• Title/Summary/Keyword: Atmospheric pollutants concentration

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A WSR-88D Radar Observation of Chaff Transport and Diffusion in Clear Sky

  • Lee, Dong-In
    • Environmental Sciences Bulletin of The Korean Environmental Sciences Society
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    • v.4 no.4
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    • pp.263-271
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    • 2000
  • To investigate the distribution of air pollutants dispersion in the horizontal wind fields, a chaff release experiment was carried out by an airplane. The temporal and spatial variations of a chaff plume from an elevated point source using the WSR-88D(NEXRAD) radar. The observed profiles of radar reflectivity were compared with the Gaussian diffusion model at slightly unstable atmospheric condition. The present study shows that the distributions of radar reflectivity from chaffs and their concentration by the model are in general agreement with time variation. The dispersion coefficients in downwind($\sigma$(sub)x) and crosswind($\sigma$(sub)y) spread data exceeded what has generally been found at Pasquill and Brigg\`s estimates. As a result, it was clearly shown that horizontal and vertical diffusion coefficients are more accurately determined as compared with theoretical coefficients. At longer diffusion distances(than 10km), a radar observation provided the determination of maximum range and diffusion height more qualitatively, too.

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Concentration variations of gaseous pollutants at Tokchok Island from April 1999 to June 2000 (덕적도에서의 가스상 오염물질 농도 변화 특성 : 1999년 4월~2000년 6월 측정 결과 분석)

  • 김진영;김영성;이승복;진현철;문길주
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 2000.11a
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    • pp.61-62
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    • 2000
  • 중국의 풍하측에 위치한 우리나라는 대기오염물질의 장거리 이동에 의하여 많은 영향을 받고 있다 (문길주 등, 1999). 특히 황해는 중국과 한반도에 의해 삼면이 막혀있는 바다로서, 오염물질의 이동배출이 낮아 오염문제의 해결이 어려운 지역이다. 본 연구에서는 황해의 대기오염물질 이동 특성을 살펴보기 위하여 황해상의 도서지역인 덕적도에서 15개월간 측정한 가스상 오염물질 및 기상자료를 분석하였다. 덕적도는 중국의 영향뿐 아니라 한반도의 영향도 받을 수 있는 지점에 위치해 있으므로, 대기오염 농도와 오염물질 배출원과의 관련성에 주목하여 대기오염물질의 국지 배출과 외부로부터의 유입 특성을 구분하고자 하였다. (중략)

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Concentration Characteristics of Acidic Air Pollutants in the Summer and Winter Seasons (여름과 겨울철 산성오염 물질 농도 특성)

  • 이학성;강병욱;정용승;이지영;김재섭
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 2000.11a
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    • pp.127-129
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    • 2000
  • 산성오염물질과 미세입자($PM_{2.5}$)는 인체 및 생태계에 많은 악 영향을 미치고 있다. 특히 미세입자와 미세입자의 주성분인 ${SO_4}^{2-}$, ${NO_3}^{-}$, ${NH_4}^{+}$, 원소탄소(EC), 유기탄소(OC)는 호흡기 계통의 질병 및 시정장애에 커다란 영향을 미치는 것으로 알려지고 있다(Pope et al., 1995; Reichhardt, 1995; Chow et al., 1993; Conner et al., 1991; Spongier et al., 1990). 미세입자는 연소과정에서 직접 배출되거나 대기 중에서 응집, 휘발성 물질의 응축, 가스에서 입자로의 전환 등에 의하여 이차 입자상 물질로 생성된다(Seinfeld, 1986). (중략)

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Variability of the PM10 Concentration in the Urban Atmosphere of Sabah and Its Responses to Diurnal and Weekly Changes of CO, NO2, SO2 and Ozone

