• 대한기계학회논문집B
• /
• 제34권2호
• /
• pp.121-127
• /
• 2010

추가적인 챔버를 필요로 하지 않는 로 내 탈황 기술은 순산소 연소 기술에 적용 가능할 것으로 기대되어 많은 연구가 진행중이다. 이때, 수 나노부터 수십 마이크로미터의 넓은 사이즈 분포를 가지는 $CaCO_3$ 입자가 흡착제로써 사용된다. 본 연구에서는 순산소 연소 시스템을 모사하는 랩스케일의 실험 장치를 구축하였다. $CaCO_3$ 흡착제 입자는 $1200^{\circ}C$로 설정된 고온 반응로에 각각 공기 분위기와 CO2 분위기에서 노출되게 된다. 이때 고온 반응로에서의 체류 시간을 0.33 ~ 1.46 초로 변화시켜 가면서 분석을 수행하였다. 흡착제 입자는 고온 반응로의 전단과 후단에서 각각 포집되어 주사형 이동도 입자계수기, X-선 회절장치, 열중량 분석기, 주사전자현미경 등을 사용하여 정성적/정량적으로 분석하였다. 결과적으로, 고온 반응로에서의 체류 시간과 분위기 기체성분이 흡착제 입자의 하소 반응률, 반응 메커니즘 등에 영향을 미침을 확인하였다.

• 한국대기환경학회지
• /
• 제26권5호
• /
• pp.533-542
• /
• 2010

The $PM_{10}$ concentrations in the underground should be monitored for the health of commuters on the underground subway system. Seoul Metro and Seoul Metropolitan Rapid Transit Corporation are measuring several air pollutants regularly. As for the measurement of $PM_{10}$ concentrations, instruments based on $\beta$-ray absorption method and gravimetric methods are being used. But the instruments using gravimetric method give us 20-hour-average data and the $\beta$-ray instruments can measure the $PM_{10}$ concentration every one hour. In order to keep the $PM_{10}$ concentrations under a healthy condition, the air quality of the underground platform and tunnels should be monitored and controlled continuously. The $PM_{10}$ instruments using light scattering method can measure the $PM_{10}$ concentrations every less than one minute. However, the reliability of the instruments using light scattering method is still not proved. The purpose of this work is to study the reliability of the instruments using light scattering method to measure the $PM_{10}$ concentrations continuously in the underground platforms. One instrument using $\beta$-ray absorption method and two different instruments using light scattering method (LSM1, LSM2) were placed at the platform of the Jegi station of Seoul metro line Number 1 for 10 days. The correlation between the $\beta$-ray instrument and the LSM2 ($r^2$=0.732) was higher than that between the $\beta$-ray instrument and the LSM1 ($r^2$=0.393). Thus the LSM2 was chosen for further analysis. Three different regression analysis methods were tested: Linear regression analysis, Nonlinear regression analysis and Orthogonal regression analysis. When the instruments using light scattering method were used, the data measured these instruments have to be converted to actual $PM_{10}$ concentrations using some factors. With these analyses, the factors could be calculated successfully as linear and nonlinear forms with respect to the data. And the orthogonal regression analysis was performed better than the ordinary least squares method by 28.45% reduction of RMSE. These findings propose that the instruments using light scattering method light scattering method can be used to measure and control the $PM_{10}$ concentrations of the underground subway stations.

