular denuder filter pack sampling system (ADS) was used to collect acidic air pollutants in Pusan. During the study period (from June 1995 to November 1995), forty eight samples were collected every 12 hours starting from 6:00 in the morning. These samples were devided into two sets of data for day (6:00 a.m.-6:00 p.m.) and night (6:00 p.m.-6:00 a.m.). The chemical species were analyzed for HN $O_3$, HN $O_2$, S $O_2$ and N $H_3$ in the gas Phase, and N $O_3$$^{[-10]}$ , S $O_4$$^{2-}$ and N $H_4$$^{+}$ in the particulate phase. The mean concentrations measured from this study were 0.24, 1.91, 30.07 and 4.24 $\mu\textrm{g}$/㎥ for HN $O_3$, HN $O_2$, S $O_2$ and N $H_3$, respectively. The mean concentrations of N $O_3$$^{[-10]}$ , S $O_4$$^{2-}$ and N $H_4$$^+{\ulcorner}$ were 1.95, 7.36 and 3.48 $\mu\textrm{g}$/㎥, respectively. The mean concentrations of gaseous species except for HN $O_2$ were higher in daytime than in nighttime, but the reverse was true in the particulates except for N $H_4$$^{+}$. +/..

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Diurnal Size Distributions of Black Carbon by Comparison of Optical Particulate Measurements - Part I (광학 입자 측정기 비교 측정에 의한 입경별 일평균 블랙카본 분석 - Part I)

  • Park, Da-Jeong;Lee, Kwang-Yul;Park, Kihong;Bae, Min-Suk
    • Journal of Korean Society for Atmospheric Environment
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    • v.32 no.1
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    • pp.1-8
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    • 2016
  • Optical particle sizer (OPS), optical particle counter (OPC), and aethalomter were deployed to measure the particle number concentrations from 0.3 to $10.0{\mu}m$ and black carbon (BC) concentrations. Comparisons of particle number concentrations measured by OPS and OPC were conducted to evaluate the performance of the each optical instrument at the Gwangju sampling site ($35.23^{\circ}N$, $126.84^{\circ}E$) for 14 days from Dec. 27 in 2014. Although a good correlation ($r^2=0.99$) between the OPS and OPC was observed for both the particle number and volume concentrations, different relationships by BC concentrations can be associated with the intensities by different light scattering angles. In addition, based on diurnal patterns of size distributions in 24 hr running correlation coefficient determination, BC concentrations were highly related to the particles less than $0.3{\mu}m$ observed in the morning traffic hour.

Characteristics of Heavy Metal Emissions from Stationary Sources (고정오염원에서의 중금속 배출특성 연구)

  • Park, Jung-Min;Lee, Sang-Bo;Cha, Jun-Seok;Kwon, Oh-Sang;Lee, Sang-Hak
    • Journal of Korean Society for Atmospheric Environment
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    • v.24 no.5
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    • pp.574-583
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    • 2008
  • The results of HAPs emission data using TRI (Toxic Release Inventory), SODAM (Source Data Management system) were investigated and the emissions of 7 heavy metals from their sources and emission processes were also analyzed. Questionnaire for source data analysis as well as the stack sampling were carried out for 17 factories among 6 selected industrial types. The annual amount of emissions was estimated based on the measured concentration and flow rates. All sources were operated with high efficiency control devices and the concentration levels of all heavy metals were shown to be below 0.1 to of regulation standard. The highest emission source of heavy metals was steel manufacturing industry with the annual emission of 342.9 kg/yr and followed by hazardous waste incinerator, paint manufacturing, nonferrous metal manufacturing, rolling & press goods manufacturing and storage battery manufacturing. In the case of Hg, the emissions were quite significant from electric acros of steel manufacturing industry, although the concentration level was below the emission standard, showing the necessity of specific care for its management.