• Title/Summary/Keyword: Atmospheric particles

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Chemical characteristics of atmospheric particulate species in Mt. Soback, Korea(II):The sources and seasonal variations of metallic elements (소백산 대기 중 입자상 물질의 화학적 특성에 관한 연구(II):금속 원소의 계절적인 변화와 기원을 중심으로)

  • 최만식;이선기;최재천;이민영
    • Journal of Korean Society for Atmospheric Environment
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    • v.11 no.2
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    • pp.191-198
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    • 1995
  • In order to evaluate the distribution and behaviour of atmospheric particulate metals in high-altitude area, we collected 22 aerosol samples using a high volume air sampler at Soback Mt. Meteorological Observation Station from Jan. to Nov. 1993 and analysed for metals (Al, Fe, Mg, Na, Ca, Mn, Co, Ni, Cu, Zn, Cd, and Pb) with ICP/AES and ICP/MS. Although sampling site is located in high-altitude and far from local sources of atmospheric pollutants, enrichments of metals are 2 times higher than those of western coastal reural area. This fact may imply that of metallic pollutants in the coastal rural site were came from further western side (e.g. China), atmospheric metals in this study area contain the signal of metropolitan cities located in the main wind direction (NNW). Sea salts are negligible in the aerosol particle population because reference elements of sea salts (Na, Mg) are all originated from soil particles. The contents of soil particles in aerosols are highest in spring and lowest in winter. Atmospheric enriched elements (Ni, Cu, Zn, Cd and Pb) are diluted with soil particles, especially during the yellow sand period. The results of factor analysis suggest possibility of interpreting their chemical significance in terms of sources (soil, pollutants) and gas-particle conversion processes (formation of ammonium sulfates, ammonium nitrates and/or their mixtures).

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Single Particle Characterization of Aerosol Particles Collected at Jeju Island, Korea, During 'ACE-Asia' Intensive Observation Period, Using Low-Z Particle Electron Probe X-ray Microanalysis (Low-Z Particle Electron Probe X-ray Microanalysis법을 이용한 2001년 ACE-Asia 집중 측정 기간 중 제주도 고산에서의 입자상 물질의 특성분석)

  • An Yong Hoon;Kim HyeKyeong;Ro Chul-Un
    • Journal of Korean Society for Atmospheric Environment
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    • v.20 no.6
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    • pp.811-821
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    • 2004
  • Low-Z particle electron probe X-ray microanalysis (low-Z particle EPMA) was applied to characterize aerosol particles collected at Gosan in Jeju island during an IOP (intensive observation period) for an international ACE-Asia project in April, 2001. Various types of atmospheric particles such as organics, carbon-rich, aluminosilicates, silicon oxide, sodium nitrate, sodium chloride, and ammonium sulfate were observed. The reacted sea salt particles such as sodium nitrate were the most abundantly encountered, but original sea salt particles were rarely observed. Since the Low-Z particle EPMA can provide quantitative information on the chemical composition of aerosol particles, many different particle types on the basis of their chemical compositions were observed and identified. In this study, it is demonstrated that the Low-Z particle EPMA can provide detailed information on the chemical compositions for the aerosol particles collected for six consecutive days in April, 2001, at Gosan super-site.

Review of Viscosities and Phases of Biogenic Secondary Organic Aerosols (생물기원 이차유기에어로졸의 점성도와 상 규명에 관한 최근 연구 동향)

  • Song, Mijung
    • Journal of Korean Society for Atmospheric Environment
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    • v.32 no.4
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    • pp.349-359
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    • 2016
  • Researchers have traditionally assumed that aerosol particles containing secondary organic aerosols (SOAs) are to be in liquid state with low viscosity even at low relative humidity. However, recent measurements showed that SOAs can have high viscosity under certain conditions. Herein, new different techniques for measurements of viscosities of SOA particles are introduced. Moreover, laboratory studies for the viscosities and the phases of biogenic SOAs produced by ${\alpha}$-pinene, isoprene, limonene, and ${\beta}$-caryophyllene of atmospheric relevance are reviewed. Future studies for determination of the phases of atmospheric aerosol particles are also suggested.

Experimental Study on Saltation of Sand Particles Located behind Porous Wind Fences (바람에 의한 야적모래입자의 비산에 관한 실험적 연구)

  • Park, Ki-Chul;Lee, Sang-Joon
    • Proceedings of the KSME Conference
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    • 2000.04b
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    • pp.740-745
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    • 2000
  • Effects of porous fences on the wind erosion of sand particles from a triangular pile were investigated experimentally. The porous fence and sand pile were installed in a simulated atmospheric boundary layer. The mean velocity and turbulent intensity profiles measured at the sand pile location were well fitted to the atmospheric boundary layer over the open terrain. Particle motion was visualized to see the motion of windblown sand particles qualitatively. In addition, the threshold velocity were measured using a light sensitive video camera with varying the fence porosity ${\varepsilon}$. As a result, various types of particle motion were observed according to the fence porosity. The porous wind fence having porosity ${\varepsilon}=30%$ was revealed to have the maximum threshold velocity, indicating good shelter effect for abating windblown dust particles.

