• 한국재료학회지
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• 제29권12호
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• pp.774-780
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• 2019

The performance of Li-ion hybrid supercapacitors (asymmetric-type) depends on many factors such as the capacity ratio, material properties, cell designs and operating conditions. Among these, in consideration of balanced electrochemical reactions, the capacity ratio of the negative (anode) to positive (cathode) electrode is one of the most important factors to design the Li-ion hybrid supercapacitors for high energy storing performance. We assemble Li-ion hybrid supercapacitors using activated carbon (AC) as anode material, lithium manganese oxide as cathode material, and organic electrolyte (1 mol L^-1 LiPF₆ in acetonitrile). At this point, the thickness of the anode electrode is controlled at 160, 200, and 240 ㎛. Also, thickness of cathode electrode is fixed at 60 ㎛. Then, the effect of negative and positive electrode ratio on the electrochemical performance of AC/LiMn₂O₄ Li-ion hybrid supercapacitors is investigated, especially in the terms of capacity and cyclability at high current density. In this study, we demonstrate the relationship of capacity ratio between anode and cathode electrode, and the excellent electrochemical performance of AC/LiMn₂O₄ Li-ion hybrid supercapacitors. The remarkable capability of these materials proves that manipulation of the capacity ratio is a promising technology for high-performance Li-ion hybrid supercapacitors.

• 복식문화연구
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• 제23권5호
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• pp.737-754
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• 2015

The structural aesthetics of architecture are becoming an inspirational source for many fashion designers and have been reborn in structural fashion. This study planned to analyze the method of expression of structural aesthetics expressed in modern structural fashion design and the construction method to maximize such an effect on the basis of the construction characteristic of Santiago Calatrava as the representative architect of the structural aesthetic. According to the study, the structural aesthetics expressed in modern structural fashion design are as follows: 1) The symbolical formative aesthetic expressed by symbolical inference and analyzation; 2) the dynamic beauty of physic expressed by visual emphasis and dynamics; and 3) the asymmetric beauty of symmetry expressed by metastasis toward the boundary between balance and imbalance. In addition, to maximize structural aesthetics, we used repetition and a progressive technique based on rhythm, asymmetry, and incision-based variances, such as balance, polygon flux, and inference, and analyzation-based distortion as the structuring principle. The following expression methods for maximizing structural aesthetics were found: 1) symbolical and structural exaggeration of appearance; 2) detail technique expansion and material property diversification; and 3) the three-dimensional transformation of structure and shell expression. Structural fashion design was found to have maximized structural aesthetics by using such expression methods to secure artistic esthetics, destroy existing shapes and patterns, and create unique shapes.

• Korean Chemical Engineering Research
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• 제46권3호
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• pp.521-528
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• 2008

중공사막 접촉기에 적절한 PVDF 중공사막을 상전이 공정에 의하여 제조하였으며, SEM 과 기체투과도에 의하여 그 특성을 분석하였다. 벤치규모 중공사막 접촉기에서 $SO_2$ 제거를 위한 흡수제는 수산화나트륨 수용액을 사용하였다. 기체는 shell side, 액체는 lumen side로 흐르는 counter-current로 실험하였으며, 흡수제의 농도, 기체의 유속, 액가스비, 유입 $SO_2$ 농도에 따른 영향을 알아보았으며, 수학적 모델링에 의해 막 물질전달계수($k_m$)를 측정하였다. 흡수제의 농도와 액기비가 증가함에 따라 기-액 계면에서 충분한 알칼리도가 제공되므로, 액체막 저항이 감소하며, 총괄물질전달 용량계수는 증가하였다. 기체유속이 증가함에 따라 기체막저항은 감소하게 되므로 총괄물질전달 용량계수는 증가하였다.

• 정보처리학회논문지C
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• 제9C권3호
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• pp.313-322
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• 2002

본 논문에서는 IETF CAT Working Group에서 발표한 PKNIT 기반의 인증서비스를 향상시킨 Kerberos 인증 메커니즘을 제안한다. PHNIT기반의 X.509, BS/DNS를 적용하여 영역간의 서비스를 제공하는 인증과 키 교환방식으로 DNS를 통해 외부영역의 위치를 탐색하고 X.509 디렉토리 인증 시스템을 적용, 영역간 체인(CertPath)으로 DNS 서버로부터 공개키를 획득하여 다른 영역을 인증하도록 하였다. 영역간 인증과 키 교환은 Kerberos의 관용키 암호방식을 사용하고 세션 연결은 공개키 방식에 기반을 둔 X.509를 연동시키기 위하여 디렉토리서비스를 이용하였다. 이로써 Client를 확인하기 위한 임의 난수 키($K_{rand}$) 생성과 이로 인한 이중 암호화 과정을 배제하였으며 통신상의 Overload를 감소시키는 효과와 인증절차의 간소화를 가지는 Kerberos 시스템을 설계하였다.

