• Journal of Environmental Science International
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• v.11 no.6
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• pp.489-496
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• 2002

The purpose of this study was to investigate spatial distributions of total deposition. A total number 79 samples were collected at 17 sampling sites from September 1999 to January 2000. Total (=wet+dry) atmospheric depositions were collected by filtered deposition sampler at sampling site (the Western Part of Kyongsangnam Province). In addition, the deposition of soluble and insoluble fraction was also investigated to find a suitable simplified collection method for a long-term monitoring of total deposition. The total depositions were measured soluble amount(mm/month), insoluble amount(kg/km$^2$/month), pH, conductivity(E.C.) and eight ionic components. The spatial distribution of deposition flux was to estimated by using a kringing analysis. The 17 sites mean fluxes of water soluble ionic components; SO$_4$$\^$2-/, Cl$\^$-/, NO$_3$$\^$-/, Na$\^$+/, NH$_4$$\^$+/, K$\^$+/, Mg$\^$2+/, Ca$\^$2+/ were 100.7∼315.6kg/km$^2$/month, 30.1∼234.3kg/km$^2$/month, 64.4∼ 139.4kg/km$^2$/month, 7.5∼68.3kg/km$^2$/month, 10.7∼48.7kg/km$^2$/month, 5.6∼27.9kg/km$^2$/month, 4.5∼17.5kg/km$^2$/month, 27.6∼81.7kg/km$^2$/month, respectively.

• Korean Journal of Agricultural and Forest Meteorology
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• v.12 no.4
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• pp.277-288
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• 2010

The multi-level $H_2O/CO_2$ profile system has been widely used to quantify the storage and advection effects on energy and mass fluxes measured by eddy covariance systems. In this study, we expanded the utility of the profile system by accommodating air sampling devices for isotope analyses of water vapor and $CO_2$. A pre-evacuated 2L glass flask was connected to the discharge of an Infrared Gas Analyzer (IRGA) of the profile system so that airs with known concentration of $H_2O$ and $CO_2$ can be sampled. To test the performance of this sampling system, we sampled airs from 8 levels (from 0.1 to 40 m) at the KoFlux tower of Gwangneung deciduous forest, Korea. Air samples in the 2L flask were separated into its component gases and pure $H_2O$ and $CO_2$ were extracted by using a vacuum extraction line. This novel technique successfully produced vertical profiles of ${\delta}D$ of $H_2O$ and ${\delta}^{13}C$ of $CO_2$ in a mature forest, and estimated ${\delta}D$ of evapotranspiration (${\delta}D_{ET}$) and ${\delta}^{13}C$ of $CO_2$ from ecosystem respiration (${\delta}^{13}C_{resp}$) by using Keeling plots. While technical improvement is still required in various aspects, our sampling system has two major advantages over other proposed techniques. First, it is cost effective since our system uses the existing structure of the profile system. Second, both $CO_2$ and $H_2O$ can be sampled simultaneously so that net ecosystem exchange of $H_2O$ and $CO_2$ can be partitioned at the same temporal resolution, which will improve our understanding of the coupling between water and carbon cycles in terrestrial ecosystems.

• Journal of Korean Society for Atmospheric Environment
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• v.19 no.E1
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• pp.11-20
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• 2003

To characterize airborne particulate carbon and its temporal variation in the heavily industrialized metropolitan city, Seoul in South Korea, aerosol sampling was performed from 1986 to 1996. Correlation coefficients of elemental carbon (EC) and organic carbon (OC) with mass concentration of fine particles ($\underline{\leq}$2.1 ${\mu}m$) are 0.73 and 0.51, respectively. EC concentrations of the fine particle mode are 10.1, 5.9, 4.5, and 7.4 ${\mu}g\;m^{-3}$ in winter, spring, summer, and autumn, respectively. On the other hand, OC concentration shows maximum value in winter and followed by autumn, summer, and spring. A seasonal peak in the ratio of OC to EC in fine particles was observed during the summer photochemical season from June to August. Concentrations of EC and OC in Asian dust storm events are generally higher than in non- Asian dust storm events except in 1990. The difference of EC concentrations between Asian dust storm periods and non-Asian dust storm periods are much larger than those of OC concentrations. There are slight increases of EC concentration between 1987 and 1990 and a gradual decrease between 1990 and 1996.

