• Bulletin of the Korean Chemical Society
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• v.30 no.5
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• pp.1021-1025
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• 2009

A novel supramolecular network containing binuclear copper unit $[Cu(phen)_{2}({\mu}-ID\;A)Cu(phen){\cdot}(NO_{3})](NO_{3}){\cdot}4(H_{2}O)$ (1) was synthesized through the self-assembly of iminodiacetic acid ($H_2IDA$) and 1,10-phenanthroline (phen) in the condition of pH = 6. It has been characterized by the infrared (IR) spectroscopy, elemental analysis, single crystal X-ray diffraction, and thermogravimetric analysis (TGA). 1 shows a 2-D supramolecular structure assembled through strong and unique $\pi-\pi$ packing interactions. Density functional theory (DFT) calculations show that theoretical optimized structures can well reproduce the experimental structure. The TGA and powder X-ray diffraction (PXRD) curves indicate that the complex 1 can maintain the structural integrity even at the loss of free water molecules. The magnetic property is also reported in this paper.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2008.06a
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• pp.270-270
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• 2008

We present details of experimental results in the fabrication of high density line patterns, using imprint technique that can provide a simple and comparatively cost-effective manufacturing means. Barrier array structures for display or interconnects for semiconductor applications were the aims of this study. For pattern fabrication, a polymer layer (Ajinomoto GX-13 dielectric film) with a thickness of 38um that can act as either an insulating or a dielectric layer was laminated on a substrate. Fine tracks were then formed using a patterned stamp under isostatic pressure. The line width was ranged between 10 to 60 mm. A self-assembled monolayer (SAM) of fluorinated alkylchlorosilane [$CF_3(CF_2)5(CH_2)2SiCl_3$] as an anti-sticking layer was coated on the surface of the stamp prior to thermal imprint to improve the de-molding characteristic.

• Wind and Structures
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• v.6 no.1
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• pp.53-70
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• 2003

Tsing Ma Bridge in Hong Kong is the longest suspension bridge in the world carrying both highway and railway. It has two H-shape concrete towers, each of which is composed of two reinforced concrete legs and four deep transverse prestressed concrete beams. A series of wind tunnel tests have been performed to measure the aerodynamic coefficients of the tower legs and transverse beams in various arrangements. A 1:100 scaled 3D rigid model of the full bridge tower assembled from various tower components has been constructed for different test cases. The aerodynamic coefficients of the lower and upper segments of the windward and leeward tower legs and those of the transverse beams at different levels, with and without the dummy bridge deck model, were measured as a function of yaw wind angle. The effects of wind interference among the tower components and the influence of the bridge deck on the tower aerodynamic coefficients were also investigated. The results achieved can be used as the pertinent data for the comparison of the computed and field-measured fully coupled buffeting responses of the entire bridge under yaw winds.

• Smart Structures and Systems
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• v.17 no.6
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• pp.1017-1030
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• 2016

This study focuses on the system identification of reinforced concrete bridges using vector autoregressive model (VAR). First, the time series output response from a bridge establishes the autoregressive (AR) models. AR models are one of the most accurate methods for stationary time series. Burg's algorithm estimates the autoregressive coefficients (ARCs) at p-lag by reducing the sum of the forward and the backward errors. The computed ARCs are assembled in the state system matrix and the eigen-system realization algorithm (ERA) computes: the eigenvector matrix that contains the vectors of the mode shapes, and the eigenvalue matrix that contains the associated natural frequencies. By taking advantage of the characteristic of the AR model with ERA (ARMERA), civil engineering can address problems related to damage detection. Operational modal analysis using ARMERA is applied to three experiments. One experiment is coupled with an artificial neural network algorithm and it can detect damage locations and extension. The neural network uses a specific number of ARCs as input and multiple submatrix scaling factors of the structural stiffness matrix as output to represent the damage.

• Earthquakes and Structures
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• v.9 no.5
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• pp.983-997
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• 2015

This research evaluates the soil conditions for seismic stations situated in Romania using the horizontal-to-vertical spectral ratio (HVSR). The strong ground motion database assembled for this study consists of 179 analogue and digital strong ground motion recordings from four intermediate-depth Vrancea seismic events with $M_w{\geq}6.0$. In the first step of the analysis, the influence of the earthquake magnitude and source-to-site distance on the H/V curves is evaluated. Significant influences from both the earthquake magnitude and hypocentral distance are found especially for soil class A sites. Next, a site classification method proposed in the literature is applied for each seismic station and the soil classes are compared with those obtained from borehole data and from the topographic slope method. In addition, the success and error rates of this method are computed and compared with other studies from the literature. A more in-depth analysis of the H/V results is performed using data from seismic stations in Bucharest and a comparison of the free-field and borehole H/V curves is done for three seismic stations. The results show large differences between the free-field and the borehole curves. As a conclusion, the results from this study represent an intermediary step in the evaluation of the soil conditions for seismic stations in Romania and the need to perform more detailed soil classification analysis is highly emphasized.

