• Title/Summary/Keyword: Asymmetric Surface

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In-situ modification of PVC UF membrane by SiO2 sol in the coagulation bath during NIPS process

  • Cheng, Liang;Xu, Zhen-Liang;Yang, Hu;Wei, Yong-Min
    • Membrane and Water Treatment
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    • v.9 no.5
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    • pp.317-325
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    • 2018
  • Polyvinyl chloride (PVC) ultrafiltration (UF) membrane was modified by silica sol in the coagulation bath during non-solvent induced phase separation (NIPS) process. The effects of silica sol concentrations on the morphology, surface property, mechanical strength and separation property of PVC UF membranes were systematically investigated. PVC membranes were characterized by Fourier transform infrared spectroscopy (FTIR), energy dispersive spectroscopy (EDS), scanning electron microscopy (SEM), contact angle goniometry and tensile strength measurement. The results showed that silica had been successfully assembled on the surface of PVC UF membrane. With the increase of silica sol concentration in the coagulation bath, the morphologies of PVC UF membranes changed from cavity structure to finger-like pore structure and asymmetric cross-section structure. The hydrophilicity and permeability of PVC UF membranes were further evaluated. When silica sol concentration was 20 wt.%, the modified PVC membrane exhibited the highest hydrophilicity with a static contact angle of $36.5^{\circ}$ and permeability of $91.8(L{\cdot}m^{-2}{\cdot}h^{-1})$. The structure of self-assemble silica had significant impact on the surface property, morphology, mechanical strength and resultant separation performance of the PVC membranes.

Formation of Hydrophobic Self-assembled Monolayers on Paper Surface with Silanes (실란화 반응에 의한 종이 표면의 소수성 자기조립 단분자막 형성)

  • Oh, Min-Jeong;Lee, Hyoung;Paik, Ki-Hyon
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.42 no.1
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    • pp.64-73
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    • 2010
  • This study was conducted to modify the surface properties of papers by formation of hydrophobic self-assembled monolayer(SAM) on paper surface with silanes. A base paper I(0.5% AKD) and base paper II(1.0-1.5% AKD) were reacted with silanes(PFDTES, DMDCS, MODDCS) by immersion method and vapor deposition method. Hydrophobic SAMs(contact angle value>$120^{\circ}C$) were obtained on all papers after treatment with $10^{\mu}l$ PFDTES for 15min, with $50^{\mu}l$ DMDCS for 30min, with $50^{\mu}l$ MODDCS for 300min. When applying PFDTES to paper surface, lower silane concentration and shorter reaction time were required, whereas MODDCS with long alkyl chain required the longest reaction time of 300min. The st$\ddot{o}$ckight sizing degree of silane treated papers were increased between 105sec(base paper I) and 130sec(base paper II). The wet tensile strength of PFDTES-treated base papers(I, II) increased by 10-34% after SAM formation. However, the wet tensile strength of the DMDCS-treated base paper(I) was found to decrease from 0.067kN/m to 0.038kN/m; this may due to the cellulose degrading as a result of generated hydrogen chloride when hydroxyl group of cellulose were reacted with DMDCS. No apparent changes of PPS roughness on silane-treated papers are observed. The ATR-IR spectrum showed absorption peak located at 465 and 1200cm-1 which can be assigned to the Si-O-C asymmetric stretching and Si-O-C bonds, respectively.

The Influence of the Stiles - Crawford Effect on the Image (Stiles - Crawford 효과가 결상에 미치는 영향)

  • Park, Seong Jong
    • Journal of Korean Ophthalmic Optics Society
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    • v.5 no.2
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    • pp.175-180
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    • 2000
  • The intensity of beam of light entering near the pupil edge is less than when it passes through the center of the pupil, this phenomenon is known as the Stiles-Crawford effect. In this paper, we investigate the variation in the shape of confusion circle when the real amplitude distribution of incident beam in pupil area is shifted to any direction by effects. The shape of confusion circle on the image surface is rotational symmetric when the real amplitude distribution of incident beam in pupil area isn't shifted, and the shape of confusion circle on the image surface is asymmetric as ellipse when the real amplitude distribution of incident beam in pupil area is shifted. The shifted direction of the real amplitude distribution of incident beam in pupil area equals the major axis direction of confusion circle on the image surface. When the shifted direction of the real amplitude distribution of incident beam in pupil area changes from ${\Delta}{\phi}$ to ${\Delta}{\phi}+{\pi}$, the intensity distributions and the shapes of confusion circle on the image surface for ${\Delta}{\phi}$ equals that for ${\Delta}{\phi}+{\pi}$. We know from above results that the influences of ${\Delta}{\phi}+{\pi}$ and ${\Delta}{\phi}+{\pi}$ cases on the image quality of optical system equal.

