• Title/Summary/Keyword: Asymmetric Surface

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Preparation, Characterization and Gas Permeability of Asymmetric Porous Membranes of Poly(carbobenzoxyl-L-Lysin) (비대칭 다공성 폴리(카르보벤족시-L-리신)막의 제조, 평가 및 기체투과)

  • Kawai, Tohru;Lee, Young Moo;Fujita, Hiroshi
    • Membrane Journal
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    • v.6 no.2
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    • pp.96-100
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    • 1996
  • In order to improve the permeability of the homogenous membrane of poly(carbobenzoxy-L-lysin)(PCLL), which has very high selectivity of helium gas to nitrogen gas, asymmetric porous membranes of PCLL were prepared by casting from 20% solutions in dioxane and dimethylformamide(DMF), respectively. The membranes were characterized by measuring the number of the pores, the pore size distribution of the surface(the skin layer) and the thickness of the skin layer by scanning electron microscope and transmission electron microscope. The mean pore size and the pore density were lower for the membrane cast from dioxane than that from DMF, which was explained by the mechanism of the formation of the pores in the asymmetric porous membrane. The permeability coefficient observed could be roughly explained by the viscous flow through the skin layer. However, the selectivity observed was against the theory of the viscous flow.

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Asymmetric Yield Functions Based on the Stress Invariants J2 and J3(II) (J2 와 J3 불변량에 기초한 비대칭 항복함수의 제안(II))

  • Kim, Y.S;Nguyen, P.V.;Ahn, J.B.;Kim, J.J.
    • Transactions of Materials Processing
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    • v.31 no.6
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    • pp.351-364
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    • 2022
  • The yield criterion, or called yield function, plays an important role in the study of plastic working of a sheet because it governs the plastic deformation properties of the sheet during plastic forming process. In this paper, we propose a modified version of previous anisotropic yield function (Trans. Mater. Process., 31(4) 2022, pp. 214-228) based on J2 and J3 stress invariants. The proposed anisotropic yield model has the 6th-order of stress components. The modified version of the anisotropic yield function in this study is as follows. f(J20,J30) ≡ (J20)3 + α(J30)2 + β(J20)3/2 × (J30) = k6 The proposed anisotropic yield function well explains the anisotropic plastic behavior of various sheets such as aluminum, high strength steel, magnesium alloy sheets etc. by introducing the parameters α and β, and also exhibits both symmetrical and asymmetrical yield surfaces. The parameters included in the proposed model are determined through an optimization algorithm from uniaxial and biaxial experimental data under proportional loading path. In this study, the validity of the proposed anisotropic yield function was verified by comparing the yield surface shape, normalized uniaxial yield stress value, and Lankford's anisotropic coefficient R-value derived with the experimental results. Application for the proposed anisotropic yield function to AA6016-T4 aluminum and DP980 sheets shows symmetrical yielding behavior and to AZ31B magnesium shows asymmetric yielding behavior, it was shown that the yield locus and yielding behavior of various types of sheet materials can be predicted reasonably by using the proposed anisotropic yield function.

Surface Order of Hexagonal Columnar Mesophases Induced by Molecular Assembly

  • Kim, Sang-Ouk;Ko, Young-Koan;Yoon, Dong-Ki;Kang, Sang-Yoon;Jung, Hee-Tae
    • KIEE International Transactions on Electrophysics and Applications
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    • v.11C no.2
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    • pp.32-36
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    • 2001
  • We investigate the surface order, defects and morphology of hexagonal columnar mesophases, Having a crown ether at one end which forms the center of the column and three fluorinated tails at the other, The orientation of the columns was successfully controlled by surface anchoring: Columns were aligned perpendicularly to an evaporated carbon surface, and the planar alignment do asymmetric compounds was induced by a water surface. TEM images show that there is a high degree of perfection in the packing do the cylinders. The hexagonal columnar mesophase (F(sub)h) was confirmed by direct images and the corresponding electron diffractions, where ordered cylindrical moieties are packed on a hexagonal lattice. The column of 12F8-ABG-15C5 was much straighter, compared with that of 12F8-AG-B15C5, resulting from the degrees of regular stacking. Elementary edge dislocation, grain boundary and +1/2 disclination have been observed, although the defects are generally rare.

