• 한국세라믹학회지
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• 제42권1호
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• pp.62-68
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• 2005

질화상압동시소결(NPS) 공정에 의해 제조된 기공율이 다른 질화규소 소결체에 대해 $1300^{circ}C$ 순산소 가스분위기에서 산화거동을 조사하였다. 질화규소 세라믹스 표면에 형성된 산화층의 두께는 산화 시간과 온도에 따라 증가되었으며, $1300^{circ}C$에서 100시간 산화시킨 5A5Y5Si와 5A5Y10Si 시편의 산화층 두께는 각각 10$\mu$m와 20$\mu$m이었다. 5A5YSi와 5A5Y10Si 시편의 산화는 각각 215kJ/mol과 104kJ/mol의 활성화 에너지를 갖고 포물선적 거동을 나타내었다. $1300^{circ}C$에서 500시간 산화시킨 후, 5A5Y5Si 시편에 대해 꺾임 강도를 측정한 결과, 초기의 약 500MPa값을 유지하고 있었으며, 반면 5A5Y10Si의 경우에는 초기의 값에서 약 100MPa의 강도저하를 나타내고 있었다.

• 한국지구과학회지
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• 제35권1호
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• pp.41-53
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• 2014

겨울철 동해안 강수 현상에 대한 규명을 위하여 라디오존데를 활용한 특별관측을 2012년 1월 5일부터 2월 29일까지 실시하였고, 이 연구는 대기의 불안정을 나타내는 다양한 변수를 활용하여 강수 사례의 분석을 수행하였다. 그 결과, 강수가 발생할 때 지표면(1000 hPa)에서 중층(약 750 hPa)까지의 상당온위가 증가하는 것을 볼 수 있었고, 이러한 대기층(1000~750 hPa)은 불안정을 일으키기에 충분한 수준의 수증기를 함유하고 있었다. 대류가용잠재에너지의 시간적인 변화를 살펴본 결과 강수가 발생하였을 때 증가하는 것을 볼 수 있었고, 연직바람쉬어의 경우에서도 대류가용잠재에너지와 마찬가지로 강수 기간 동안 상승하여 일정수준 이상의 값을 유지하는 것을 확인할 수 있었다. 강수에 따른 대기 구조의 상세한 분석을 위하여 지상 원격 탐사 자료와 지상 관측 자료를 활용하여 분석을 수행하였다. 또한 가강수량과 바람벡터를 이용하여 가강수량플럭스를 계산하였다. 가강수량플럭스와 강수량은 북동풍 계열의 바람이 발생하였을 때 높은 관계성을 보였다. 그 결과 동해안영역에서 발생하는 강수 현상에서는 풍계와 같은 역학적인 작용의 이해가 중요한 것으로 판단되었다.

• 한국지구과학회지
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• 제38권6호
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• pp.395-404
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• 2017

본 연구에서는 구미에 위치한 낙동강에서 발생한 안개를 분류하였고 안개 발생 전후의 기상특성을 분석하였다. 안개는 2013년부터 2015년까지 시정계를 이용하여 관측되었다. 안개는 총 74회 발생하였고 대부분 증기안개로 분류되었다. 관측된 증기 안개는 내륙에서 발생한 안개보다 지속시간이 길게 나타났는데 이는 지형적 특징으로 인해 야간 증발이 다른 지역보다 강하게 나타났기 때문이다. 안개 지속시간에 대한 하천 증발 효과를 분석하기 위해 Penman-Monteith(Penman법)와 Bulk aerodynamic (Bulk법) 방법을 사용하여 증발량을 추정하였다. 이 중 Bulk법은 실제 수면에서 측정한 증발량과 유사하게 나타났다. 따라서 Bulk법이 실제 수면 증발량 추정에 적합한 방법임을 확인할 수 있었다. Bulk법으로 추정한 증발량은 안개 비발생일 보다 안개 발생일에 06 LST와 07 LST에 더 높게 나타났다. 안개 발생일에 하천의 증발은 대기에 증발잠열 에너지를 공급하고 안개 내부의 난류를 유지하는 에너지원으로 작용한다. 이와 같은 결과는 안개내부의 풍속, 기온, 그리고 난류운동에너지의 증가를 통해 확인하였다.