• 한국지진공학회논문집
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• 제12권4호
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• pp.35-44
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• 2008

최근 새로운 지진하중 저항시스템으로 셀프센터링(SCED) 가새 시스템이 개발되었다. 진보된 가새 시스템인 비좌굴 가새(BRB) 시스템과는 달리 큰 지진이 발생한 후 구조물의 잔류 변형을 줄이거나 없앨 수 있는 셀프센터링 능력은 SCED 가새 시스템의 장점이다. 본 논문에서는 SCED 가새와 BRB 가새 시스템의 거동에 비틀림의 영향을 조사하기 위하여 세 가지 다른 편심을 가진 3차원 구조물의 응답을 비선형 동적해석을 수행하여 비교하였다. 해석결과에 따르면 층간변위의 높이방향의 변화는 비정형성에 관계없이 SCED 가새골조의 응답이 BRB 가새골조보다 일정하였으며, 잔류 층간변위와 잔류 회전 응답은 비정형성이 증가함에 따라 감소하였다. 중층 구조물에서 SCED 가새골조의 변형집중계수(DCF)는 BRB 가새골조보다 작은 것으로 나타났다. 이것은 SCED 가새골조가 건물 높이에 따라 보다 일정하게 변형함을 의미한다. DCF의 크기에 대한 비틀림 비정형의 효과는 작았다.

• BMB Reports
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• 제29권1호
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• pp.32-37
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• 1996

The cysteine 43, potentially important in the activity of O-acetylserine sulfhydrylase (OASS) from Salmonella typhimurium, has been changed to serine. This mutant enzyme (C43S) has been studied in order to gain insight into the structural basis for the binding of inhibitor, substrate and product. UV-visible spectra of C43S exhibit the same spectral change in the presence of OAS as that observed with wild type enzyme, indicating C43S will form an ${\alpha}$-aminoacrylate Schiff base intermediate. At pH 6.5, however, the deacetylase activity of C43S is much higher than wild type enzyme indicating that cysteine 43 plays a role in stabilizing the ${\alpha}$-aminoacrylate intermediate. The fluoroscence spectrum of C43S exhibits a ratio of emission at 340 to 502 nm of 16.9, reflecting the lower fluorescence of PLP and indicating that the orientation of cofactor and tryptophan are different from that of the wild type enzyme. The emission spectrum of C43S in the presence of OAS gives two maxima at 340 and 535 nm. The 535 nm emission is attributed to the fluoroscence of the ${\alpha}$-aminoacrylate intermediate. The visible circular dichroic spectrum was similar to wild type enzyme, but the negative effect observed at 530~550 nm and the molar ellipicity values for the mutant are decreased by about 50% compared to wild type enzyme. The circular dichroic and fluoroscence studies suggest binding of the cofactor is less asymmetric in C43S than in the wild type enzyme.

• Bulletin of the Korean Chemical Society
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• 제35권7호
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• pp.2086-2092
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• 2014

Two novel coordination compounds $[Cu_2(pypya)_3(H_2O)_2]{\cdot}Cl{\cdot}(H_2O)_5$ (1) and $\{[Cd(pypya)(ta)_{1/2}]{\cdot}H_2O\}_n$ (2) (Hpypya=2-(3-(pyridin-2-yl)-1H-pyrazol-1-yl)acetic acid, $H_2ta$=terephthalic acid) were synthesized and characterized by single X-ray diffraction. Structure determination reveals that complex 1 and complex 2 crystallize in the triclinic system, with the P-1 space group. The asymmetric unit of 1 contains two Cu(II) ions, and their coordination modes are different. These units of complex 1 are linked together via hydrogen bonds and ${\pi}-{\pi}$ interactions, and the 3D structure of complex 1 was formed. Complex 2, a mononuclear Cd(II) coordination compound, has a 2D structure which was constructed via coordination bonds. TGA and fluorescence spectra analysis of complex 1 and complex 2 have also been studied. In addition, the geometry parameters of complex 1 have been optimized with the B3LYP method of density functional theory (DFT) to explain its coordination behavior. The electronic properties of the complex 1 and ligand Hpypya have been investigated based on the nature bond orbital (NBO) analysis at the B3LYP level of theory. The result verifies that the synergistic effect have occurred in the compound.

