• Title/Summary/Keyword: Atmospheric Stability

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Evaluation of Methodology for the Measurement of VOCs in the Air by Adsorbent Sampling and Thermal Desorption with GC Analysis (흡착포집 및 열탈착/GC 분석에 의한 공기 중 휘발성 유기화합물의 측정방법론 평가)

  • 백성옥;황승만;박상곤;전선주;김병주;허귀석
    • Journal of Korean Society for Atmospheric Environment
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    • v.15 no.2
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    • pp.121-138
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    • 1999
  • This study was carried out to evaluate the performance of a sampling and analytical methodology for the measurement of selected volatile organic compounds (VOCs) in the ambient air. VOCs were determined by the adsorbent tube sampling and automatic thermal desorption coupled with GC/FID and GC/MSD analysis. Target analytes were aromatic VOCs, including BTEX, 1,3,5-and 1,2,4,-trimethylbenzenes(TMBs), and naphthalene. The methodology was investigatedwith a wide range of performance criteria such as repeatability, linearity, lower detection limits, collection efficiency, thermal conditioning, breakthrough volume and calibration methods using internal and external standards. standards. Stability of samples collected on adsorbent tubes during storage was also investigated. In addition, the sampling and analytical method developed during this study was applied to real samples duplicately collected in various indoor and outdoor environments. Precisions for the duplicate samples and distributed volume samples appeared to be well comparable with the performance criteria recommended by USEPA TO-17. The audit accuracy was estimated by inter-lab comparison of both duplicate samples and standard materials between the two independent labs. The overall precision and accuracy of the method were estimated to be within 30% for major aromatic VOCs such as BTEX. This study demonstrated that the adsorbent sampling and thermal desorption method can be reliably applied for the measurement of BTEX in ppb levels frequently occurred in common indoor and ambient environments.

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A Study on the Development of Air Pollution Dispersion Model for Personal Computer (特定地域의 大氣汚染 擴散모델 開發에 關한 硏究)

  • 송기유;임흥재;윤명희
    • Journal of Korean Society for Atmospheric Environment
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    • v.2 no.2
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    • pp.19-30
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    • 1986
  • This study was performed to develop a long-term air pollution dispersion model based on CDM program for use in the personal computer. The model CDM.PC, developmented for use of this study, simplified the plum equation of point pollution source in a windy state and sindless state. We used the classified 8 class stability, 16 wind direction and 4 class wind speed for the computer input climatological data. The plum rise equation is applied for CONCAWE's equation above 2,000 Kcal/sec of the exhaust calorie and Moses-Carson's equation below 2,000Kcal/sec at windy state, and Brigg's equation at calm. The time required is 200 minutes for drawing the air pollution contour for treating ten stacks under the above-stated conditions. It is the weakness of using personal computer that the operation time is longer than a large-size computer. But it strength is that the personal computer is used widely. To compare the treatment results of CDM.PC with TCM, we comfirmed that the shape of $SO_2$ pollution contour is similar but the concentration distribution is quite different because of characteristics of each models. Estimated and measured $SO_2$ concentration were similar, namely, Cest/Cob ratio of CDM.PC and TCM were respectively $0.96 \pm 0.25 (mean\pmS.D)$ and $1.08\pm0.26$.

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Decomposition of HFCs using Steam Plasma (스팀 플라즈마를 이용한 HFCs 분해특성)

  • Kim, Kwan-Tae;Kang, Hee Seok;Lee, Dae Hoon;Lee, Sung Jin
    • Journal of Korean Society for Atmospheric Environment
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    • v.29 no.1
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    • pp.27-37
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    • 2013
  • CFCs (Chlorofluorocarbons) and HCFCs (Hydrochlorofluorocarbons) that are chemically stable were proven to be a greenhouse gases that can destroy ozone layer. On the other hand, HFCs (Hydrofluorocarbons) was developed as an alternative refrigerant for them, but HFCs still have a relatively higher radiative forcing, resulting in a large Global Warming Potential (GWP) of 1,300. Current regulations prohibit production and use of these chemicals. In addition, obligatory removal of existing material is in progress. Methods for the decomposition of these material can be listed as thermal cracking, catalytic decomposition and plasma process. This study reports the development of low cost and high efficiency plasma scrubber. Stability of steam plasma generation and effect of plasma parameters such as frequency of power supply and reactor geometry have been investigated in the course of the development. Method for effective removal of by-product also has been investigated. In this study, elongated rotating arc was proven to be efficient in decomposition of HFCs above 99% and to be able to generate stable steam plasma with steam contents of about 20%.