• 한국대기환경학회지
• /
• 제2권1호
• /
• pp.11-21
• /
• 1986

The study was performed to investigate the effects of gaseous imission of sulfur dioxide and hydrogen fluoride on the growth of rice plant under stressed field conditions. The plants were cultivated in normal paddy fields where are 88 industrial plants operating with 285 smoke stacks emitting pollutants. There has been a number of reported studies (1, 3, 11, 19, 20) which deal with rice plant damages by air pollution under a simulated exposure experimental condition. Furthermore, these experiments were conducted to examine effects of a single pollutant on the plant. Furthermore, these experiments were conducted to examine effects of a single pollutant on the plant. In korea, however, there is no study reported in literature with respect to the in-situ dose-response relationship between rice pant reduction in yields and air pollution. This study is specifically dealt with multiple effects of sulfur dioxde and hydrogen fluoride on various plant growth indicators such as leaf damage, culm height, weight of grain, panicles per hill, spikelets per panicle and percent fertility.It appears that there is a good correlation between ambient concentrations of sulfur oxides and sulfur contents found in leaves with an average correlation coefficient of 0.868 within a 1% significance level. It is interesting to note that a better multiple correlation was found between percent leaf damage and sulfur and fluoride contentd found in leaf with a significance of 1% level. The yearly correlation coefficient ranges from 0.963 to 0.987 with an average being 0.971. It is, therefore, believed that a percent leaf damage may serve as a single indicator of pollutional damages to rice plant cultivating in fields. Regarding other factors to the diminution of rice plant growth in polluted atmosphere, it appears that a significant correlation to culm length and dry weight of grain with a 1% significance level whereas T/R ratio has a good correlation with lead damage within 5% significance level. An evaluation of data observed has demonstrated that both panicles per hill and percent fertility are significantly affected by air pollutants. As expected, hydrogen fluoride has more effects than sulfur oxide. It is, however, interesting to note that spikelets per panicles has slightly been affected while no indication of effects on 1000-grain-weight has been observed. This may lead to a conclusion that a reduction in yield of rice under polluted field conditions may have more been caused by the diminution of panicles per hill and percent fertility rather than by the diminution of spikelets per panicle and grain weight.

• 한국대기환경학회지
• /
• 제33권2호
• /
• pp.87-96
• /
• 2017

In this study, 4 gases containing typical chlorinated volatile organic compounds (VOCs) were treated by ultraviolet (UV) irradiation. The typical chlorinated VOCs are dichloromethane (DCM), trichloromethane (TCM), carbon tetrachloride (CTC) and trichloroethylene (TCE). The removal efficiency (RE) and the products of chlorinated VOCs by UV irradiation are investigated. At this time, 2 types of background gas (air and nitrogen) were used to figure out the RE by photooxidation and photolysis. The specification of UV-lamp used in this study was low-pressure mercury lamp emitting wavelength of 185~254 nm. The experimental conditions were set as initial VOC concentration of $180{\pm}10ppm$, empty bed retention time (EBRT) of 53 s, temperature of $23{\pm}2^{\circ}C$ and relative humidity of $65{\pm}5%$. In the photolysis condition with nitrogen ($N_2$) as background gas, the averaged RE of the 4 types of chlorinated VOCs was about 24% higher than that with photooxidation; and the REs of VOCs except CTC were confirmed as >99%. The composition of off-gases after UV photooxidation in air was investigated and several intermediates from DCM, TCM and TCE were detected by GC/MS. Among them, phosgene which is a toxics was detected as an intermediate of TCM. In addition, the concentration of carbon dioxide ($CO_2$) in the off-gases was measured to calculate the mineralization rate (MR). With the photooxidation, TCE showed the highest RE (>99%) while MR was the lowest (17%); and the MR of DCM was the highest (86%). In addition, particulate matters (PM) in the off-gases was also detected and high concentrated $PM_{10}$ ($21,580{\mu}g{\cdot}m^{-3}$) and $PM_{2.5}$ ($6,346{\mu}g{\cdot}m^{-3}$) were detected in TCE off-gas. More than 99% of the chlorinated VOCs could be removed using UV254-185 nm lamp, while it is necessary to conduct further studies on the production and treatment of secondary pollutants.