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Analysis Method of X-Ray Diffraction Characteristic Values and Measured Strain for Steep Stress Gradient of Metal Material Surface Layer (금속재료 표면층의 급격한 응력구배에 대한 X-Ray회절 특성값과 측정된 변형률의 해석방법)

  • Chang-Suk Han;Chan-Woo Lee
    • Korean Journal of Materials Research
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    • v.33 no.2
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    • pp.54-62
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    • 2023
  • The most comprehensive and particularly reliable method for non-destructively measuring the residual stress of the surface layer of metals is the sin2ψ method. When X-rays were used the relationship of εφψ-sin2ψ measured on the surface layer of the processing metal did not show linearity when the sin2ψ method was used. In this case, since the effective penetration depth changes according to the changing direction of the incident X-ray, σφ becomes a sin2ψ function. Since σφ cannot be used as a constant, the relationship in εφψ-sin2ψ cannot be linear. Therefore, in this paper, the orthogonal function method according to Warren's diffraction theory and the basic profile of normal distribution were synthesized, and the X-ray diffraction profile was calculated and reviewed when there was a linear strain (stress) gradient on the surface. When there is a strain gradient, the X-ray diffraction profile becomes asymmetric, and as a result, the peak position, the position of half-maximum, and the centroid position show different values. The difference between the peak position and the centroid position appeared more clearly as the strain (stress) gradient became larger, and the basic profile width was smaller. The weighted average strain enables stress analysis when there is a strain (stress) gradient, based on the strain value corresponding to the centroid position of the diffracted X-rays. At the 1/5 Imax max height of X-ray diffraction, the position where the diffracted X-ray is divided into two by drawing a straight line parallel to the background, corresponds approximately to the centroid position.

PIV Velocity Field Measurements of Flow around a Ship with Rotating Propeller (PIV를 이용한 선박 프로펠러 후류의 속도장 계측)

  • 이상준;백부근
    • Journal of the Society of Naval Architects of Korea
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    • v.40 no.5
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    • pp.17-25
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    • 2003
  • Velocity field behind a container ship model with a rotating propeller has been investigated using PIV (particle image velocimetry) system. Four hundred instantaneous velocity fields were measured at 4 different blade phases and ensemble-averaged to investigate the spatial evolution of vortical structure of near wake within one propeller diameter downstream. The phase-averaged mean velocity fields show the potential wake and the viscous wake formed due to the boundary layers developed on the blade surfaces. The interaction between bilge vortex developed along the hull surface and the tangential velocity component of incoming flow causes to have asymmetric flow structure in the transverse plane.

A Dynamic Characteristics of Horizontal Vortex;Experiment and Numerical Analysis on Rotating Effect (수평 보텍스 링의 동적 특성;회전효과에 대한 실험 및 수치해석)

  • Yeo, Chang-Ho;Park, Jae-Hyun;Suh, Yong-Kweon
    • Proceedings of the KSME Conference
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    • 2004.11a
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    • pp.1466-1471
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    • 2004
  • In this paper, we report the numerical and experimental solutions of the axi-symmetric flows in the axial plane driven by an impingement of fluid from the bottom wall of a circular cylinder. We managed to visualize successfully the flow pattern shown on the vertical plane through the container axis. The numerical results are not show to compare well with the experimental results for the case of the Rossby number 3. Because the numerical results calculate on the assumption that vortex flows are axi-symmetric flow on the other hand real experimental results are show asymmetric flow. The numerical solutions reveal that inertial oscillation plays an important role at small Rossby numbers, or at a larger background rotation.