  • Wui, Jackson CHANG Hian;Pien, CHEE Fuei;Kai, Steven KONG Soon;SENTIAN, Justin
    • Asian Journal of Atmospheric Environment
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    • v.12 no.2
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    • pp.109-126
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    • 2018
  • This paper presents seasonal variation of $PM_{10}$ over five urban sites in Sabah, Malaysia for the period of January through December 2012. The variability of $PM_{10}$ along with the diurnal and weekly cycles of CO, $NO_2$, $SO_2$, and $O_3$ at Kota Kinabalu site were also discussed to investigate the possible sources for increased $PM_{10}$ concentration at the site. This work is crucial to understand the behaviour and possible sources of $PM_{10}$ in the urban atmosphere of Sabah region. In Malaysia, many air pollution studies in the past focused in west Peninsular, but very few local studies were dedicated for Sabah region. This work aims to fill the gap by presenting the descriptive statistics on the variability of $PM_{10}$ concentration in the urban atmosphere of Sabah. To further examine its diurnal and weekly cycle pattern, its responses towards the variations of CO, $NO_2$, $SO_2$, and ozone were also investigated. The highest mean value of $PM_{10}$ for the whole study period is seen from Tawau ($35.7{\pm}17.8{\mu}g\;m^{-3}$), while the lowest is from Keningau ($31.9{\pm}18.6{\mu}g\;m^{-3}$). The concentrations of $PM_{10}$ in all cities exhibited seasonal variations with the peak values occurred during the south-west monsoons. The $PM_{10}$ data consistently exhibited strong correlations with traffic related gaseous pollutants ($NO_2$, and CO), except for $SO_2$ and $O_3$. The analysis of diurnal cycles of $PM_{10}$ levels indicated that two peaks were associated during the morning and evening rush hours. The bimodal distribution of $PM_{10}$, CO, and $NO_2$ in the front and at the back of ozone peak is a representation of urban air pollution pattern. In the weekly cycle, higher $PM_{10}$, CO, and $NO_2$ concentrations were observed during the weekday when compared to weekend. The characteristics of $NO_2$ concentration rationed to CO and $SO_2$ suggests that mobile sources is the dominant factor for the air pollution in Kota Kinabalu; particularly during weekdays.

Distribution of Airborne Hexavalent Chromium Concentrations in Large Industrial Complexes in Korea

  • Kang, Byung-Wook;Lee, Hak-Sung;Kim, Jong-Ho;Hong, Ji-Hyung;Kim, Rok-Ho;Seo, Young-Kyo;Han, Jin-Seok;Baek, Kyung-Min;Kim, Min-Ji;Baek, Sung-Ok
    • Asian Journal of Atmospheric Environment
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    • v.10 no.4
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    • pp.208-216
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    • 2016
  • This paper reports the results of a field evaluation which used sampling and analytical methods to determine the levels of airborne hexavalent chromium Cr(VI) in major industrial complexes in Korea over a seven year period (2007-2013). Cr(VI) concentrations were determined using cellulose filter sampling and ion chromatography analysis. In order to validate the analytical performance of these methods, studies were also carried out to investigate data quality control (QC) parameters, such as the method detection limit (MDL), repeatability, and recovery efficiencies. The average concentrations of Cr(VI) for the nine industrial complexes in Korea were in the range of 0.09 to $1.40ng/m^3$, which is similar to of the concentrations in other industrial areas around the world. The impacts of Cr(VI) emissions from industrial areas on Cr(VI) concentrations in neighboring-residential areas were considerably low, and the dispersion of Cr(VI) from industrial areas to residential areas was estimated to be 'not-significant'. Cr(VI) levels were not affected by seasonal variation, which suggests that chromium was emitted continuously from the industrial sources throughout the year. The concentration of Cr(VI) measured accounted for 0.7 to 9.4 percent of the total chromium level, which is a low percentage compared to those in other urban areas around the world. This is the first report in an international journal of a field study conducted in Korea to determine the concentration of Cr(VI) in the ambient air of industrial and residential areas.

A Comparative Study on the Ambient Air Quality Standard Strength among Korea, the U.S.A. and the EU (우리나라, 미국 및 유럽의 대기환경기준 강도에 관한 비교 연구)