• 대한원격탐사학회지
• /
• 제33권3호
• /
• pp.301-311
• /
• 2017

에어로솔의 광학특성과 연직고도는 태양 복사의 반사와 흡수과정을 통하여 지구복사수지에 영향을 미치게 된다. 본 연구에서는 복사전달모델과 위성관측자료를 이용하여 동북아시아 지역에서 구름의 존재 시 에어로솔 층에 의한 복사특성을 분석하였다. 복사전달 모의 결과는 구름이 하부에 존재하는 경우에 에어로솔 층의 고도가 높아짐에 따라 대기 온난화 효과가 증가하였다. 이러한 관계는 에어로솔의 광 흡수성이 커질수록, 지표 반사도가 증가할수록 비례하는 경향을 나타내었다. 그리고 연구대상지역 ($20-50^{\circ}N$, $110-140^{\circ}E$)에서 주요 에어로솔 이벤트 사례에 대하여, UV Absorbing Aerosol Index (AAI) derived from Total Ozone Mapping Spectrometer (TOMS), cloud parameters derived from the Moderate Resolution Imaging Spectro-radiometer (MODIS), with Upward Shortwave Flux (USF) Clouds and the Earth's Radiant Energy System (CERES) 위성관측자료를 이용하여 광 흡수성 에어로솔에 의한 영향을 정량적으로 분석하였다. 각 사례에 대한 평균적인 복사효과는 약 6 - 26 %에 해당하는 상향 단파 복사량의 감쇄효과가 나타났다. 이러한 결과는 에어로솔에 의한 직접효과와 간접효과를 정량화 하기 위한 중요성을 설명해 준다.

• Journal of the Korean Data and Information Science Society
• /
• 제20권6호
• /
• pp.1085-1092
• /
• 2009

지표오존 농도는 국가의 중요한 환경 척도 중의 하나이다. 본 연구에서는 경기도 파주시 오존농도를 자기회귀오차모형과 신경망모형으로 분석하였다. 오존 분석을 위한 설명변수로는 이산화황, 이산화질소, 일산화탄소, 프로메툼10 등의 대기자료와 일 최고온도, 풍속, 상대습도, 강수량, 이슬점온도, 운량, 수증기압 등의 기상자료를 사용하였다. 분석 결과 전반적으로 신경망모형이 좋은 모형으로 나타났고, 자기회귀오차모형도 오존에 영향을 주는 설명변수를 첨가하면 좋은 모형이 될 것으로 생각된다.

• 한국초지조사료학회지
• /
• 제21권4호
• /
• pp.217-224
• /
• 2001

In order to identify the growth characterization, the yield and chemical composition of Jeju barnyard grass (Echinochloa crusgalli var. fiurnentacea(Roxb) Wight) based on seeding date in Jeju region, seeding carried out the 10-day intervals from March 27 to September 30 in 2000, respectively. Plant height was 143.2 cm, showing the highest on seeding date, April 6 among that of any other seeding date. On the other hand, those of early and late seeding gradually decrease. Plant height was 119.2 an in May 16 seeding. The results of stem diameter, number of withering leaves, number of leaves and fresh weight per plant were similar to those of the plant heights. The yield of fresh, dry matter forage, crude protein and TDN found the highest on April 6 seeding, 63.5 MT/ha, 13.9 MTha, 1.1 MT/ha, and 7.6 MT/ha, respectively. In early and late seeding, the yield was gradually decreased. In seeding May 16, the yield found .38.2 MTIha in fresh forage, 6.2 MTha in dry matter forage, 0.7 MT/ha in crude protein and 3.7 MTha in TDN, respectively. According to delaying the seeding date, March 27 to May 16, the contents of crude protein (from 7.9 to 10.8%), ether extract (from 4.6 to 6.0%), nitrogen free extract (from 45.1 to 46.5%), and TDN (from 54.2 to 60.8%) were gradually increased, respectively. On the other hand, those of crude fiber (from 28.9 to 25.6%) and crud ash (from 13.5 to 11.2%) were decreased. These results showed that April 6 was the optimum seeding date with the sole object of feed production of Jeju barnyard grass under the environmental condition like as atmospheric phenomena and soil in Jeju region. (Key words : Jeju barnyard grass, Seeding date, Forage yield, Chemical composition)

• Transactions on Electrical and Electronic Materials
• /
• 제5권5호
• /
• pp.204-207
• /
• 2004