• Korean Chemical Engineering Research
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• 제43권1호
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• pp.85-91
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• 2005

ECR-MOCVD를 이용한 상온조건에서 투명전도성 고분자막이$(CH_3)_4Sn-H_2-O_2$ 분위기하에 $SnO_2$막이 제조되었다. 제조된 투명전도막의 전기적특성은 공정압력, 전자석/분사링/기판사이의 거리, 전자석의 전류, 마이크로파 출력, 증착시간과 같은 공정변수에 따라 조사되었다. 마이크로파 출력과 전자석의 전류가 증가함에 따라 낮은 전기적 저항을 갖는 $SnO_2$막이 형성되었다. 또한 이들 공정변수들이 증착된 막의 광학적특성에 미치는 영향은 중요하게 나타났다. ECR-MOCVD에 의해 제조된 막의 투과도와 반사도는 380-780 nm의 가시광영역에서 각각 93-98%, 0.1-0.5%였다. 증착된 막의 평균 grain 크기는 공정변수에 관계없이 20-50 nm범위의 값으로 일정하였다. 본 연구의 최적화된 조건에서 전기적저항은 $7.5{\times}10^{-3}ohm{\cdot}cm$, 투과도 93%, 반사도 0.2%를 갖는 막이 얻어졌다.

• 자원리싸이클링
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• 제24권1호
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• pp.35-42
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• 2015

본 연구는 건식제련법으로 폐 PCB를 처리하는 공정에서 슬래그 중 Ni의 용해거동에 대한 기초연구로서, CaO-$SiO_2-Al_2O_3$-MgO계 슬래그와 Cu-5 wt%Ni합금 사이의 Ni 분배거동을 1623~1823 K의 $CO_2$-CO 분위기 중에서 조사하였다. 평형산소분압이 증가할수록 Ni의 분배비는 선형적으로 증가하였으며, 이 결과로부터 Ni의 슬래그 중 용해반응은 다음과 같이 나타낼 수 있다. $$Ni(l)_{metal}+\frac{1}{2}O_2(g)NiO(l)_{slag}$$ 슬래그 중 염기성 산화물(CaO와 MgO)의 농도가 증가할수록 Ni의 분배비는 선형적으로 증가하였다. 그러나 반응 온도가 높을수록 Ni의 분배비는 선형적으로 감소하였다. 이러한 결과로부터 Ni의 분배비에 미치는 실험변수의 영향을 다중 회귀분석하여 다음과 같은 경험식을 얻었다. $${\log}L_{Ni}=0.4000{\log}P_{O2}-5.1{\times}10^{-4}T+0.3375\(\frac{X_{CaO}+X_{MgO}}{X_{SiO2}}\)$$

• 대기
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• 제24권3호
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• pp.283-301
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• 2014

In 2010, only 14 tropical cyclones (TCs) were generated over the western North Pacific (WNP), which was the smallest since 1951. This study summarizes characteristics of TCs generated in 2010 over the WNP and investigates the causes of the record-breaking TC genesis. A long-term variation of TC activity in the WNP and verification of official track forecast in 2010 are also examined. Monthly tropical sea surface temperature (SST) anomaly data reveal that El Ni$\tilde{n}$o/Southern Oscillation (ENSO) event in 2010 was shifted from El Ni$\tilde{n}$o to La Ni$\tilde{n}$a in June and the La Ni$\tilde{n}$a event was strong and continued to the end of the year. We found that these tropical environments leaded to unfavorable conditions for TC formation at main TC development area prior to May and at tropics east of $140^{\circ}E$ during summer mostly due to low SST, weak convection, and strong vertical wind shear in those areas. The similar ENSO event (in shifting time and La Ni$\tilde{n}$a intensity) also occurred in 1998, which was the second smallest TC genesis year (16 TCs) since 1951. The common point of the two years suggests that the ENSO episode shifting from El Ni$\tilde{n}$o to strong La Ni$\tilde{n}$a in summer leads to extremely low TC genesis during La Ni$\tilde{n}$a although more samples are needed for confidence. In 2010, three TCs, DIANMU (1004), KOMPASU (1007) and MALOU (1009), influenced the Korean Peninsula (KP) in spite of low total TC genesis. These TCs were all generated at high latitude above $20^{\circ}N$ and arrived over the KP in short time. Among them, KOMPASU (1007) brought the most serious damage to the KP due to strong wind. For 14 TCs in 2010, mean official track forecast error of the Korea Meteorological Administration (KMA) for 48 hours was 215 km, which was the highest among other foreign agencies although the errors are generally decreasing for last 10 years, suggesting that more efforts are needed to improve the forecast skill.

