• Title/Summary/Keyword: Asymmetric addition

Search Result 288, Processing Time 0.029 seconds

The Interaction of Chiral Amino Thiols with Organozinc Reagents and Aldehydes: A Mechanism of Amino Thiol-Catalyzed Addition of Organozinc Reagents to Aldehydes

  • 강자효;김진범;김지영;이덕환
    • Bulletin of the Korean Chemical Society
    • /
    • v.19 no.4
    • /
    • pp.475-481
    • /
    • 1998
  • Details of various equilibria involved in the reactions of oxaza- and thiazazincolidine catalysts, generated from either β-amino alcohol or β-amino thiol, with aldehyde were studied by colligative measurements. The results indicated that the coordination of diethylzinc prior to the coordination of aldehyde is essential for high enantioselectivity of the thiol catalyzed reaction. The probable origin of asymmetric nonlinearity is also presented.

Pressure-Loss Characteristics of an Asymmetric Bifurcation Model of Human Lung Airways (비대칭 인체 기관지 분지관의 압력손실 특성)

  • Kang, Min-Yeong;Lee, Jin-Won
    • Transactions of the Korean Society of Mechanical Engineers B
    • /
    • v.36 no.3
    • /
    • pp.301-307
    • /
    • 2012
  • The characteristics of pressure loss in an asymmetric bifurcating tube were investigated numerically for steady inspiratory conditions. The loss coefficient K calculated for various asymmetry and flow-distribution ratios found in human lung airways showed a power-law dependence on the Reynolds number (Re) and length-to-diameter ratio (L/d), with different exponents for Re $\geq$ 100 and Re < 100. The fundamental characteristics of the asymmetric bifurcation are similar to the case of symmetric bifurcation. In addition, the effect of skewed inlet velocity profiles on the pressure loss was weak, and decreased with an increasing number of bifurcations.

A Study on Secure Binding Update Protocol Supporting Mobile Nodes with Constraint Computational Power in Mobile IPv6 Environment (모바일 IPv6 환경에서 제한된 계산 능력을 갖는 모바일 노드를 지원하는 바인딩 갱신 인증 프로토콜에 관한 연구)

  • Choi, Sung-Kyo;You, Il-Sun
    • Journal of Internet Computing and Services
    • /
    • v.6 no.5
    • /
    • pp.11-25
    • /
    • 2005
  • In MIPv6 environment, an important design consideration for public key based binding update protocols is to minimize asymmetric cryptographic operations in mobile nodes with constraint computational power, such as PDAs and cellular phones, For that, public key based protocols such as CAM-DH. SUCV and Deng-Zhou-Bao's approach provides an optimization to offload asymmetric cryptographic operations of a mobile node to its home agent. However, such protocols have some problems in providing the optimization. Especially, CAM-DH with this optimization does not unload all asymmetric cryptographic operations from the mobile node, while resulting in the home agent's vulnerability to denial of service attacks. In this paper, we improve the drawbacks of CAM-DH. Furthermore, we adopt Aura's two hash-based CGA scheme to increase the cost of brute-force attacks searching for hash collisions in the CGA method. The comparison of our protocol with other public key based protocols shows that our protocol can minimize the MN's computation overhead, in addition to providing better manageability and stronger security than other protocols.

  • PDF

Concurrency Control based on Serialization Graph for Query Transactions in Broadcast Environment : CCSG/QT (방송환경에서 질의 거래를 위해 직렬화 그래프에 기반을 둔 동시성 제어 기법)

  • 이욱현;황부현
    • Journal of KIISE:Databases
    • /
    • v.30 no.1
    • /
    • pp.95-107
    • /
    • 2003
  • The broadcast environment has asymmetric communication aspect that is typically much greater communication bandwidth available from server to clients than in the opposite direction. In addition, most of mobile computing systems allow mostly read-only transactions from mobile clients for retrieving different types of information such as stock data, traffic information and mews updates. Since previous concurrency control protocols, however, do not consider such a particular characteristics, the performance degradation occurs when previous schemes are applied to the broadcast environment. In this paper, we propose the efficient concurrency control for query transaction in broadcast environment. The following requirements are satisfied by adapting weak consistency that is the appropriate correctness criterion of read-only transactions: (1) the mutual consistency of data maintained by the server and read by clients (2) the currency of data read by clients. We also use the serialization graph scheme to check the weak consistency efficiently. As a result, we improved a performance by reducing unnecessary aborts and restarts of read-only transactions caused when global serializability was adopted.

Asymmetric Index Management Scheme for High-capacity Compressed Databases (대용량 압축 데이터베이스를 위한 비대칭 색인 관리 기법)

  • Byun, Si-Woo;Jang, Seok-Woo
    • Journal of the Korea Academia-Industrial cooperation Society
    • /
    • v.17 no.7
    • /
    • pp.293-300
    • /
    • 2016
  • Traditional databases exploit a record-based model, where the attributes of a record are placed contiguously in a slow hard disk to achieve high performance. On the other hand, for read-intensive data analysis systems, the column-based compressed database has become a proper model because of its superior read performance. Currently, flash memory SSD is largely recognized as the preferred storage media for high-speed analysis systems. This paper introduces a compressed column-storage model and proposes a new index and its data management scheme for a high-capacity data warehouse system. The proposed index management scheme is based on the asymmetric index duplication and achieves superior search performance using the master index and compact index, particularly for large read-mostly databases. In addition, the data management scheme contributes to the read performance and high reliability by compressing the related columns and replicating them in two mirrored SSD. Based on the results of the performance evaluation under the high workload conditions, the data management scheme outperforms the traditional scheme in terms of the search throughput and response time.

