• 폴리머
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• 제25권2호
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• pp.151-160
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• 2001

결정성 약제가 함침된 생분해성 고분자학이 고분자(poly(d,1-lactide)), 약제(progesterone) 및 용매(dimethylformamide)로 이루어진 고분자용액을 고형화시켜 제조되었다. 용매에 약제 및 고분자를 용해시켜 준비된 제막용액을 유리판 위에 도포한 후, 이로부터 용매를 증발시켜 고형화시키거나, 또는 고분자 및 함침 약제 모두에 비용매로 작용하는 물과 용액 필름에 존재하는 용매를 교환시켜 용액 필름이 응고되도록 하였다. 제조된 고분자막들은 용액 필름의 응고화 경로에 따라 뚜렷하게 다른 형상을 보여주었다. 진공 상태에서 용매의 증발을 통해 응고화되었을 때, 함침 약제인 프로제스테론은 구의 형상을 보여주며 고형화된 고분자 구조에 둘러싸여 막의 내부에 균일하게 분포되었다. 이에 비해, 비용매인 물에 침지시켜 용매와 비용매의 급속한 확산에 의해 응고화시키거나, 대기에 방치시켜 대기에 존재하는 수증기의 흡수에 의해 고분자 희박 지역의 핵 형성을 통한 용액 필름의 액체-액체 상분리를 유도하며 응고화시킨 경우, 함침된 약제는 고분자막 내부에 편상의 결정 구조를 지니며 막 내부에 불균일하게 분포되었다.

• 한국결정학회:학술대회논문집
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• 한국결정학회 2003년도 춘계학술연구발표회
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• pp.8-8
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• 2003

Electron-phonon interaction plays a significant role in forming of colossal magnetoresistance effect (CMR). Polaron formation was observed by neutron diffraction and by extended X-ray absorption fine structure (EXAFS) analysis. Local probe as given by the EXAFS is a useful method to study the polaronic charge and its dependence on temperature and ions size. Here we present the EXAFS study of polaronic charge in La/sub 0.7/Ca/sub 0.3-X/Ba/sub X/MnO₃ compositions. The single phase La/sub 0.7/Ca/sub 0.3-X/Ba/sub X/MnO₃ manganites (x=0; 0.03; 0.06, ..., 0.3) were prepared by ceramic technology [1]. The Curie temperature was determined by extrapolation of the temperature dependence of the magnetization (down to zero magnetization). EXAFS experiments were carried out at the 7C EC beam line of the Pohang Light Source (PLS) in Korea. The atomic pair distribution functions (PDF) were obtained by re-regularization method [2] from filtered spectra. The PDF for the x=0.3 sample showed a single peak function and for x=0.0, 0.03, 0.06, 0.09, 0.12 compositions were asymmetric in agreement with a small Jahn-Teller elongation of two (short and long) bonds of the MnO/sub 6/ octahedron. Dispersion, σ/sub Min-O//sup 2/, and asymmetry, σ/sub Min-O//sup 3/, of the Mn-O bond distances varied significantly with x and showed a maximums at x=0.09. The maximum of σ/sub Min-O//sup 2/ is caused by increase of dynamic rms displacements of the Mn-O distances near the T/sub C/. The observed x dependence of σ/sub Min-O//sup 3/ reflects the reduction of charge carriers mobility at approaching to T/sub C/ from low as well as high temperatures.

• 한국재료학회지
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• 제13권4호
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• pp.233-238
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• 2003

Ferromagnetic tunnel junctions, Ta/Cu/Ta/NiFe/Cu/$Mn_{75}$ $Ir_{25}$ $Co_{70}$ $Fe_{30}$/Al-oxide, were fabricated by do magnetron sputtering and plasma oxidation process. The effect of annealing temperature on the local transport properties of the ferromagnetic tunnel junctions was studied using contact-mode Atomic Force Microscopy (AFM). The current images reflected the distribution of the barrier height determined by local I-V analysis. The contrast of the current image became more homogeneous and smooth after annealing at $280^{\circ}C$. And the average barrier height $\phi_{ave}$ increased and its standard deviation $\sigma_{\phi}$ X decreased. For the cases of the annealing temperature more than $300^{\circ}C$, the contrast of the current image became large again. And the average barrier height $\phi_{ave}$ decreased and its standard deviation $\sigma_{\phi}$ increased. Also, the current histogram had a long tail in the high current region and became asymmetric. This result means the generation of the leakage current that is resulted from the local generation of a low barrier height region. In order to obtain the high tunnel magnetoresistance(TMR) ratio, the increase of the average barrier height and the decrease of the barrier height fluctuation must be strictly controlled.led.

