[KSCI] Korea Science Citation Index Service

http://dx.doi.org/10.5012/bkcs.2006.27.4.463

Regulation of Stereoselectivity and Reactivity in the Inter- and Intramolecular Allylic Transfer Reactions

Yu, Chan-Mo (Department of Chemistry and Institute of Basic Sciences, Sungkyunkwan University)
Youn, Jin-soup (Department of Chemistry and Institute of Basic Sciences, Sungkyunkwan University)
Jung, Hee-Keum (Department of Chemistry and Institute of Basic Sciences, Sungkyunkwan University)

Publication Information

Bulletin of the Korean Chemical Society / v.27, no.4, 2006 , pp. 463-472 More about this Journal

Abstract

The preparation of enatiomerically enriched homoallylic alcohols through asymmetric addition of chiral allylic transfer reagents and allylating reagents with chiral catalysts to the carbonyl functionalities represents an important chemical transformation. Excellent progress has been made over past decade in the development and application of catalytic asymmetric allylic transfer reactions. In this account, our efforts for the various intermolecular allylic transfer reactions such as allylation, propargylation, allenylation, and dienylation utilizing accelerating strategy and sequential allylic transfer reactions to achieve multiple stereoselection mainly using transition metal catalysts are described.

Keywords

Allylation; Asymmetric synthesis; Catalyst; Selectivity; Stereochemistry;

Citations & Related Records

Times Cited By Web Of Science : 27 (Related Records In Web of Science)
Times Cited By SCOPUS : 25

Reference
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8	/ Journal of the American Chemical Society
9	/ Angewandte Chemie - International Edition
10	/ Aldrichimica Acta
11	/ Bulletin of the Korean Chemical Society
12	/ Angewandte Chemie - International Edition
13	/ Chemical Communications
14	/ Journal of the American Chemical Society
15	/ Bulletin of the Korean Chemical Society
16	/ Topics in Organometallic Chemistry
17	/ Chemical Communications
18	/ Journal of the American Chemical Society
19	/ Journal of Organic Chemistry
20	/ Journal of the American Chemical Society
21	/ Journal of the American Chemical Society
22	/ Journal of the American Chemical Society
23	/ Journal of Organic Chemistry
24	/ Angewandte Chemie - International Edition

1	A Highly Diastereoselective Cyclocarbonylation of Allene-Aldehyde Mediated by Mo(CO)₆: Synthesis of Bicyclic Lactones / [Ko, Kyoung-Jun;Kim, Sang-Hoon;Kim, Yu-Rim;Min, Dong-Won;Yu, Chan-Mo;] / Bulletin of the Korean Chemical Society
2	Stereoselective Cylization of Allenoates Containing Carbonyl Functionalities Mediated Mo(CO)₆: Synthesis of Canadensolide and Sporothriolide / [Kwon, Ji-Sook;Gong, Su-Yeon;Woo, Seok-Hoon;Yu, Chan-Mo;] / Bulletin of the Korean Chemical Society
3	Intramolecular Carbocyclization of Allenoate-aldehydes with Hexamethylditin Catalyzed by Palladium Complex: Synthesis of Cyclic Dienes / [Seong, Won-Jae;Gong, Su-Yeon;Woo, Seok-Hoon;Yu, Chan-Mo;] / Bulletin of the Korean Chemical Society