Flutter Control of Flexible Structure under Random Atmospheric Disturbance (불규칙한 대기교란을 받는 유연한 구조물의 플러터 제어)

  • Oh, Soo-Young;Kim, Yong-Kwan;Cho, Kyoung-Lae;Heo, Hoon;Cho, Yun-Hyun
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2000.06a
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    • pp.1210-1215
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    • 2000
  • Investigation is performed on the stability of general form of dynamic system under colored noise random disturbance whose damping and stiffness are varying in irregular manner along time, which is a preliminary result in the course of research on the characteristic and the control of the stochastic system. Adopted physical model is airfoil under random atmospheric disturbance, which becomes a "time-varying system" whose the governing equation is derived via F-P-K approach in stochastic sense. Control performance and effect of 'Heo-stochastic controller for colored noise' is studied. Also stochastic feature of flutter boundary is discussed as well.

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A Composite of Metal and Polymer Films: Thin Nickel Film Coated on a Polypropylene Film after Atmospheric Plasma Induced Surface Modification

  • Song, Ho-Shik;Choi, Jin-Moon;Kim, Tae-Wan
    • Transactions on Electrical and Electronic Materials
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    • v.12 no.3
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    • pp.110-114
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    • 2011
  • Polymeric films of high chemical stability and mechanical strength covered with a thin metallic film have been extensively used in various fields as electric and electronic materials. In this study, we have chosen polypropylene (PP) as the polymer due to its outstanding chemical resistance and good creep resistance. We coated thin nickel film on PP films by the electroless plating process. The surfaces of PP films were pre-treated and modified to increase the adhesion strength of metal layer on PP films, prior to the plating process, by an environment-friendly process with atmospheric plasma generated using dielectric barrier discharges in air. The surface morphologies of the PP films were observed before and after the surface modification process using a scanning electron microscope (SEM). The static contact angles were measured with deionized water droplets. The cross-sectional images of the PP films coated with thin metal film were taken with SEM to see the combined state between metallic and PP films. The adhesion strength of the metallic thin films on the PP films was confirmed by the thermal shock test and the cross-cutting and peel test. In conclusion, we made a composite material of metallic and polymeric films of high adhesion strength.

One-Year Continuous Measurement of Outdoor Radon Progeny Concentration in Beijing Area

  • Zhang, Lei;Wang, Yunxiang;Guo, Qiuju
    • Journal of Radiation Protection and Research
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    • v.45 no.3
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    • pp.95-100
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    • 2020
  • Background: Compared with reported data of radon concentration, data of radon progeny concentration is limited in general, especially in outdoor environment. Materials and Methods: To know both the level and the variation of radon progeny concentration in outdoor environment in Beijing area, one-year continuous measurement with a cycle of 60 minutes was carried out by a step-advanced filter (SAF) monitor for radon progeny measurement. The observation site was located in a park in Eastern Beijing area, and the observation period was from October 17, 2018 to September 29, 2019. Results and Discussion: The equivalent equilibrium concentration (EEC) of radon progeny varies from 0.7 to 19.1 Bq·m-3, with an annual average of 4.9 ± 2.7 Bq·m-3. A clear diurnal variation of EEC, higher in the early morning and lower in the late afternoon, is observed due to the high sensitivity of the SAF monitor. Conclusion: Vertical convection of atmospheric boundary layer is thought to be the main reason of this phenomenon. For annual variation, the lowest monthly average EEC appeared in April, while the highest appeared in November, which might attribute to the atmospheric stability in different seasons.

Evaluation on Decomposition Processes of Laundry wastewater produced from Steam Generator (증기발생기 세정폐액 처리 공정 평가)

  • 강덕원;이홍주;최영우;이두호
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2003.11a
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    • pp.78-82
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    • 2003
  • For the decomposition of laundry wastewater containing Fe-EDTA produced from the steam generators in nuclear power plants, Supercritical Water Oxidation (SCWO) Process, Photocatalytic Oxidation (PO) Process, and Dielectric Barrier Discharge (DBD) Atmospheric Pressure Plasma Process were evaluated. Even though EDTA was converted over 99.98 % by the SCWO process, it was estimated that the countermeasure against corrosion of the equipment should be reinforced for the process stability. It was considered that the PO process is not appropriate for the decomposition of high concentrated laundry wastewater since the conversion ratio of EDTA was around 10 %. Finally, High efficiency of the decomposition of organic matter (methylene blue) was obtained using DBD process even low energy was supplied. However there is still room for the evaluation of EDTA decomposition in order that the DBD process should be applied for the field samples.