• 대기
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• 제27권3호
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• pp.359-370
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• 2017

In this study, the oceanic Total Precipitable Water (TPW) retrieval algorithm at 16 km altitude of High Altitude Long Endurance Unmanned Aerial Vehicle (HALE UAV) is described. Empirical equation based on Wentz method (1995) that uses the 18.7 and 22.235 GHz channels is developed using the simulated brightness temperature and SeeBor training dataset. To do radiative simulation, Satellite Data Simulator Unit (SDSU) Radiative Transfer Model (RTM) is used. The data of 60% (523) and 40% (349) in the SeeBor training dataset are used to develop and validate the TPW retrieval algorithm, respectively. The range of coefficients for the TPW retrieval at the altitude of 3~18 km with 3 km interval were 153.69~199.87 (${\alpha}$), 54.330~58.468 (${\beta}$), and 84.519~93.484 (${\gamma}$). The bias and RMSE at each altitude were found to be about $-0.81kg\;m^{-2}$ and $2.17kg\;m^{-2}$, respectively. Correlation coefficients were more than 0.9. Radiosonde observation has been generally operated over land. To validate the accuracy of the oceanic TPW retrieval algorithm, observation data from the Korea Meteorological Administration (KMA) Gisang 1 research vessel about six clear sky cases representing spring, autumn, and summer season is used. Difference between retrieved and observed TPW at 16 km altitude were in the range of $0.53{\sim}1.87kg\;m^{-2}$, which is reasonable for most applications. Difference in TPW between retrieval and observation at each altitude (3~15 km) is also presented. Differences of TPW at altitudes more than 6 km were $0.3{\sim}1.9kg\;m^{-2}$. Retrieved TPW at 3 km altitude was smaller than upper level with a difference of $-0.25{\sim}0.75kg\;m^{-2}$ compared to the observed TPW.

• 대기
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• 제26권4호
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• pp.509-522
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• 2016

Heavy snowfall events have occurred frequently in the Yeongdong region but understanding of these events have trouble in lack of snowfall observation in this region because it is composed of complex topography like the "Taebaek mountains" and the "East sea". These problems can be solved by quantitative precipitation estimation technique using remote sensing such as radar, satellite, etc. Two radars which are able to cover over Yeondong region were installed at Gangneung (GNG) and Gwangdeoksan (GDK). This study uses radar and water equivalent of snow cover to investigate the characteristics of radar echoes and the $Z_e-R$ relations associated with the 10 Yeongdong heavy snowfall events during the last 5 years (2010~2014). It was found that the heights which the probability of detection (POD) of snow detection by GNG radar is more than 80% are 3,000 m and 1,500 m in convective cloud and stratiform cloud, respectively. The vertical gradient of radar reflectivity is less decreased in convective cloud than stratiform cloud. However, POD by GDK radar are lower than 80% at all layers because the majority of Yeondong observational stations are more than 100 km away from GDK radar site. Furthermore, we examined $Z_e-R$ relation from the 10 events using GNG radar and compared the "a" and "b" obtained from these examinations at Sokcho (SC) and Daegwallyeong (DG). These "a" and "b" are estimated from radar echo at 500 m (SC) and 1,500 m (DG). The values of "a" differ in their stations such as SC and DG are 30~116 and 6~39, respectively. But "b" is 0.4~1.7 irrespective of stations. Moreover, the value of "a" increased with surface air temperature. Therefore, quantitative precipitation estimation in heavy snowfall events by radar echo using fixed "a" and "b" is difficult because these values changed according to those precipitation characteristics.