• 대한조선학회논문집
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• 제48권2호
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• pp.128-133
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• 2011

In the present study, the flow fields in between the propeller and the semi-spade rudder are investigated by using PIV technique to find out the influences of both simulated hull wake and propeller wake on the incident flow to the rudder. The velocity fields are measured at the propeller rotation angle of $180^{\circ}$ and the rudder deflection angles of $0^{\circ}$. Flow fields measured at each rudder deflection angle are analyzed in terms of angle-of-attack against the rudder leading edge. The hull wake increases the angle-of-attack more than that in the uniform inflow condition, forming the angle-of-attack of about $20^{\circ}$ at 0.7R(R=propeller radius) position. The distribution of the angle-of-attack is strongly affected by the stagnation point around the leading edge and camber effect of the rudder. These effects provide asymmetric distribution of angle-of-attack with respect to the leading edge of the rudder.

• 멤브레인
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• 제22권3호
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• pp.178-190
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• 2012

침지법 상전이 공정 방법으로 polysulfone (PSF) 분리막을 제조하였다. PSF/NMP/PVP/phosphoric acid의 캐스팅 용액과 물 침전조를 이용하여 분리막을 제조하였다. 증기 유도 상전이법과 비용매 유도 상전이법을 연속하여 적용함으로서 캐스팅 용액에 첨가된 인산의 영향이 분리막의 구조 및 투과량에 미치는 영향을 살펴보았다. 미량의 인산의 첨가로도 평균 기공의 크기, 공극률, 수투과량의 증가를 볼 수 있었다. 또한 분리막의 구조가 치밀한 스펀지 형태의 구조에서 비대칭성이 향상된 구조로 변화함을 확인할 수 있었다. PSF/NMP/PVP/phosphoric acid/BE를 함유한 캐스팅 용액을 준비한 후 동일한 조건으로 증기 유도 상전이법과 비용매 유도 상전이법을 연속하여 적용하여 분리막을 제조하였다. BE의 첨가는 평균 기공의 크기를 거의 0.1 ${\mu}m$ 정도 향상시키는 효과를 가져왔으며 수 투과 유량 또한 10~12 $L/cm^2{\cdot}min{\cdot}bar$ 향상시키는 결과를 나타내었다.

• 수산경영론집
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• 제45권2호
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• pp.29-38
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• 2014

This study is to analyse the timing of the structural change of price volatility and the asymmetry of price volatility during the period before and after the timing of the structural change of price volatility using Jeju Farming Olive Flounder's production area market price data from January 1, 2007 to June 30, 2013. The analysis methods of Quandt-Andrews break point test and Threshold GARCH model are employed. The empirical results of this study are summarized as follows: First, the result of Quandt-Andrews break point test shows that a single structural change in price volatility occurred on May 4, 2010 over the sample period. Second, during the period before structural change, daily price change rate has averagely positive value which means price increase, but during the period after structural change daily price change rate has averagely negative value which means price decrease. Also, daily volatility of price change rate during the period before structural change is higher than during the period after structural change. This indicates that price volatility decreases after structural change. Third, the estimation results of Threshold GARCH Model show that the volatility response against price increase is larger during the period after structural change than during the period before structural change. Also the result shows the volatility response against price decrease is larger during the period after structural change than during the period before structural change. And, irrespective of the timing of structural change, price increase has an larger effect on volatility than price decrease. This means volatility is asymmetric at price increase.