Simulations of Capacitively Coupled Plasmas Between Unequal-sized Powered and Grounded Electrodes Using One- and Two-dimensional Fluid Models

  • So, Soon-Youl
    • KIEE International Transactions on Electrophysics and Applications
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    • v.4C no.5
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    • pp.220-229
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    • 2004
  • We have examined a technique of one-dimensional (1D) fluid modeling for radio-frequency Ar capacitively coupled plasmas (CCP) between unequal-sized powered and grounded electrodes. In order to simulate a practical CCP reactor configuration with a grounded side wall by the 1D model, it has been assumed that the discharge space has a conic frustum shape; the grounded electrode is larger than the powered one and the discharge space expands with the distance from the powered electrode. In this paper, we focus on how much a 1D model can approximate a 2D model and evaluate their comparisons. The plasma density calculated by the 1D model has been compared with that by a two-dimensional (2D) fluid model, and a qualitative agreement between them has been obtained. In addition, 1D and 2D calculation results for another reactor configuration with equal-sized electrodes have also been presented together for comparison. In the discussion, four CCP models, which are 1D and 2D models with symmetric and asymmetric geometries, are compared with each other and the DC self-bias voltage has been focused on as a characteristic property that reflects the unequal electrode surface areas. Reactor configuration and experimental parameters, which the self-bias depends on, have been investigated to develop the ID modeling for reactor geometry with unequal-sized electrodes.

The preparation and Characterization of Bismuth Layered Ferroelectric Thin Films by Sol-Gel Process (솔-젤법을 이용한 Bismuth Layered Structure를 가진 강유전성 박막의 제조 및 특성평가에 관한 연구)

  • 주진경;송석표;김병호
    • Journal of the Korean Ceramic Society
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    • v.35 no.9
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    • pp.945-952
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    • 1998
  • Ferroelectric Sr0.8Bi2.4Ta2O9 stock solutions were prepared by MOD(Metaloganic Decompostion) process. The phase transformation for the layered perovskite of the SBT thin films by changing RTA(Rapid her-mal Annealing) temperatuer from 700$^{\circ}C$to 780$^{\circ}C$ were observed using XRD and SEM. Layered perovskite phase began to appear above 740$^{\circ}C$ and then SBT thin films were annealed at 800$^{\circ}C$ for 1hr for its com-plete crystallization. The specimens showed well shaped hysteresis curves without post annealing that car-ried out after deposition of Pt top electrode. The SBT thin films showed the asymmetric ferroelectric pro-perties. It was confirmed that the properties were caused by interface effect to SBT and electrode by leak-age current density measurement and asymmetric properties reduced by post annealing. At post annealing temperature of 800$^{\circ}C$ remanant polarization values (2Pr) were 6.7 9 ${\mu}$C/cm2 and those of leakage current densities were 3.73${\times}$10-7 1.32${\times}$10-6 A/cm2 at 3, 5V respectively. Also bismuth bonding types of SBT thin film surface were observed by XPS.

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Investigation of Asymmetric Aspherical Triangular Prism Optical System for Video Information Display (영상정보디스플레이용 비대칭 비구면 삼각 프리즘 광학계 연구)

  • Youn, Gap-Suck;Yoo, Kyung-Sun;Hyun, Dong-Hoon
    • Journal of the Korean Society of Manufacturing Technology Engineers
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    • v.23 no.6
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    • pp.590-595
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    • 2014
  • We have investigated anamorphic prism lenses with distortions of 0.3-0.5%. We designed the plastic triangular lens and confirmed the minimum resolution using MTF graphs. Also we confirmed that the SVGA optical system can realize a resolution of $864{\times}648$ 56 megapixels. A distortion of about 0.5% aberration appears in the maximum field, and a finite beam aberration of about $15{\mu}m$ is confirmed. We made a mold based on the design data and completed the prism lens through exodus molding. We confirmed the shape error (< $30{\mu}m$) and surface roughness (> 40 nm) of the three sides. We made the video-information-display prototype glasses using prism lens by measuring the performance, we determined the distortion aberration (0.3%) and SVGA resolution. Our approach will enable fabrication of a portable large-screen display device for glasses and sunglasses for the domestic market and, after 2015, for the world market.

Asymmetric Light curves of Contact and Near-Contact Binaries

  • Rittipruk, Pakakaew;Kang, Young-Woon
    • The Bulletin of The Korean Astronomical Society
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    • v.37 no.2
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    • pp.143.1-143.1
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    • 2012
  • We attempt to investigate the main reason of the asymmetrical light curves of contact and near-contact eclipsing binary base on the hypothesis that cool spot was produced on late type star while hot spot was produced from transferred material from their companion star hitting surface. We select 7 eclipsing binary systems which showed asymmetric light curves and mass transfer. Period variation and mass transfer rate were obtained from O-C diagram. Radial velocity curves and light curves of those 7 eclipsing binary system were adopted from available literature in order to obtain the absolute dimension. For four contact eclipsing binary system (AD Phe, EZ Hya, AG Vir and VW Boo), their component stars belonged to spectral type G to K was fitted by cool spot model. While the other two near-contact systems (RT Scl and V1010 Oph) and one contact system (SV Cen) was fitted by cool spot model. The densities of the materials are adopted from stellar model which calculate by stellar structure code. The calculated spot temperature turns out to agree with the photometric solution but there are no correlate between period variation rate and type of spot.