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Micro-PIXE as a Technique for Multi-elemental Detection and Localization in Various Atmospheric Environmental Samples

  • Ma, Chang-Jin;Choi, Sung-Boo
    • Journal of Korean Society for Atmospheric Environment
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    • v.24 no.E1
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    • pp.54-62
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    • 2008
  • Microbeam PIXE, often called micro-PIXE, is one of powerful tools for analyzing a wide range of elements for various samples. Moreover, it has important applications of interest to the atmospheric science. In the present study, a qualitative elemental imagination for various atmospheric environmental species was attempted using micro-PIXE. Especially, in combination with a novel individual droplet collection method and the micro-PIXE analytical technique, the chemical specification of various individual atmospheric samples could be carried out. Here, we briefly introduce the results of an application of micro-PIXE to the study of atmospheric environment. The detailed spatial resolution of multiple elements for various samples like individual ambient particles, individual raindrops, individual fog droplets, and individual snow crystals could be successfully achieved by scanning 2.6 MeV $H^+$ micro beam ($1{\sim}2{\mu}m$) accelerated by 3 MeV single-end accelerator.

Measurement of Insoluble Mineral Particles in a Saturated Atmosphere

  • Ma, Chang-Jin;Choi, Sung-Boo
    • Journal of Korean Society for Atmospheric Environment
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    • v.24 no.E1
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    • pp.44-53
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    • 2008
  • This study was undertaken to measure the properties of individual mineral particles in an artificially saturated atmosphere at a vertical extinct mine with 430 m height. By synchrotron radiation X-ray fluorescence (SR-XRF) microprobe analysis, it was possible to determine the elemental composition of residual insoluble particles on individual cloud droplet replicas formed on the Collodion film. The XRF visualized elemental maps enabled us not only to presume the chemical mixing state of particles retained in cloud droplet, but also to estimate their source. Details about the individual mineral particles captured by artificial cloud droplets should be helpful to understand about the removal characteristics of dust particles such as interaction with clouds. Nearly all individual particles captured in cloud droplets are strongly enriched in Fe. Mass of Fe is ranged between 41 fg and 360 fg with average 112 fg. There is a good agreement between single particle analysis by SR-XRF and bulk particle analysis by PIXE.

Major Factors Affecting PM2.5 Water Content in Seoul and Gosan (서울과 고산의 미세입자 수분함량에 영향을 미치는 주요 인자)

  • Choi E. K;Kim Y.P
    • Journal of Korean Society for Atmospheric Environment
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    • v.20 no.6
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    • pp.803-810
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    • 2004
  • Water contents in fine particles at Seoul and Gosan are estimated by using a gas/particle equilibrium model, SCAPE (Simulating Composition of Atmospheric Particles at Equilibrium). Also, sensitivity of particulate inorganic ionic concentrations on the total ionic species is estimated. Water content at Gosan is more sensitive to ambient relative humidity (RH) than Seoul. At both sites water content is most sensitive to sulfate concentration among sulfate, nitrate, and ammonium. Solid salts levels and compositions are also studied.

Experimental Study on Brownian Coagulation in the Transition Regime (전이영역에서의 Brown 응집에 관한 실험적 연구)

  • Kim Dae-Seong;Lee Gyu-Won
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 2003.05b
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    • pp.355-356
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    • 2003
  • Coagulation is a process whereby particles collide with one another due to their relative motion, and adhere to form large particles. Coagulation caused by the random Brownian motion of particles is called Brownian coagulation. Many properties, such as light scattering, electrostatic charges, toxicity, as well as physical processes, including diffusion, condensation and thermophoresis depend strongly on their size distribution. Therefore, Brownian coagulation is substantially important in atmospheric science, combustion technology, inhalation toxicology and nuclear safety analysis. (omitted)

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Estimation of water content and strong acideity of ambient particles in Seoul (서울지역 입자의 수분함량 및 강산성도 예측)

  • 김진영;김용표;심상규;문길주;천만영;김희강
    • Journal of Korean Society for Atmospheric Environment
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    • v.11 no.1
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    • pp.69-76
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    • 1995
  • Water content and strong acidity are estimated for ambient particles measured between Fall, 1991 and Summer, 1992 in Seoul using a gas/aerosol equilibrium model, called SCAPE. Particle water content and formation of solid species are closely related to ambient relative humidity and ionic concentrations. Generally, water content of particles is high during the night and summer. Estimated particle strong acidity level of Seoul is similar to that of Los Angeles, U.S.A. Acidity of wet and dry depositions in Seoul is discussed.

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