  • Park, Min-Bin;Lee, Tae-Jung;Lee, Eun-Sun;Kim, Dong-Sool
    • Journal of Korean Society for Atmospheric Environment
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    • v.32 no.6
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    • pp.559-574
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    • 2016
  • Based on air quality monitoring data ('10~'14) of Suwon City provided by the Korean Department of Environment, a fundamental statistic for 5 criteria pollutants such as $SO_2$, CO, $NO_2$, $O_3$, and $PM_{10}$ was initially investigated. The purpose of this paper was to review the ambient air quality standards(AAQS) of Korea, the U.S.A. and the EU and further to assess the degree of standard strength by the achievability of the AAQS comparing each national standard. Since the level and the way of standards for each air pollutant are various among countries, it is difficult to determine the degree of relative attainment using the same set of data above. Further when all the areas having bad air quality for a specific pollutant are classified as non-attainment case, it is more difficult to assess the degree of standard strength. Thus we introduced a new concept called the average concentration distance (ACD) to quantitatively estimate the strength. As results, the Korean 1-hr $NO_2$ AAQS is slightly stronger than the US standard and weaker than the EU standard. The Korean $O_3$ standard is strongest; however, the Korean $PM_{10}$ standard is weakest. Furthermore the equivalent levels of 8-hr $O_3$ standards in the U.S.A. and the EU were respectively estimated as 97.5 and 95.7 percentiles of the Korean standard with maintaining the existing standard of 60 ppb.

The Study on the Comparison of the ISCST3 Model and Receptor Model by Dispersion Tracing of Particulate Matter from Large Scale Pollution Sources (대단위배출원에서 기인한 입자상오염물질의 확산ㆍ추적을 통한 ISCST3모델과 수용모델의 비교연구)

  • 전상기;이성철;박경선
    • Journal of Korean Society for Atmospheric Environment
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    • v.19 no.6
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    • pp.789-803
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    • 2003
  • The purpose of this study is to compare the usefulness between Gaussian dispersion model and receptor model with the experimental result of the dispersion tracing of the particulate pollutants from Taean coal-fired power plants. For this purpose, the component analysis of the collected PM 10 samples was performed. In order to trace the pollution sources, factor analysis was done with the result of the component analysis. As a result of the correlativity analysis of the fifteen power plants' profiles offered by US EPA, the correlativity of No.11202 source profile showed highest rate up to 84.5%. Thus it was adopted as proper one and the contribution rate by each pollution source was calculated by Chemical Mass Balance (CMB)-8 model. The contribution rate, which was the effect rate of the power plants on each measuring point, were calculated with a range of 24∼52% and the standard error was below 0.9 $\mu\textrm{g}$/㎥. This indicates the selection of the source profile was appropriate. Also, the concentrations of each point were calculated by the ISCST3 which is suggested by US EPA as one of the regulatory Gaussian dispersion model. The calculation result showed that the predicted concentration was 50∼58 $\mu\textrm{g}$/㎥, comparing with the measured result of 9∼65 $\mu\textrm{g}$/㎥. It was found that the concentration calculated by ISCST3 was underpredicted. It was thought that the receptor model was more favorable than the Gaussian dispersion model in estimating the effect of the particulate matter on a certain receptive point.

Source Tracking of PCDD/Fs in Ambient Air Using Pine Needles (소나무 잎을 이용한 대기 중 다이옥신/퓨란 발생원 추정)

  • Chun, Man-Young;Kim, Jeong-Soo;Koh, Doh-Yun
    • Journal of Environmental Health Sciences
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    • v.41 no.1
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    • pp.49-60
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    • 2015
  • Objectives: Pine needles were used as a passive air sampler (PAS) of atmospheric persistent organic pollutants (POPs). This study was performed to investigate concentrations of polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs) deposited on pine needles near a waste incinerator and PCDD/Fs source contributions using principal component analysis (PCA). Methods: Two-year-old pine needles were sampled at 11 points with respect to distance and wind direction from the incinerator. PCDD/Fs deposited on pine needles were analyzed with HRGC/HRMS. The source contribution of PCA was calculated with SPSS. Results: The average concentration of PCDD/Fs deposited on pine needle was 0.79 (0.27-1.76) pg TEQ/g dry, PCDDs with 0.24 (0.01-0.95) pg TEQ/g dry and PCDFs with 0.56 (0.27-0.82) pg TEQ/g dry, respectively. The average concentration fraction of PCDDs was 29.7%, that of PCDFs was 70.3%, and PCDFs were more prevalent than PCDDs. The contributions of PCDD/Fs sources were estimated as incineration at 58.3% and automobiles at 28.4%. However, a relation and regulation between PCDD/Fs concentrations deposited on pine needles and distance from incinerator or wind direction was not shown. Conclusion: It was concluded that atmospheric PCDD/Fs concentrations near an industrial complex with a waste incinerator were affected by multiple sources. However, PCDD/Fs concentrations were lower than in other inland cities with the exception of background area.

