• Title/Summary/Keyword: Asymmetric addition

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Folded Ranked Set Sampling for Asymmetric Distributions

  • Bani-Mustafa, Ahmed;Al-Nasser, Amjad D.;Aslam, Muhammad
    • Communications for Statistical Applications and Methods
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    • v.18 no.1
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    • pp.147-153
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    • 2011
  • In this paper a new sampling procedure for estimating the population mean is introduced. The performance of the new population mean estimator is discussed, along with its properties, and it is shown that the proposed method generates an unbiased estimator. The relative efficiency of the suggested estimator is computed, in regards to the simple random sample(SRS), and comparisons are made to the ranked set sampling(RSS) and extreme ranked set sampling(ERSS) estimators used for asymmetric distributions. The results indicate that the proposed estimator is more efficient than the estimators based on the ERSS. In addition, the folded ranked set sampling(FRSS) procedure has an advantage over the RSS and ERSS in that it reduces the number of unused sampling units.

Effects of Asymmetric Tip Clearance on Centrifugal Compressor Flow (비대칭 팁간극이 원심압축기의 유동에 미치는 영향)

  • Yoon, Yong-Sang;Song, Seung-Jin
    • 유체기계공업학회:학술대회논문집
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    • 2005.12a
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    • pp.533-541
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    • 2005
  • Compared to axial compressors, an analytical model capable of analyzing the flow in centrifugal compressor lacks because of the difficulty in governing equations for radial duct. Therefore, this paper presents a new model to predict flow field in a centrifugal compressor with a sinusoidal asymmetric tip clearance. To predict the 2 dimensional flow in the inlet and exit of the centrifugal compressor, the two flow fields are connected with compressor characteristic based on Moore-Greitzer model. Contrary to axial compressors, the nonuniformity of impeller exit pressure in centrifugal compressor decreases as flow coefficient decreases. In addition, that is sensitive to the slope of pressure rise by eccentricity. The maximum velocity exists right before the maximum tip clearance.

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Regulation of Stereoselectivity and Reactivity in the Inter- and Intramolecular Allylic Transfer Reactions

  • Yu, Chan-Mo;Youn, Jin-soup;Jung, Hee-Keum
    • Bulletin of the Korean Chemical Society
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    • v.27 no.4
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    • pp.463-472
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    • 2006
  • The preparation of enatiomerically enriched homoallylic alcohols through asymmetric addition of chiral allylic transfer reagents and allylating reagents with chiral catalysts to the carbonyl functionalities represents an important chemical transformation. Excellent progress has been made over past decade in the development and application of catalytic asymmetric allylic transfer reactions. In this account, our efforts for the various intermolecular allylic transfer reactions such as allylation, propargylation, allenylation, and dienylation utilizing accelerating strategy and sequential allylic transfer reactions to achieve multiple stereoselection mainly using transition metal catalysts are described.

Improvement of Luminous Efficacy in AC PDP with Asymmetric Metal Electrode Structure (AC PDP의 효율 향상을 위한 비대칭형 금속전극구조)

  • Dong, Eun-Joo;Ok, Jung-Woo;Yoon, Cho-Rom;Lee, Hae-June;Lee, Ho-Joon;Park, Chung-Hoo
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.57 no.4
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    • pp.660-667
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    • 2008
  • To improve the luminous efficacy of PDPs, an AC PDP with new metal electrode structure is suggested. Operating voltage margin, power consumption, luminance, luminous efficacy, addressing jitter and ICCD image of test panel with proposed structure are measured, to compared with performances of the conventional ITO structure and proposed structures. To enhance luminous efficacy, we designed new structure which have asymmetric metal electrode structure. The experimental results show that the suggested structure shows luminance to maximum 89% and luminous efficacy to maximum 107% compared with conventional ITO standard structure. In addition, proposed structures with asymmetric electrode show low power consumption by $2{\sim}3%$, high luminance by $5{\sim}7%$, and high luminous efficacy by $2{\sim}3%$ compared with proposed symmetric electrode structures.

Addition Compounds of Alkali Metal Hydrides. 32. A Comparison Study of Chiral Trialkylborohydrides and Chiral Dialkylmonoalkoxyborohydrides for the Asymmetric Reduction of Prochiral Ketones: The Effect of Comparable Chiral Alkyl and Alkoxy Groups on Asymmetric Industion$^\dag$

  • Brow, Hervert C.;Park, Won-Suh;Cho, Byung-Tae
    • Bulletin of the Korean Chemical Society
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    • v.8 no.4
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    • pp.276-280
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    • 1987
  • Several chiral potassium B-alkyl-9-boratabicyclo[3.3.1]nonanes $(K\; B-R^*-9-BBNH)$ and potassium B-alkoxy-9-boratabicyclo[3.3.1]nonanes $(K \;B-OR^*-9-BBNH)$ were synthesized by treatment of the corresponding trialkylboranes and dialkylmonoalkoxyboranes with a small excess of potassium hydride. The chiral B-alkoxy derivatives generally reduce representative ketones, such as acetophenone and 3-methyl-2-butanone, with greater optical induction than the corresponding B-alkyl derivatives, suggesting the involvement of the oxygen atom in the control process for asymmetric synthesis.