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Dynamic Behaviors of Skewed Bridge with PSC Girders Wrapped by Steel Plate

  • Rhee, In-Kyu;Kim, Lee-Hyeon;Kim, Hyun-Min;Lee, Joo-Beom
    • International Journal of Railway
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    • v.3 no.3
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    • pp.83-89
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    • 2010
  • This paper attempts to extract the fundamental dynamic properties, i.e. natural frequencies, damping ratios of the 48 m-long, $20^{\circ}$ skewed real bridge with PSC girders wrapped by a steel plate. The forced vibration test is achieved by mounting 12 Hz-capacity of artificial oscillator on the top of bridge deck. The acceleration histories at the 9 different locations of deck surface are recorded using accelerometors. From this full-scaled vibration test, the two possible resonance frequencies are detected at 2.38 Hz and 9.86 Hz of the skewed bridge deck by sweeping a beating frequency up to 12 Hz. The absolute acceleration/energy exhibits much higher in case of higher-order twist mode, 9.86 Hz due to the skewness of bridge deck which leads asymmetric situation of vibration. This implies the test bridge is under swinging vertically in fundamental flexure mode while the bridge is also flickered up and down laterally at 9.86 Hz. This is probably by asymmetric geometry of skewed deck. A detailed 3D beam-shell bridge models using finite elements are performed under a series of train loads for modal dynamic analyses. Thereby, the effect of skewness is examined to clarify the lateral flickering caused by asymmetrical geometry of bridge deck.

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Cement/PVDF hollow-fiber hybrid basement membrane: Preparation, microstructure, and separation application

  • Yabin, Zhang;Xiongfei, Du;Taotao, Zhao
    • Membrane and Water Treatment
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    • v.13 no.6
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    • pp.291-301
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    • 2022
  • In this study, cement/PVDF hollow-fiber hybrid membranes were prepared via a mixed process of diffusion-induced phase separation and hydration. The presence of X-ray diffraction peaks of Ca(OH)2, an AFt phase, an AFm phase, and C-S-H phase confirmed the hydration reaction. Good hydrophilicity was obtained. The cross-sectional and surface morphologies of the hybrid membranes showed that an asymmetric pore structure was formed. Hydration products comprising parallel plates of Ca(OH)2, fibrous ettringite AFt, and granulated particles AFm were obtained gradually. For the hybrid membranes cured for different time, the pore-size distribution was similar but the porosity decreased because of blocking of the hydration products. In addition, the water flux decreased with hydration time, and carbon retention was 90% after 5 h of rejection treatment. Almost all the Zn2+ ions were adsorbed by the hybrid membrane. The above results proved that the obtained membrane could be alternative as basement membrane for separation application.

Effect of Bonding Surface Laser Patterns on Interfacial Toughness of GFRP/Al Composite (GFRP/Al 복합재료의 접합부 레이저 패턴이 계면인성에 미치는 영향)

  • Woo Yong Sim;Yu Seong Yun;Oh Heon Kwon
    • Journal of the Korean Society of Safety
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    • v.38 no.2
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    • pp.1-7
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    • 2023
  • Fiber-metal laminates (FMLs) and polymer matrix composites (PMCs) are formed in various ways. In particular, FMLs in which aluminum is laminated as a reinforced layer are widely used. Also, glass fiber-reinforced plastics (GFRPs) are generally applied as fiber laminates. The bonding interface layer between the aluminum and fiber laminate exhibits low strength when subjected to hot press fabrication in the event of delamination fracture at the interface. This study presents a simple method for strengthening the interface bonding between the aluminum metal and GFRP layer of FML composites. The surfaces of the aluminum interface layer are engraved with three kinds of patterns by using the laser machine before the hot press works. Furthermore, the effect of the laser patterns on the interfacial toughness is investigated. The interfacial toughness was evaluated by the energy release rate (G) using an asymmetric double cantilever bending specimen (ADCB). From the experimental results, it was shown that the strip type pattern (STP) has the most proper pattern shape in GFRP/Al FML composites. Therefore, this will be considered a useful method for the safety assessment of FML composite structures.