Heavy Metals in Ambient Air at Shinchon Area in Seoul (도시 대기중 중금속에 관한 연구 -서울시 신촌지역을 중심으로-)

  • Chung, Yong;Jang, Jae-Yeon;Chu, Ui-Jo
    • Journal of Korean Society for Atmospheric Environment
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    • v.3 no.2
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    • pp.18-26
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    • 1987
  • In order to investigate the character of air pollution by heavy metals and to elucidate the possible sources in Seoul city, this study was performed to measure the concentrations of heavy metals of total suspended particulate and air pollutants such as $SO_2, NO_2, CO, CH_4$, Non-methane hydrocarbon, ozone at the residential-traffic area (shinchon dong) in January and February, 1986. The results are as follows: 1. $SO_2$ and TSP concentration were 135ppb and 167 $\mug/m^3$ in average, respectively. 2. While concentrations of heavy metals such as Fe, Cu, Pb in the ambient air seems gradually decreasing annually, Ni compound has been shown the tendency of increasing. 3. Among heavy metals in TSP analysed, the iron was detected at the highest level, 0.905% and the cadimium was the lowest 0.004% in average, respectively. 4. V, Fe and Zn compounds in air were observed to be highly correlated with their correlation coefficients(r) higher than 0.7. Pb compound was highly correlated to the levels of Zn and Fe, however relatively less correlated to V compound. 5. Among concentrations of heavy metals in the particulates, V and Ni compounds were highly correlated with coefficient(r) of 0.8587; the cause might be imagined by the fact of releasing from combustion of fuel oil. Fe, Pb and Zn compounds were highly correlated $SO_2$ concentration. It might be explained that they were released by combustion of coal. 6. The level of $SO_2$ was highly correlated to most of heavy metals: especially correlation coefficient(r) to Pb compound was 0.9081. Pb compound was also highly correlated to NO, CO and TSP. TSP showed higher correlation to Pb and Cd compounds than to V and Ni compounds. It might be assumed that particulate was mainly produced by combusting coal from space heating and by exhausting gasoline and diesel oil from transportation rather than by burning fuel oil.

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Aerosol Characteristics at Tokchok Island in the Yellow Sea (황해상 덕적도의 대기 에어로졸 특성)

  • 이승복;배귀남;김용표;진현철;윤용석;문길주
    • Journal of Korean Society for Atmospheric Environment
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    • v.18 no.4
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    • pp.305-316
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    • 2002
  • Various air pollutants were measured at Tokchok Island in the Yellow Sea that is about 50 km distant from Incheon since April 1999. This study was undertaken to help understanding the level of air pollution and its distribution characteristics over the Yellow Sea. The geographical characteristics of the air pollution monitoring station and emission inventories of Tokchok Island are introduced. The mass concentrations and chemical compositions of TSP and P $M_{2.5}$ measured until March 2000 are discussed in this paper. The overall average mass concentrations are about 37.2 $\mu\textrm{g}$/㎥ for TSP and 18.7 $\mu\textrm{g}$/㎥ for P $M_{2.5}$ , respectively, which are similar to or a little lower than the values observed in other background sites at Kangwha and Taean. However, they are much lower than those observed at Qingdao in China. The low mass concentration and major anthropogenic ion concentrations in aerosols collected at Tokchok Island show that local sources are not dominant at Tokchok Island. The estimated average fractions of anthropogenic non-sea-salt sulfate to the total sulfate concentration of TSP and P $M_{2.5}$ are greater than 80% for both sizes. It hence suggests that the sulfate be mainly affected by anthropogenic sources. If we consider the average mass ratio of P $M_{2.5}$ to TSP, the mass fractions of anthropogenic species to P $M_{2.5}$ , and the molar ratio of nss S $O_4$$^{2-}$ to total N $O_{3-}$, it may be possible to infer that a part of anthropogenic species measured at Tokchok Island be transported from China. The characteristics of neutralization of nss S $O_4$$^{2-}$ and the particle size of major ions are also discussed.