• Bulletin of the Korean Chemical Society
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• 제27권4호
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• pp.568-572
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• 2006

To study the effect of sequence on DNA structure, the two decamer crystal structures one alternating,d(GTACGCGTAC), and the other non-alternating, d(GGCCGCGGCC), were solved. Crystals of both decamers belong to the hexagonal space group $P6_122$, with one strand in the asymmetric unit. The unit cell constants of the alternating decamer are a = b = 39.26 $\AA$, c = 77.70 $\AA$. The structure was refined with 1,828 reflections from 8.0 to 2.0 Aresolution to an R value of 21.3% with all DNA atoms and 63 water molecules. The isomorphous non-alternating decamer had unit cell dimensions of a = b = 39.05 $\AA$, c = 82.15 $\AA$. The structure was refined with 2,423 reflections from 8.0 to 2.0 $\AA$ resolution to a final R value of 22.2% for all DNA atoms and 65 water molecules. Although the average helical parameters of the decamers are typical of A-DNAs, there are some minor differences between them. The helical twist, rise, x-displacement, inclination and roll alternate in the alternating decamer, but do not in the non-alternating decamer. The backbone conformations in both structures show some differences; the residue G(7) of the alternating decamer is trans for $\alpha$ and $\gamma$ while the trans conformations are observed at the residue G(8) of the non-alternating decamer.

• 천문학회보
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• 제41권1호
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• pp.47.3-48
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• 2016

The zodiacal light (ZL), combination of the sunlight scattered by and the infrared light emitted by the interplanetary dust (IPD) particles, changes with time due to the asymmetric distribution of the particles with respect to the Earth's orbit. Especially, the variation of the ZL brightness toward the ecliptic poles are useful to probe the properties of the global distribution of the IPD because we can evade the effect of the small scale structures, such as the asteroidal dust bands. The ecliptic poles are frequently visited by the infrared (IR) space telescopes owing to their sun-synchronous orbits or for specific purposes. We collect and analyze the observations toward the ecliptic poles by COBE/DIRBE, AKARI, and MIRIS, covering the wavelengths from about 1 to $25{\mu}m$. The observed seasonal variations of the ZL are modeled with a simple IPD cloud model to derive cloud parameters. The parameters are compared with those of the empirical cloud models by Kelsall et al. (1998) and Kondo et al. (2016), and the discrepancies are discussed.

• Korean Chemical Engineering Research
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• 제49권4호
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• pp.498-504
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• 2011

본 연구는 폴리이미드와 폴리이서설폰 중공사막을 이용하여 매립가스의 메탄 회수를 위한 메탄과 질소에 대한 투과도와 선택도를 실험하였다. 폴리이미드와 폴리이서설폰 소재를 건/습식 상전이 법을 이용하여 중공사 형태로 제조하고 표면 실리콘 코팅 후 모듈을 제조하였다. 전자주사 현미경 관찰을 이용하여 제조된 중공사 막의 구조가 치밀한 표면과 망상구조의 비대칭으로 형성된 것을 확인하였다. 압력과 온도가 증가함에 따라 메탄과 질소의 투과도는 증가하였으나 선택도($CH_4/N_2$)는 감소하는 것으로 나타났다. Air gap이 증가할수록 메탄과 질소의 투과도는 감소하였으며 용매치환을 한 중공사막의 투과도는 3.2~7.0배 증가하였다.

• 디지털융복합연구
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• 제12권3호
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• pp.149-160
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• 2014

본 연구는 유상증자 공시전 배당정책이 유상증자 공시효과에 어떤 영향을 미치는가를 실증 분석하고자 한다. 이에 따라 2000년 1월부터 2009년 12월까지의 총 683건의 유상증자 자료를 유상증자 공시 이전 배당지급 기업표본과 배당미지급 기업표본으로 구분하여 사건연구를 실행한 결과, 배당지급기업의 유상증자 공시효과가 배당미지급 기업의 유상증자 공시효과에 비하여 더욱 부정적으로 측정되었다. 이 결과는 유상증자공시 전 배당금 지급이 유상증자공시효과에 부정적인 영향을 미치고 있음을 시사한다. 그 이유로써, 배당금 지급으로 인한 외부자금조달에서 발생하는 불필요한 비용(out of pocket cost), 혹은 배당금 지급이 Myers and Majluf(1984)의 역선택효과를 희석시키기 위한 "허위신호"를 본 연구는 제시한다.