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Membrane for the Removal of Volatile Organic Compounds from Air (대기중의 휘발성 유기물 제거용 분리막)

  • Deng, S.;Lang, K.;Wang, J.;Tremblay, A.;Matsuura, T.
    • Membrane Journal
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    • v.7 no.1
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    • pp.22-30
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    • 1997
  • Porous asymmetric membranes were prepared from polyetherimide polymer by the phase-inversion technique under different conditions. The performance of the membranes was tested for the removal of acetone vapour from nitrogen. A membrane which showed a high acetone permeability and a high selectivity was chosen and tested further for the separation of different organic vapours from nitrogen. The molecular structure of organic vapours and the selectivity were correlated. A strong correlation was also found between the chromatographic retention time of the organic vapour and the selectivity. These experimental results led to the conclusion that the sorption is the factor governing the separation of volatile organic compounds from nitrogen. A membrane was also prepared by coating the surface of a porous polyetherimide membrane with silicone rubber. The performance of membranes with and without silicone rubber coating was compared.

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Stream Function Wave Theory에 관한 고찰

  • 여운광;편종근
    • Proceedings of the Korea Water Resources Association Conference
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    • 1983.07a
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    • pp.78-79
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    • 1983
  • It is well known that small amplitude wave theory, a first approximation to the complete theoretical description of wave behavior, yields a maximum investment in mathematical endeavor. But, if the wave amplitude is large, the small amplitude considerations are not valid, and finite amplitude wave theory which retains higher-order terms to obtain an accurate representation of the wave motion is numercal theory. The Stream function wave theory, one of the numerical methods, was developed by Dean for use with asymmetric measured wave profiles and with symmetric theoretical wave profiles. Dalrymple later improved the comjputational procedure by adding two Lagrangian constraints so that more efficient convergence of the iterative numerical method to a specified wave heigh and to a zero mean free surface displacement resulted. This paper introduces in details the Dean and Darlymple Stream Function Method in case of the symmetric theoretical wave, because in design purposes, wave height and wave period are given.

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Photoelectic BV Light Curves of Algol and the Interpretations of the Light Curves

  • Kim, Ho-Il
    • Journal of Astronomy and Space Sciences
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    • v.2 no.1
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    • pp.35-45
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    • 1985
  • Standardized B and V photoelectric light curves of Algol are made with the obsevations obtained during 1982-84 with the 40-cm and the 61-cm reflectors of Yonsei University Observatory. These light curves show asymmetry between ascending and descending shoulders. The ascending shoulder is 0.02 mag brighter than descending shoulder in V light curve and 0.03mag in B light curve. These asymmetric light crves are interpreted as the result of inhomogeneous energy distribution on the surface of one star of the eclipsing pair rather than the result of gaseous stream flowing from KOIV to B8V star. The 180-year periodicity, so called great inequality, are most likely the result proposed by Kim et al.(1983) that the abrupt and discrete mass losses of cooler component may be the cause of this orbital change. The amount of mass loss deduced from these discrete period changes turned out to be of the order of $10^{-6}$ - $10^{-5}M_\odot$.

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A study on transverse vibration characteristics of a sandwich plate with asymmetrical faces

  • Ahn, Namshik;Lee, Kangsu
    • Structural Engineering and Mechanics
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    • v.40 no.4
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    • pp.501-515
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    • 2011
  • Sandwich elements have high flexural rigidity and high strength per density. They also have excellent anti-vibration and anti-noise characteristics. Therefore, they are used for structures of airplanes and high speed ships that must be light, as well as strong. In this paper, the Reissner-Mindlin's plate theory is studied from a Hamilton's principle point of view. This theory is modified to include the influence of shear deformation and rotary inertia, and the equation of motion is derived using energy relationships. The theory is applied to a rectangular sandwich model which has isotropic, asymmetrical faces and an isotropic core. Investigations are conducted for five different plate thicknesses. These plates are identical to the sandwich plates currently used in various structural elements of surface effect ships (SES). The boundary conditions are set to simple supports and fixed supports. The elastic and shear moduli are obtained from the four-point bending tests on the sandwich beams.