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Comparison of Development Mechanisms of Two Heavy Snowfall Events Occurred in Yeongnam and Yeongdong Regions of the Korean Peninsula (영동과 영남 지역에서 발생한 두 대설의 발달 메커니즘 비교)

  • Park, Ji-Hun;Kim, Kyung-Eak;Heo, Bok-Haeng
    • Atmosphere
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    • v.19 no.1
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    • pp.9-36
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    • 2009
  • Two heavy snowfall events occurred in Yeongnam and Yeongdong regions of the Korean Peninsula during the period from 4 to 6 March 2005 are analyzed. The events were developed by two different meso-scale snow clouds associated with an extratropical low passing over the Western Pacific. Based on synoptic data, GOES-9 satellite images, and precipitation amount data, the events were named as Sokcho and Busan cases, respectively. We analyzed the development mechanism of the events using meterological variables from the NCEP(National Centers for Environmental Prediction) /NCAR(National Centers for Atmospheric Research) reanalysis data such as potential vorticity(PV), divergence, tropopause undulation, static stability, and meridional wind circulation. The present analyses show that in the case of Sokcho, the cyclonic circulation in the lower atmosphere in the strong baroclinic region induced the cyclonic circulation in the upper atmosphere. The cyclonic circulation in the lower and upper atmosphere caused a heavy snowfall in the Sokcho region. In the case of Busan, the strong cyclonic circulation in the upper atmosphere was initiated by the stratospheric air intrusion with the high positive PV into the troposphere during the tropopause folding. The upper strong cyclonic circulation enhanced the cyclonic circulation in the lower disturbed atmosphere due to the extratropical low. This lower cyclonic circulation in turn, intensified the upper cyclonic circulation, that caused a heavy snowfall in the Busan region.

The Impact of Interaction between Cloud and Longwave Radiation on the Asian Monsoon Circulation (구름-장파복사 상호작용이 아시아 몬순에 미치는 영향)

  • Ryu, Geun-Hyeok;Sohn, Byung-Ju
    • Journal of the Korean earth science society
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    • v.30 no.1
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    • pp.58-68
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    • 2009
  • Three-dimensional distributions of longwave radiation flux for the April-September 1998 period are generated from radiative transfer calculations using the GEWEX Asian Monsoon Experiment (GAME) reanalysis temperature and humidity profiles and International Satellite Cloud Climatology Project (ISCCP) cloudiness as inputs to understand the effect of cloud radiative forcing in the monsoon season. By subtracting the heating of the clear atmosphere from the cloudy radiative heating, cloud-induced atmospheric radiative heating has been obtained. Emphasis is placed on the impact of horizontal gradients of the cloud-generated radiative heating on the Asian monsoon. Cloud-induced heating exhibits its maximum heating areas within the Indian Ocean and minimum heating over the Tibetan Plateau, which establishes the north-south oriented differential heating gradient. Considering that the differential heating is a ultimate source generating the atmospheric circulation, the cloud-induced heating gradient established between the Indian Ocean and the Plateau can enhance the strength of the north-south Hadley-type monsoon circulation. Cooling at cloud top and warming at cloud bottom, which are the vertical distributions of cloud-induced heating, can exert on the monsoon circulation by altering the atmospheric stability.

A Case Study on the Polar Low Developed over the Sea Near Busan on 11~12 February 2011 (2011년 2월 11~12일 부산 근해에서 발달한 극저기압에 대한 사례연구)

  • Lee, Jae Gyoo;Kim, Hae-Min;Kim, Yu-Jin
    • Atmosphere
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    • v.26 no.2
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    • pp.301-319
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    • 2016
  • The evolutionary process of the polar low, which caused the heavy snowfall in the East Coast area on 11~12 February 2011, was investigated to describe in detail using synoptic weather charts, satellite imageries, and ERA (European Centre for Medium-Range Weather Forecasts Re-Analysis) -Interim reanalysis data. It was revealed that 1) the polar low was generated over the sea near Busan where a large cyclonic shear in the inverted trough branched from the parent low existed, 2) during the developing and mature stages, there was a convectively unstable region in the lower layer around the polar low and its south side, 3) the polar low was developed in the region where the static stability in the 500~850 hPa layer was the lowest, 4) the result from the budget analysis of the vorticity equation indicated that the increase in the vorticity at the lower atmosphere, where the polar low was located, was dominated mainly by the stretching term, 5) the warm core structure of the polar low was identified in the surface-700 hPa layer during the mature stage, 6) there was a close inverse relationship between a development of the polar low and the height of the dynamic tropopause over the polar low, and 7) for generation and development of the polar low, large-scale circulation systems, such as upper cold low and its combined short wave trough, major low (parent low), and polar air outbreak, should be presented, indicating that the polar low has the nature of the baroclinic disturbance.