• Asian Journal of Atmospheric Environment
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• v.8 no.3
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• pp.115-125
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• 2014

In this study, particle composition data for $PM_{10}$ samples were collected every 3 days at Seoul, Korea from August 2006 to November 2007, and were analyzed to provide source identification and apportionment. A total of 164 samples were collected and 21 species (15 inorganic species, 4 ionic species, OC, and EC) were analyzed by particle-induced x-ray emission, ion chromatography, and thermal optical transmittance methods. Positive matrix factorization (PMF) was used to develop source profiles and to estimate their mass contributions. The PMF modeling identified nine sources and the average mass was apportioned to secondary nitrate (9.3%), motor vehicle (16.6%), road salt (5.8%), industry (4.9%), airborne soil (17.2 %), aged sea salt (6.2%), field burning (6.0%), secondary sulfate (16.2%), and road dust (17.7%), respectively. The nonparametric regression (NPR) analysis was used to help identify local source in the vicinity of the sampling area. These results suggest the possible strategy to maintain and manage the ambient air quality of Seoul.

• Journal of Korean Society for Atmospheric Environment
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• v.19 no.4
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• pp.437-449
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• 2003

A multi-functional indoor smog chamber was designed and evaluated to investigate photochemical or water vapor reaction mechanisms of air pollutants. Various smog chamber experiments could be conducted using ambient air or purified air in this smog chamber. The smog chamber consisted of a housing, a Teflon bag, blacklights, injection ports, sampling ports, and utility facilities. The characteristics of light source, the wall losses of air pollutants, and the quality of purified air were experimentally investigated. The maximum NO$_2$ photolysis rate was 1.10 min$^{-1}$ . In a 2.5-m$^3$ Teflon bag, the wall losses of ambient $O_3$, NO, and NO$_2$ were 1.2~2.4$\times$10$^{-3}$ min$^{-1}$ , 0.7~2.0$\times$10$^{-3}$ min$^{-1}$ , and 0.4~2.0$\times$10$^{-3}$ min$^{-1}$ , respectively. The wall loss of ambient particles ranging 0.05 to 0.2 ${\mu}{\textrm}{m}$ was 1.8~5.4$\times$10$^{-3}$ min$^{-1}$ , which was slightly higher than those of ambient gaseous species. The purified air supply system provided high quality of air with NO$_{x}$ < 1 ppb, and total hydrocarbons < 5 ppb.b.

• Journal of Korean Society for Atmospheric Environment
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• v.19 no.4
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• pp.363-376
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• 2003

In this study, the fugitive emission characteristics of airborne volatile organic compounds from different source categories were evaluated with respect to the concentrations measured in the vicinity of the sources. A total of 22 different sources were investigated, including gasoline storage and filling stations, painting spray booth, laundry, printing officer, textile industries, and a number of environmental sanitary facilities such as landfill, wastewater treatment and incineration plants. The target VOCs included 83 individual compounds, which were determined by adsorption sampling and thermal desorption coupled with GC/MS analysis. Overall, the aliphatic compounds appeared to be the most abundant class of compounds in terms of their concentrations, followed by aromatic, and halogenated hydrocarbons. As a single compound, however, toluene was the most abundant one, explaining 11% of the total VOC concentrations as an average of all the dataset. Among source categories, petroleum associated sources such as gasoline storage/filling stations, and laundry factory were identified as the most significant sources of aliphatic hydrocarbons, while aromatic VOCs were dominantly emitted from the sources handling organic solvents, such as painting booth, printing offices, and textile dyeing processes. However. there was no apparent pattern in terms of the contributions of eath group to the total VOCs concentrations in environmental sanitary facilities. It was also found that the activated carbon adsorption tower installed for the VOC emission control in some facilities do not show any effective performances, which may result in the increased VOC levels in the ambient atmosphere.

• Journal of Korean Society for Atmospheric Environment
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• v.20 no.1
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• pp.17-31
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• 2004

The subway play an important part in serious traffic problems. However, because subway system is a closed environment, many serious air pollution problems occurred in subway stations and injured passenger's health. Therefor, it is a necessary to identify sources and to estimate pollutant sources in order to protect passenger's health and to keep clean subway environment. The purpose of this study was to analyze a air quality in the subway stations and to apply a new receptor methodology for quantitatively estimate of PM10 sources. In this study, the size distributions of particulate matters has been measured by using Aerosizer LD (U.S.A., API, Inc.). It's real time measurement capability of time-of-flight technique offers a significant advantage of user convenience and air pollution management. Also, the mass concentrations of PM 10 has been measured by using mini-vol portable sampler (U.S.A., Airmetrics Co.). The sampling performed in Seoul subway stations during the period of February 2000 and April 2000. The number distribution data used in this study consisted of 26 raw data sets in the Jongno-sam-ga station. Correlation Analysis can be used in subway stations for source separation and identification. Then, number contribution from each source is determined by the particle number balance (PNB). The mass concentration data used in this study consisted of 31 raw data in the 8 different stations. The mass contributions of PM10 sources in the concourse by using PMF/CMB model.

