• Journal of Korean Society for Atmospheric Environment
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• v.17 no.E1
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• pp.9-16
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• 2001

To evaluate the correct separation capacity of cascade impactor for liquid aerosol, theoretical and experimental calculations of 50% cut-off diameter(ECOD(sub)50) were performed. A recalculation method of original diameter for hemispheric liquid aerosol collected on casecad impactor is also proposed newly using fixation technique. Calculated values for theoretical (ECOD(sub)50) of 40stage cascade impactor are 20, 6.4, 2.8, and 1.4$\mu\textrm{m}$ at 1st- ,2nd-, 3rd- and 4th-stage, respectively. A good agreement between the result of theoretical (ECOD(sub)50) and that og experimental ones was obtained at Stage 2 and 3. On the other hand, relatively large differences were found at Stage 1 and 4. Fixation for liquid aerosols using ${\alpha}$-cyanoacrylate monomer was performed successfully. The orignal diameter of liquid aerosols collected on each stage was calculated. The maximum levels of number size distribution curves at each stage are 19.8, 6.5, 3.1 and 1.5 $\mu\textrm{m}$ at 1st-, 2nd-, 3rd- and 4th-stage, respectively. The distortion of separation capacity of cascade impactor due to the split, merger, disappearance, and evaporation of liquid aerosols in the fluid did not occur.

• Journal of Korean Society for Atmospheric Environment
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• v.19 no.2
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• pp.167-177
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• 2003

The number size distribution of urban aerosols ranging from 0.02 to 20 ${\mu}{\textrm}{m}$ in diameter was measured by using a scanning mobility particle sizer (SMPS) system and an aerodynamic particle sizer spectrometer (APS) at Seoul from November 30,2001 to January 14, 2002. The gaseous species such as CO, NO, NO$_2$, and $O_3$ were also continuously monitored. The daily average concentration of urban aerosols sorted into three groups (0.02~0.1 ${\mu}{\textrm}{m}$, 0.1~1 ${\mu}{\textrm}{m}$ and 1~10 ${\mu}{\textrm}{m}$) and the typical number, surface, and volume distributions of urban aerosols were discussed in this paper. The weekly variation of aerosol concentration was compared with those of gaseous concentrations. relative humidity, and visibility. The results showed that the particle number concentration seemed to increase in the morning and the number concentration of fine particles less than 1 fm in diameter seemed to increase when the concentrations of CO, NO, and NO$_2$ were high. The number concentration of fine particles was relatively high when the relative humidity was greater than 70％ during the increasing period of relative humidity. The visibility was weakly correlated with the concentration of aerosols ranging 0.1 to 1 ${\mu}{\textrm}{m}$, and the number size distribution for high visibility episode was apparently different from that for low visibility episode.

• Journal of Korean Society for Atmospheric Environment
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• v.24 no.4
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• pp.470-482
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• 2008

Seasonal variations of chemical composition and optical properties of aerosols at Seoul and Gosan were investigated using the ground-based aerosol measurements and an optical model calculation. The mass fraction of elemental carbon was $8{\sim}17%$, but its contribution on light absorption was high up to $29{\sim}48%$ in Seoul. In Gosan, the contribution of water soluble aerosols on aerosol extinction was $83{\sim}94%$ due to the high mass fraction of these particles in the range of $56{\sim}88%$. Model calculation showed that the water holding capacity of aerosols was larger in Gosan than in Seoul because of higher relative humidity and temperature along with abundant water soluble aerosols. Difference between measured and calculated aerosol optical depths was the highest in summer. This was because aerosol optical depth calculated from ground-based measurements could not consider aerosol loadings at high altitude in spite of high column-integrated aerosol loadings observed by Sun photometer. Although hygroscopic growth was expected to be dominant in summer, the mass concentration of water soluble aerosols was too low to permit this growth.

• Journal of Korean Society for Atmospheric Environment
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• v.22 no.1
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• pp.1-14
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• 2006

Tropospheric aerosols are highly variant in time and space due to non-uniform source distribution and strong influence of meteorological conditions. Backscatter lidar measurement is useful to understand vertical distribution of aerosol. However, the backscatter lidar equation is undetermined due to its dependence on the two unknowns, extinction and backscattering coefficient. This dependence necessitates the exact value of the ratio between two parameters, that is, the lidar ratio. Also, Iidar ratio itself is useful optical parameter to understand properties of aerosols. Tropospheric aerosols were observed to understand variance of lidar ratio at Anmyeon island ($36.32^{/circ}N$, $126.19^{/circ}E$), Korea using a multi-wavelength raman lidar system developed by the Advanced Environmental Monitoring Research Center (ADEMRC), Gwangju Institute Science and Technology (GIST), Korea during measurement periods; March 15$\sim$April $16^{th}$, 2004 and May 24$\sim$ $8^{th}$ 2005. Extinction coefficient, backscattering coefficient, and lidar ratio were measured at 355 and 532 nm by the Raman method. Different types of aerosol layers were distinguished by the differences in the optical properties such as Angstrom exponent, and lidar ratio. The average value of lidar ratio during two observation periods was found to be $50.85\pm4.88$ sr at 355 nm and $52.43\pm15.15$ sr at 532 nm at 2004 and $57.94\pm10.29$ sr at 355 nm and $82.24\pm15.90$ sr at 532 nm at 2005. We conduct hysplit back-trajectory to know the pathway of airmass during the observation periods. We also calculate lidar ratio of different type of aerosol, urban, maritime, dust, continental aerosols using OPAC (Optical Properties of Aerosols and Clouds), Remote sensing of atmospheric aerosol using a multi-wavelengh lidar system with Raman channels is quite and powerful tool to characterize the optical propertises of troposheric aerosols.