• Nuclear Engineering and Technology
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• 제24권3호
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• pp.243-251
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• 1992

소형 냉각재 상실사고시 루프밀봉 형성 및 제거에 대하여 LSTF에서 수행된 실험 SB-CL-18의 결과를 RELAP5/MOD2와 /MOD3를 이용하여 예측하였다. 본 연구는 증기발생기 상향 및 하향 유동에서의 비대칭 냉각재수용에 따른 마노메트릭 유동에 의해 노심노출의 조기발생을 야기시키는 열수력학적 현상을 예측하기 위하여 수행되었다. RELAP5/MOD2를 이용한 해석결과는 루프밀봉 형성 및 제거를 포함하여 감압사고시의 주요 현상을 전반적으로 잘 예측하고 있으나 기초 계산외 결과를 볼 때 현상 및 시간적 순서에 관련하여 몇 가지의 차이가 있었다. RELAP5/MOD3는 RELAP5/MOD2보다 전반적인 현상, 특히 증기발생기 액체수용을 보다 잘 예측하고 있으며, 또 한 RELAP5/MOD3를 이용하여 증기발생기 U자관과 펌프 흡입관의 nodalization수를 늘린 경우는 루프 밀봉제거현상과 시간적 순서를 잘 예측할 수 있었다.

• 공업화학
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• 제19권6호
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• pp.633-639
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• 2008

상전환법을 이용하여 폴리설폰, n-메틸피롤리돈과 톨루엔으로 이루어진 제막용액으로부터 고분자 분리막이 제조되었다. 톨루엔은 폴리설폰에 대한 비용매로서 제막용액에 첨가되었으며, 침지용 비용매로는 이소프로필알코올이 사용되었다. 제조된 모든 분리막은 밀집 형상의 표면층과 스폰지 형상의 하부층으로 구성된 이중구조 형태의 비대칭성 구조를 보였다. 첨가된 톨루엔은 제막용액의 열역학적 성질을 변화시켜 열역학적 상분리를 촉진하는 역할을 할 수 있음을 보였으며, 제조된 분리막은 톨루엔을 첨가에 의해 막의 표면층 두께가 증가하는 특성을 보였다. 분리막의 투과 특성을 측정한 결과, 톨루엔이 첨가되었을 때 밀집 표면층의 두께 증가에도 불구하고 거의 동일한 배제율을 유지하면서 투과플럭스는 5배 이상 증대하는 효과를 보였다.

• 대한방사선기술학회지:방사선기술과학
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• 제25권1호
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• pp.55-62
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• 2002

Aneurysm-mimicking findings were frequently visualized due to hemodynamical causes of dephasing effects around area of A-com artery during magnetic resonance angiography(MRA) and these kind of phenomena have not been clearly known yet. We investigated the hemodynamical patterns of dephasing effect around area of the A-com artery that might be a cause of false intracranial aneurysms on MRA. For experimental study, We used hand-made silicon phantoms of the asymmetric A-com artery as like a bifurcation configuration. In a closed circulatory system with UHDC computer driven cardiac pump system. MRA and fast digital subfraction angiography(DSA) involved the use of these phantoms. Flow patterns were evaluated with axial and coronal imaging of MRA(2D-TOF, 3D-TOF) and DSA of Phantoms constructed from an automated closed-type circulatory system filled with glycerol solution [circulation fluid(glycerol:water = 1:1.4)]. These findings were then compared with those obtained from computational fluid dynamic(CFD) for inter-experimental correlation study. Imaging findings of MRA, DSA and CFD on inflow zone according to the following: a) MRA demonstrated high signal intensity zone as inflow zone on silicon phantom; b) Patterns of DSA were well matched with MRA on trajectory of inflow zone; and c) CFD were well matched with MRA on the pattern of main flow. Imaging findings of MRA. DSA and CFD on turbulent flow zone according to the following: a) MRA demonstrated hyposignal intensity zone at shoulder and axillar zone of main inflow; b) DSA delineated prominent vortex flow at the same area. The hemodynamical causes of signal defect, which could Induce the false aneurysm on MRA, turned out to be dephasing effects at axilla area of bifurcation from turbulent flow as the results of MRA, DSA and CFD.