• Bulletin of the Korean Chemical Society
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• v.15 no.9
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• pp.732-739
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• 1994

Asymmetric [2,3]-Wittig rearrangements of allyl propargyl ethers in hexane were performed in the presence of s-butyllithium and (-)-${\alpha}$-isosparteine which is a $C_2$-symmetric chiral ligand for the alkyllithium reagent. The reactions of (Z)-or (E)-allyl 3-trimethylsilylpropargyl ethers at -78$^{\circ}C$ showed good diastereoselectivities (74-100%) and moderate enantioselectivities (29-71%). The absolute configurations of the rearrangement products were determined by the corresponding Mosher's esters. It was found that (-)-${\alpha}$ -isosparteine induced (R) configuration at the hydroxy carbon and syn stereochemistry more favorably. The possible transition state is discussed.

• Bulletin of the Korean Chemical Society
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• v.29 no.2
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• pp.313-318
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• 2008

An enantioselective ring opening of racemic terminal epoxides has been achieved by using heterobimetallic cobalt salen complexes with variety of nucleophiles. They were proven to be highly enantioselective and reactive for the synthesis of valuable chiral building blocks in enantio-riched forms up to 98% ee.

• The Bulletin of The Korean Astronomical Society
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• v.37 no.2
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• pp.79.1-79.1
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• 2012

Due to the quantum interference of many atomic levels, the exact scattering cross section around a given resonance transition deviates from the Lorentz function when the frequency of the incident radiation is quite far from the resonance frequency. This atomic effect is quite significant in the case of damped Ly alpha systems, where HI column density is in excess of 10^20 cm^-2. In this poster, we present the deviation quantitatively taking into consideration of the Rayleigh and Raman scattering around Lyman alpha and Lyman beta.

• Proceedings of the Membrane Society of Korea Conference
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• 1998.10a
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• pp.103-105
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• 1998

Asymmetric polymeric membranes prepared by the phase transition technique usually have either a top layer consisting of closely packed nodules or pores dispersed throughout the membrane surfaces. In this study, we present AFM image of a polysulfone membrane which show a clear evidence for the nodular structure and porous structure resulted from different phase separation mechanisms; spinodal decomposition and nucleation and growth. The surface morphology obtained by SEM and AFM was also compared.

• Korean Journal of Optics and Photonics
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• v.28 no.2
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• pp.59-67
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• 2017

This paper proposes an asymmetric split-loop resonator with an outer square loop (ASLR-OSL), which can actively control terahertz wave transmission properties while maintaining a high-Q-factor of the asymmetric split-loop resonator (ASLR). An added outer square loop is designed to play the roles of both a metamaterial and a micro-heater, which can control the temperature through a directly applied bias voltage. A vanadium dioxide ($VO_2$) thin film, which exhibits an insulator-metal phase transition with temperature change, is used to control the transmission properties. The proposed ASLR-OSL shows transmission properties similar to those of the ASLR, and they can be successfully controlled by directly applying bias voltage to the outer square loop. Based on these results, an electrically controllable terahertz high-Q metamaterial could be achieved simply by adding a square loop to the outside of a well-known high-Q metamaterial.

• Bulletin of the Korean Chemical Society
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• v.31 no.2
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• pp.315-326
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• 2010

This study examined the overlapping resonances in the systems involving 1 open and 2 closed channels using the phase-shifted version of multichannel quantum-defect theory (MQDT). The results showed that 21 patterns for the q reversals in the autoionization spectra are possible depending on the relative arrangements of the two simple poles and roots of the quadratic equations. Complete cases could be generated easily using the q zero planes determined using only 3 asymmetric spectral line profile indices. The transition of the spectra of the coarse interloper Rydberg series from the lines into a structured continuum by being dispersed onto the entire Rydberg series was found. The overall behavior of the time delays was found to be governed by the dense Rydberg series, which is quite different from the one of the autoionization cross sections that is governed by an interloper, indicating that different dynamics prevail for them. This is in contrast to the two channel system where both quantities behave similarly. The dynamics obtained in the presence of overlapping resonances is as follows. The absorption process is instant and dominated by a transition to the interloper line. This process is followed by rapid leakage into the dense Rydberg series, which has a longer residence time before ionization than that of the interloper state. This is because the orbiting period is proportional to $\upsilon^3$ so that an excited electron has a shorter lifetime in the interloper state belonging to a lower member of the Rydberg series.

• Strategy21
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• s.36
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• pp.180-214
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• 2015

The Republic of Korea navy challenged from the unexpected surprise attacks by the North Korea navy, albeit, the developments of up-to-date naval forces' technology, and the ceaseless efforts for war preparedness. My study divided into two categories. Qualitative methods used for literature review of international relations theory related to the war onset and for investigating events occurred on the Peninsula and its surrounding seas from 1968 to 2007. Quantitative method used such as the analyses of national power index of the two Koreas, the United States, and China, the uses of equation model to calculate power index of alliance, COPDAB(Conflict and Peace Data Bank) index analysis. Like Choi's study on East Asia maritime conflict, as a conclusion, considering both AT theory and maritime national power as a tool for predicting maritime conflict in the Peninsula proved significant. Based on the study, ROK navy need to prepare for the maritime conflict because the results showed North Korea would initiate maritime disputes sooner or later using fatal asymmetric forces and methods. As a policy suggestion, we are required to maintain a concrete ROK-US alliance ties and to construct naval forces due to the deterring functions of maritime national power.

• Textile Coloration and Finishing
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• v.25 no.4
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• pp.241-246
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• 2013

The color properties of a white or nearly colorless fabric are represented by whiteness index (WI) or yellowness index (YI). These two indexes relate to a white fabric's color quality. The purpose of this study was to identify the properties of WI and YI on the CIELAB through the simulations of estimation data for a systemization of color quality control. The results indicated that the relationship between WI and YI was a negative correlation, however the coefficients of correlation function between WI and YI were depended on hue. There were two hue transition points of the rate of changes in WI and YI. These hue transition points were the reference points to divide the hue contribution to WI and YI. These points were not the point of h=0 and h=180 and asymmetric. In addition, where the colors were same distance from the white point on the CIELAB, the rate of changes in WI and YI by ${\Delta}$Ew were depending on hue. Specifically, when WI decreased, YI of reddish and yellowish tinted colors decreased more than bluish tinted colors.

• Journal of the Korean Magnetic Resonance Society
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• v.9 no.1
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• pp.21-28
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• 2005

$^{11}B$ nuclear magnetic resonance (NMR) measurements have been performed to investigate electronic structures and vortex states of $M_gB_2$ superconductor. The central transition shows a narrow peak down to 25 K at 3.15 T. Below 25 K, an extra line starts to show up and dominates. The extra line is broad and asymmetric with a long tail in the high frequency side, which confirms that this originates from vortex pinning below the irreversibility temperature. From temperature evolution of the fraction and linewidth of the broad portion, temperature dependence of coherence length and penetration depth are extracted.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.20 no.9
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• pp.2965-2972
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• 1996

Transitional flow in an obstructed channel is investigated using numerical simulation. Two-dimensional thin obstacles are mounted symmetrically in the vertical direction and periodically in the streamwise direction. Flow separation occurs at the tip of the sharp obstacles. Depending on the Reynolds number, the flow undergoes Hopf bifurcation as the primary instability leading to a two-dimensional unsteady periodic solution. At higher Reynolds numbers, the unsteady solution exhibits a symmetry-breaking bifurcation which results in an unsteady asymmetric solution. The results are compared with experiments currently available, and show a good agreement.