• 한국전기전자재료학회논문지
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• 제25권5호
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• pp.398-402
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• 2012

Synthesis of $Li_2MnSiO_4$ was attempted by the conventional solid-state reaction method, and the phase formation behavior according to the change of the calcination condition was investigated. When the mixture of the three source materials, $Li_2O$, MnO and $SiO_2$ powders, were used for calcination in air, it was difficult to develop the $Li_2MnSiO_4$ phase because the oxidation number of $Mn^{2+}$ could not be maintained. Therefore, two-step calcination was applied: $Li_2SiO_3$ was made from $Li_2O$ and $SiO_2$ at the first step, and $Li_2MnSiO_4$ was synthesized from $Li_2SiO_3$ and MnO at the second step. It was easy to make $Li_2MnSiO_3$ from $Li_2O$ and $SiO_2$. $Li_2MnSiO_4$ single phase was developed by the calcination at $900^{\circ}C$ for 24 hr in Ar atmosphere as the oxidation of $Mn^{2+}$ was prevented. However, the $Li_2MnSiO_4$ was ${\gamma}-Li_2MnSiO_4$, one of the polymorph of $Li_2MnSiO_4$, which could not be used as the cathode materials in Li-ion batteries. By applying the additional low temperature annealing at $400^{\circ}C$, the single phase ${\beta}-Li_2MnSiO_4$ powder was synthesized successfully through the phase transition from ${\gamma}$ to ${\beta}$ phase.

• Journal of Electrical Engineering and Technology
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• 제8권6호
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• pp.1474-1480
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• 2013

Silicon carbide (SiC)-zirconium diboride ($ZrB_2$) composites were prepared by subjecting a 60:40 vol% mixture of ${\beta}$-SiC powder and $ZrB_2$ matrix to spark plasma sintering (SPS) in 15 $mm{\Phi}$ and 20 $mm{\Phi}$ molds. The 15 $mm{\Phi}$ and 20 $mm{\Phi}$ compacts were sintered for 60 sec at $1500^{\circ}C$ under a uniaxial pressure of 50 MPa and argon atmosphere. Similar composites were simulated using $Flux^{(R)}$ 3D computer simulation software. The current and power densities of the specimen sections of the simulated SiC-$ZrB_2$ composites were higher than those of the mold sections of the 15 $mm{\Phi}$ and 20 $mm{\Phi}$ mold simulated specimens. Toward the centers of the specimen sections, the current densities in the simulated SiC-$ZrB_2$ composites increased. The power density patterns of the specimen sections of the simulated SiC-$ZrB_2$ composites were nearly identical to their current density patterns. The current densities of the 15 $mm{\Phi}$ mold of the simulated SiC-$ZrB_2$ composites were higher than those of the 20 $mm{\Phi}$ mold in the center of the specimen section. The volume electrical resistivity of the simulated SiC-$ZrB_2$ composite was about 7.72 times lower than those of the graphite mold and the punch section. The power density, 1.4604 $GW/m^3$, of the 15 $mm{\Phi}$ mold of the simulated SiC-$ZrB_2$ composite was higher than that of the 20 $mm{\Phi}$ mold, 1.3832 $GW/m^3$. The $ZrB_2$ distributions in the 20 $mm{\Phi}$ mold in the sintered SiC-$ZrB_2$ composites were more uniform than those of the 15 $mm{\Phi}$ mold on the basis of energy-dispersive spectroscopy (EDS) mapping. The volume electrical resistivity of the 20 $mm{\Phi}$ mold of the sintered SiC-$ZrB_2$ composite, $6.17{\times}10^{-4}{\Omega}cm$, was lower than that of the 15 $mm{\Phi}$ mold, $9.37{\times}10^{-4}{\Omega}{\cdot}cm$, at room temperature.