Stability of unilateral sagittal split ramus osteotomy for correction of facial asymmetry: long-term case series and literature review

  • Lee, Seong-Geun;Kang, Young-Hoon;Byun, June-Ho;Kim, Uk-Kyu;Kim, Jong-Ryoul;Park, Bong-Wook
    • Journal of the Korean Association of Oral and Maxillofacial Surgeons
    • /
    • v.41 no.3
    • /
    • pp.156-164
    • /
    • 2015
  • Bilateral sagittal split ramus osteotomy is considered a standard technique in mandibular orthognathic surgeries to reduce unexpected bilateral stress in the temporomandibular joints. Unilateral sagittal split ramus osteotomy (USSO) was recently introduced to correct facial asymmetry caused by asymmetric mandibular prognathism and has shown favorable outcomes. If unilateral surgery could guarantee long-term postoperative stability as well as favorable results, operation time and the incidence of postoperative complications could be reduced compared to those in bilateral surgery. This report highlights three consecutive cases with long-term follow-up in which USSO was used to correct asymmetric mandibular prognathism. Long-term postoperative changes in the condylar contour and ramus and condylar head length were analyzed using routine radiography and computed tomography. In addition, prior USSO studies were reviewed to outline clear criteria for applying this technique. In conclusion, patients showing functional-type asymmetry with predicted unilateral mandibular movement of less than 7 mm can be considered suitable candidates for USSO-based correction of asymmetric mandibular prognathism with or without maxillary arch surgeries.

Optimistic Concurrency Control based on TimeStamp Intervals for Broadcast Environment: OCC/TI (방송환경에서 타임스탬프 구간에 기반을 둔 낙관적 동시성 제어 기법)

  • 이욱현;황부현
    • Journal of KIISE:Databases
    • /
    • v.29 no.6
    • /
    • pp.477-491
    • /
    • 2002
  • The broadcast environment has asymmetric communication aspect that is typically much greater communication bandwidth available from server to clients than in the opposite direction. In addition, mobile computing systems generate mostly read-only transactions from mobile clients for retrieving different types of information such as stock data, traffic information and news updates. Since previous concurrency control protocols, however, do not consider such a particular characteristics, the performance degradation occurs when previous schemes are applied to the broadcast environment. In this paper, we propose optimistic concurrency control based on timestamp interval for broadcast environment. The following requirements are satisfied by adapting weak consistency that is the appropriate correctness criterion of read-only transactions: (1) the mutual consistency of data maintained by the server and read by clients (2) the currency of data read by clients. We also adopt the timestamp Interval protocol to check the weak consistency efficiently. As a result, we improved a performance by reducing unnecessary aborts and restarts of read-only transactions caused when global serializability was adopted.

Two-dimensional Model Testing System for Analysis of PVD Installation and Soil Disturbance (PVD 설치 및 지반교란의 분석을 위한 2차원 모형실험 시스템)

  • Kim, Jae Hyun;Choo, Yun Wook;Park, Hyun-Il;Kim, Dong-Soo
    • KSCE Journal of Civil and Environmental Engineering Research
    • /
    • v.32 no.4C
    • /
    • pp.149-157
    • /
    • 2012
  • In order to investigate the soil disturbance induced by anchor-shoe for PVD installation and the anchoring mechanism, a new two dimensional testing system was developed. By using the developed testing system, 1g and centrifuge model tests were performed, simulating the driving-retrieval process of both conventional symmetric anchor shoe and new asymmetric anchor shoe. Various size anchor-shoes were simulated and the results were compared. The images recorded during the installation were analyzed by image processing technique. The results of the image analysis presented the clay disturbance depending on the size and type of anchor shoe. In addition, from the retrieval process, the anchoring mechanism was revealed and the holding capacity was measured. As results, the size of anchor shoe influences the soil disturbance and holding capacity. The new asymmetric anchor shoe reduces the soil disturbance and improves anchoring performance.

When Does Auto-Parts Suppliers' Innovation Reduce Their Dependence on the Automobile Assembler?

  • Kang, Jihoon;Choe, Soonkyoo
    • Journal of Korea Trade
    • /
    • v.24 no.3
    • /
    • pp.37-54
    • /
    • 2020
  • Purpose - This study is to investigate the determinants of suppliers' dependence on buyers in the home country by developing a theoretical model of innovative activities. The high dependence of auto parts suppliers on a single local buyer in South Korea due to firm ownership issues and incremental innovation is examined using data from a set of organizations that supply intermediate goods to this automotive manufacturer. Furthermore, we tested the moderating effect of FDI and global knowledge sourcing on the relationship between firm ownership and suppliers' dependence on the local buyer. Design/methodology - To test the hypotheses, we examined a sample of 101 suppliers over 10 years in the Korean automobile parts industry. In this empirical analysis, we utilized a fixed-effects generalized least squares model using panel data. Findings - In this study, domestic firms (automobile parts suppliers) were more dependent on a single local buyer (automobile assembler) than foreign-owned suppliers operating in Korea. In addition, incremental innovation was the mediating mechanism between domestic firms and dependence on the local buyer. To reduce this dependence on the buyer, we suggest two different international strategies: geographical diversification through FDI and global knowledge sourcing. Originality/value - Previous studies showed that asymmetric dependence between firms has many adverse effects. This study proved that domestic and foreign-owned suppliers have different levels of dependence on local buyers due to their heterogeneous characteristics and business strategies. We distinguish two different types of innovation - radical innovation and incremental innovation - that previous studies have often treated as equal when it comes to firm autonomy. Finally, we propose that both FDI and international knowledge sourcing as global strategies to weaken suppliers' asymmetric dependence on a single buyer.