In this work, we present the electrochemical properties of Al bipolar plate, which can be re-searched for the application of PEMFC system. Bulk resistance of the plate was measured with a four-point probe method. The electrical conductivity of noble metal coated Al plate was 4.40 x 10$^4$ S/cm. On the other hand, the electrical interfacial resistance of the noble metal coated Al plate valued at 0.15 mΩ-$\textrm{cm}^2$ and that of graphite was 0.26 mΩ-$\textrm{cm}^2$ under the holding pressure of 140 N/$\textrm{cm}^2$ at the applied current of 5 A. And the performance of Al bipolar plate for PEMFC was evaluated at various conditions. The single cell performance was more than 0.43 W/$\textrm{cm}^2$ (0.47 Wig) for noble metal coated Al bipolar plate at 5$0^{\circ}C$ under atmospheric pressure in external humidified hydrogen and oxygen condition. As the present results, we could show the results that the noble metal coated Al bipolar plates were favorable in the aspect of electrical properties compared with those of the commercialized resin-impregnated graphite plates.

• 한국결정성장학회지
• /
• 제10권1호
• /
• pp.5-12
• /
• 2000

Silicon carbide(SiC)는 뛰어난 전기적, 열적, 물리적 특성 때문에 내환경 전자소자용 반도체 재료로 널리 연구되고 있다. 본 연구에서는 화학기상증착법으로 단결정 6H-SiC 동종박막을 성장시키고 이의 성장 특성을 조사하였다. 특히, 몰리브덴 (Mo)-plate를 이용하여 SiC를 코팅하지 않은 graphite susceptor를 사용한 6H-SiC 동종박막 성장조건을 성공적으로 얻었다. 대기압 상태의 RF-유도가열식 챔버에서 CVD성장을 수행하였고, <1120> 방향으로 $3.5^{\circ}$off-axis된 기판을 사용하였다. 성장 박막의 결정성을 평가하기 위하여 Nomarski 관찰, 투과율 측정 , 라만 분광, XRD, 광발광(PL) 분광, 투과전자현미경(TEM) 측 정 등의 방법을 이용하였다. 이상과 같은 실험을 통하여, 본 연구에서는 성장온도 $1500^{\circ}C$, C/Si flow ratio ($C_3H_8$ 0.2 sccm, $SiH_4$ 0.3 sccm)인 성장조건에서 결정성이 가장 좋은 6H-SiC 동종박막을 얻을 수 있었다.

• Smart Structures and Systems
• /
• 제25권1호
• /
• pp.111-122
• /
• 2020

Researchers up to date have introduced several Structural Health Monitoring (SHM) techniques with varying advantages and drawbacks for each. Satellite positioning systems (GPS, GLONASS and GALILEO) based techniques proved to be promising, especially for high natural period structures. Particularly, the GPS has proved sufficient performance and reasonable accuracy in tracking real time dynamic displacements of flexible structures independent of atmospheric conditions, temperature variations and visibility of the monitored object. Tall structures are particularly sensitive to oscillations produced by different sources of dynamic actions; such as typhoons. Wind forces induce in the structure both longitudinal and perpendicular displacements with respect to the wind direction, resulting in torsional effects, which are usually more complex to be detected. To efficiently track the horizontal rotations of the in-plane sections of such flexible structures, two main issues have to be considered: a suitable sensor topology (i.e., location, installation, and combination of sensors), and the methodology used to process the data recorded by sensors. This paper reports the contributions of the measurements recorded from dual frequency GPS receivers and uni-axial accelerometers in a full-scale experimental campaign. The Canton tower in Guangzhou-China is the case study of this research, which is instrumented with a long-term structural health monitoring system deploying both accelerometers and GPS receivers. The elaboration of combining the obtained rather long records provided by these two types of sensors in detecting the torsional behavior of the tower under ambient vibration condition and during strong wind events is discussed in this paper. Results confirmed the reliability of GPS receivers in obtaining the dynamic characteristics of the system, and its ability to capture the torsional response of the tower when used alone or when they are combined with accelerometers integrated data.