• Steel and Composite Structures
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• v.22 no.6
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• pp.1337-1358
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• 2016

The current study focuses on the assessment and interface response of reinforced concrete elements with composite materials (carbon fiber reinforced polymers-CFRPs, glass fiber reinforced polymers-GFRPs, textile reinforced mortars-TRM's, near surface mounted bars-NSMs). A description of the transfer mechanisms from concrete elements to the strengthening materials is conducted through analytical models based on failure modes: plate end interfacial debonding and intermediate flexural crack induced interfacial debonding. A database of 55 in total reinforced concrete columns (scale 1:1) is assembled containing elements rehabilitated with various techniques (29 wrapped with CFRP's, 5 wrapped with GFRP's, 4 containing NSM and 4 strengthened with TRM). The failure modes are discussed together with the performance level of each technique as well as the efficiency level in terms of ductility and bearing/ bending capacity. The analytical models' results are in acceptable agreement with the experimental data and can predict the failure modes. Despite the heterogeneity of the elements contained in the aforementioned database the results are of high interest and point out the need to incorporate the analytical expressions in design codes in order to predict the failure mechanisms and the limit states of bearing capacities of each technique.

• Proceedings of the Korean Vacuum Society Conference
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• 2010.02a
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• pp.63-63
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• 2010

Ability to transport extracted carriers from NQDs is essential for the development of most NQD based applications. Strategies to facilitate carrier transport while preserving NQDs' optical characteristics include: 1) Fabricating neat films of NQDs with modified surfaces either by adapting series of ligands with certain limitations or by applying physical processes such as heat annealing 2) Coupling of NQDs to one-dimensional nanostructures such as single walled carbon nanotubes (SWNTs) or various types of nanowires. NQD-nanowire hybrid nanostructures are expected to facilitate selective wavelength absorption, charge transfer to 1-D nanostructures, and efficient carrier transport. Even with the vast interests in using NQD-SWNT hybrid materials in optoelectric applications, still, no reports so far have clearly elucidated the optoelectric behavior when they were assembled on the FET mainly because the complexity involving in both components in their preparation and characterization. We have monitored the optical properties of both components (NQDs, SWNTs) from the synthesis, to the assembly, and to the device. More importantly, by using pyridine molecules as a linker to non-covalently attach NQDs to SWNTs, we were able to assemble NQDs on SWNTs with precise density control without harming their electronic structures. Furthermore, by measuring electrical signals from the fabricated aligned SWNTs-FET using dielectrophoresis (DEP), we were able to elucidate the charge transfer mechanism.

• Korean Journal of Materials Research
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• v.19 no.6
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• pp.300-304
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• 2009

The domain structures of annealed (001)-oriented $Pb(Mg_{1/3}Nb_{2/3})O_3-x%PbTiO_3$ (PMN-x%PT) crystals for x = 10, 20, 30, 35, and 40 at% were investigated by Polarized Optical Microscopy (POM) and Scanning Force Microscopy (SFM) in the piezoresponse mode. Both Polar Nano-Domains (PND) and long strip-like domains were clearly observed. The results also showed how the domain structure changed between phases with an increasing x in the PMN-x%PT crystals and the domain hierarchy on various length scales ranging from 40 nm to 0.1 mm. Distorted pseudo-cubic phase (x < 20%) consisted of PNDs that did not self-assemble into macro-domain plates. The rhombohedral phase (x = 30%) consisted of PNDs that began to self-assemble into colonies along preferred {110} planes. The monoclinic phase (x = 35%) consisted of miniature polar domains on the nm scale, whereas, the tetragonal phase (x = 40%) consisted of {001} oriented lamella domains on the mm scale that had internal nano-scale heterogeneities, which self-assembled into macro-domain plates oriented along {001} the mm scale.

• Journal of the Korean Society for Precision Engineering
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• v.21 no.3
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• pp.38-43
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• 2004

This paper describes the construction of a circular polariscope. Generally, a circular polariscope contains four optical elements and a light source. The first element following the light source is called the linear polarizer. It converts the ordinary light into plane-polarized light. The second element is a quarter wave plate which converts the plane-polarized light into circularly polarized light. Following the quarter wave plate, a specimen made of transparent photoelastic material is located in a loading device. The second quarter wave plate is set and the last element is the analyzer. These polarizing elements, two quarter wave plates and two linear polarizing filters, were purchased from the USA. Frames and other structures for holding polarizing filters were machined and assembled to be rotated. Light box, which includes four incandescent lamps and two sodium-vapor lamps, was made. In order to proof the function of the newly built polariscope, Tardy compensation test was applied to a rectangular shaped specimen made of poly-carbonate material (PSM 1). The error of the fringe constant, which was measured by the newly built polariscope, was within 4.4 percent compared to the standard value of this material. It is possible to make a good quality of polariscope if accurate polarizing filters will be used.

• Wind and Structures
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• v.28 no.3
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• pp.155-170
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• 2019

This paper presents a novel test method for the galloping of iced conductor using wind generated by a moving vehicle which can produce relative wind field. The theoretical formula of transiting test is developed based on theoretical derivation and field test. The test devices of transiting test method for aerodynamic coefficient and galloping of an iced conductor are designed and assembled, respectively. The test method is then used to measure the aerodynamic coefficient and galloping of iced conductor which has been performed in the relevant literatures. Experimental results reveal that the theoretical formula of transiting test method for aerodynamic coefficient of iced conductor is accurate. Moreover, the driving wind speed measured by Pitot tube pressure sensors, as well as the lift and drag forces measured by dynamometer in the transiting test are stable and accurate. Vehicle vibration slightly influences the aerodynamic coefficients of the transiting test during driving in ideal conditions. Results of transiting test show that the tendencies of the aerodynamic coefficient curve are generally consistent with those of the wind tunnel tests in related studies. Meanwhile, the galloping is fairly consistent with that obtained through the wind tunnel test in the related literature. These studies validate the feasibility and effectiveness of the transiting test method. The present study on the transiting test method provides a novel testing method for research on the wind-resistance of iced conductor.