• Journal of Korean Society for Atmospheric Environment
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• v.21 no.5
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• pp.481-494
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• 2005

The monitoring of persistent organic pollutants (POPs) in the atmosphere is a basis for the study of the fate of POPs in multimedia environments. Recently, passive air samplers (PASs) for POPs have been developed. In this paper, we deal with the principle, properties, and applications of the PAS. The principle of PAS, which has no pump, is physical sorption of semi-volatile organic chemicals on various sorbent materials. The PAS is much smaller than a high-volume air sampler and does not need electricity. These properties of the PAS make it possible to conduct various-scaled environmental monitoring all over the world including the Arctic and Antarctic, but the major disadvantage of PAS is its long sampling periods up to 2 years. To date, four kinds of PAS have been developed: polyurethane foam (PUF), polymer-coated glass (POG), semi-permeable membrane devices (SPMDs), and XAD resin-based PAS. Among them, SPMDs have been commercialized and are most widely used now. Meanwhile, the POPs emitted from China have a large potential to influence the levels and fates of POPs in Korea. Since characteristics of PAS are quite useful to monitor long-range transport of POPs, the use of PAS is highly recommended.

• Journal of Environmental Health Sciences
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• v.31 no.3
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• pp.215-220
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• 2005

The atmospheric transportation and dispersion processes of air pollutants are important issues in dealing with air pollution problems. Air pollutants originated from biological and anthropogenic activities are not only limited to the local emission sources, but could also be transported and dispersed to other regions by synoptic weather systems. Besides, the complexity of topography of central Taiwan helps accumulating air pollutants to promote high-concentration episodes. The techniques of tethersonding were applied to monitor the vertical profiles of winds, air temperatures and humidity, as well as to collect air samples, to be analyzed for pollutants $(O_3,\;NO_2,\;NO\;and\; NMHC)$ from the ground up to 1000m. A time period of about one week, 19-26 October 2002, was chosen as the sampling period due to the high frequency of episode occurrence in autumn based on the past records. Associating with the analysis of weather patterns, the atmospheric characteristics over high-concentration areas can be resolved in more detail. The result of the tethersonding studies showed that weak northerly sea breeze (with thickness about 300m) with low wind speed (about 1 to 2 m/sec) could help develop high ozone concentrations in the down-wind areas. It is also important to have a built-up aloft of precursors and ozone to develop high concentration on the previous day.

• Journal of Korean Society for Atmospheric Environment
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• v.13 no.6
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• pp.463-474
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• 1997

Metallic elements in dustfall have been known as notable air pollutants directly or indirectly influencing human health and wealth. The first aim of this study was to obtain precise spatial distribution patterns of 5 elements (Pb, Zn, K, Cr, and Al) in dustfall around Suwon area. To predict isometric lines of metal fluxes deposited on unsupervised random sites, the study has applied both spatial statistics as a receptor model and a GIS (geographic information system). Total of 31 sampling sites were selected in the study area (roughly 3 by 3 km grid basis) and dustfall samples were then collected monthly basis by the British deposit gauges from Dec., 1995 to Nov., 1996. The metallic elements in the dustfall were then analyzed by an atomic absorption spectrometer (AAS). On the other hand, a base map overlapped by 7 layers was constructed by using the AutoCAD R13 and ARC/INFO 3.4D. Four different spatial interpolation and expolation techniques such as IDW (inverse distance weighted averaging), TIN (triangulated irregular network), polynomial regression, and kriging technique were examined to compare spatial distribution patterns. Each pattern obtained by each technique was substantally different as varing pollutant types, land of use types, and topological conditions, etc. Thus, our study focused intensively on uncertainty analysis based on a concept of the jackknife and the sum of error distance. It was found that a kriging technique was the best applicalbe in this study area.