• Journal of Korean Society for Atmospheric Environment
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• v.20 no.2
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• pp.161-174
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• 2004

Aerosol formation and growth by water vapor reactions were investigated in a 2.5 -㎥ indoor smog chamber filled with the unfiltered ambient air. The relative humidity of test ambient air was elevated at 59～64% or 84～88% by adding water vapor. The aerosol number size distribution and the concentrations of $O_3$, NO, NO$_2$, and SO$_2$ were measured during the experiments. The $O_3$ and NO$_2$ gases were well reacted with the water vapor at high relative humidity of 84～88%, and the reaction rates of these gases seemed to be decreased at low relative humidity of 59～64%. The formation and condensational growth phenomena of ambient aerosols by water vapor reactions were observed in a Teflon bag, depending strongly on the initial particle size distribution. The water vapor reactions might be affected by the contents of oxidants produced by photochemical reactions under sunlight.

• Proceedings of the KSRS Conference
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• v.2
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• pp.794-796
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• 2006

This study investigated the Brightness Temperature Difference threshold as criterion between aerosols and clouds in conjunction with radiative transfer model. Surface temperature is caused by a significant error over 50% in the BTD threshold. In addition, The BTD threshold contains the uncertainties about 20% due to the surface emissivity and 8% due to the satellite zenith angle. Therefore, we have composed the Look-up table for BTD between 11㎛and 12㎛ according to satellite zenith angle, surface temperature, and surface emissivity. The modified BTD show the enhanced signal, especially over bright surface such as desert in China. However, a weak aerosol signal over Ocean remains in the modified BTD.

• Journal of Korean Society for Atmospheric Environment
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• v.16 no.E
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• pp.19-27
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• 2000

Particle Induced X-ray Emission (PIXE) and Elemental Analysis Syztem (EAS) were applied to the investiga-tion of the Characteristics and sources of wintertime atmospheric aerosols in Seoul. Atmospheric aerosols were collected by both fine and coarse fractions using a two-stage filter pack sampler from Kon-Kuk university during the winter season of 1999. PIXE was applied to the analysis of the middle and heavy elements with atomic numbers greater than 14(Si) and EAS was applied to the measurement of the light elements such as H, C and N. The fact that 64.2% of mass of fine particles in Seoul consists of the light elements (N, C , and H) suggests that the measurement of light elements is extremely important. The average mass concentration is Seoul was 38.6$\mu\textrm{g}$m(sup)-3. Elements such as Ca, Fe, Mg, and Ti appeared to have very low Fine/Coarse ratios(0.1∼0.4), whereas che-mical components related to anthropogenic sources such as Br, V, Pb, and Zn were observed to accumulate in the fine fraction. In the Asian Dust Storm(ADS) event, the concentation of soil components increased dramatically. Reconstruction of the fine mass concentrations estimated by a newly revised simple model was fairly in good agreement with the measured ones. Source identification was attempted using the enrichment factor and Pearsons coefficient of correlation. The typical elements derived from each source could be classified by this method.

• Proceedings of the Korea Air Pollution Research Association Conference
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• 2004.11a
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• pp.457-458
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• 2004

• Proceedings of the Korea Air Pollution Research Association Conference
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• 1999.04a
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• pp.191-192
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• 1999

• Journal of Korean Society for Atmospheric Environment
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• v.24 no.2
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• pp.162-175
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• 2008

Gyeongju, which was the central city of the ancient civilization at Silla Kingdom, has various kinds of stone cultural properties. It is significantly important to preserve historical sources of Korea. However, recent air quality data measured in Gyeongju did not show good air quality level. In order to investigate variation of the concentration of the air pollutants with meteorological condition, an air quality monitoring and an aerosol sampling were conducted during the intensive monitoring period in Gyeongju. Impacts of the meteorological factors on the air pollutants were also analyzed based on the air mass pathway categories using HYSPLIT model and the local wind patterns using MM5 model. The prevailing air mass pathways were classified into four categories as following; category I affected by easterly marine aerosols, category II affected by northwesterly continental aerosols, category III affected by southwesterly continental aerosols, and category IV affected by northerly continental aerosols. The concentrations of the air quality standards were relatively lower during the fall intensive monitoring period. At that time, the easterly marine air mass pattern was dominated. The seasonal average mass concentration of $PM_{10,Opt}$, which optically measured at the monitoring site, was the highest value of $77.6{\pm}28.3\;{\mu}g\;m^{-3}$ during the spring intensive monitoring period but the lowest value of $20.1{\pm}5.3\;{\mu}g\;m^{-3}$ during the fall intensive monitoring period. The concentrations of $SO_2$ and CO were relatively higher when the air mass came from the northwestern continent or the northern continent. The concentrations of ${SO_4}^{2-}$ and ${NO_3}^-$ increased under the northwesterly continental condition. It was estimated that the acidic aerosols were dominated in the atmosphere of Gyeongju when the air mass came from the continental regions.