• Proceedings of the Korean Institute of Resources Recycling Conference
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• 2001.05b
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• pp.19-22
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• 2001

In recent years, the creation of waste recycling society has been required to cope with the traditional ways of waste treatments. In accordance with the package recycling law in force, calls for the developments of new waste treatment techniques suitable for 21st century are growing higher. A new ash melting furnace system named Eco Burner Ash Melting Furnace System has been developed. It is a burner type ash melting system in which the fluffs made of the plastics segregated from municipal solid wastes are directly fired at high temperature in the furnace. This system provides an economical ash melting system because plastic wastes or paper scraps that have heretofore been considered hard to recycle are used in compensation for fossil fuel. In this paper, we describe the ash melting test results obtained from a substantiative facility.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 1999.10a
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• pp.65-68
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• 1999

A plasma melting system to vitrify ny ash from MSW(Municipal Solid Waste) incinerator has been operated in SHI(Samsung Heavy Industries) since 1996. Waste feeding rate was 200kg/hr. with maximum working power of 500㎾. Because of high melting temperature of fly ash, bottom ash was used as an additive to decrease melting temperature. Data analysis for discharged slag shows volume reduction up to 30% and no leaching of heavy metals such as Pb, Cd, Cr which were an obstacle for landfill and recycle. Atmospheric pollution gas like nitrogen oxides, carbon monoxide, and PCDD/PCDF were restrained below the regulatory limit.

• 연구논문집
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• s.31
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• pp.5-14
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• 2001

These days, interest in the leaching of hazardous heavy metals to consist of incinerator fly ash is increasing, because the heavy metals that leach from the incinerator fly ash pollute the soil and ground water. Therefore this study was undertaken to crystallize the fly ash and prevent the leaching of hazardous heavy metals from fly ash. The concentrations and the leaching concentration of hazardous heavy metals(Cd, Cr, Hg, Pb, Zn) in the law incinerator fly ash have been measured. The fly ash was melted with two kinds of flux($Na_2CO_3, CaCO_3$) and its add quantity(0, 1, 2, 3 wt%). The crystal structure of melting materials was analyzed by SEM(Scaning Electron Microscope) and X-RD(X-Ray Diffractometer). The leaching test of melting materials was undertaken. And the relation between crystallization of melting materials and flux and leaching concentration. These experiments indicate that the concentration and leaching concentration of heavy metals in incinerator fly ash was much higher than the regulatory standard for leachates in Korea and U.S.A and average concentration of heavy metals in soil. And the crystal structure was better.

• Korean Journal of Materials Research
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• v.12 no.12
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• pp.924-929
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• 2002

To recycle waste materials, this work was focused on development of glass-ceramic from incinerator fly ash with a large content of Cl and its physical property was evaluated. In the process, water washing as a pre-treatment before melting the fly ash was used to remove large amount of Cl component in the ash and to reduce melting temperature. As a result, glass was obtained at below $100^{\circ}C$ compared to the melting temperature before washing the ash. Also, internal crystallization occurred under single stage heat treatment (at $850-950^{\circ}C$ for 20-340min) without adding other materials into the ash. It was shown that the glass-ceramic was composed of four crystals, diopside, anorthite, akermanite, and unknown phase. Hardness of 8.3GPa was found in the glass-ceramic, which is a high value compared to reported others. Thus, the present process suggests that a good glass-ceramic produced from an incinerator ash could be applicable for structural materials in terms of economic and environmental points.

• Korean Chemical Engineering Research
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• v.52 no.2
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• pp.233-239
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• 2014

The slagging which generated from ash deposition on furnace wall and tube in boiler reduces the heat transfer efficiency and damages to safety of boiler. The slag flow behavior in boiler is affected by melting temperature which is related to ash compositions. In this study, the behavior of slag is researched by using ash fusibility test, called TMA (Thermo-Mechanical Analysis). The technique measures the percentage shrinkage as the function of temperature, T25%, T50%, T75%, T90%. These temperatures indicate different stages of melting. Then, the effect of ash chemical compositions measured from XRF (X-ray Fluorescence Spectrometer) to ash fusion temperatures is discussed. Among the chemical compositions, refractory and fluxing influence on ash fusibility is described. High levels of refractory component and limited amount of fluxing components ($Fe_2O_3$, $K_2O$, CaO) increase overall melting temperatures. High $SiO_2/Al_2O_3$ ratio decrease high melting temperatures (T75%, T90%). Meanwhile, the presence of reasonable levels of fluxing components reduces overall melting temperature. A presence of fluxing component such as $K_2O$ and CaO is found to decrease the T25% values significantly. From this research, it is possible to make a reasonable explanation and prediction of ash fusion characteristic from analysis of TMA results and ash chemical compositions.

• Resources Recycling
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• v.13 no.4
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• pp.46-52
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• 2004

The present main research direction of waste treatment is the development of incineration system for low pollution. Also, heat value of waste is increased because of the rising of living standard, environmental consideration and collection of sorted waste for recycling. Therefore, many researches have been continued for solving ash problem including heavy metals, dioxin problem and high energy efficiency by use of high heat value. This study is described for the facilities of pyrolysis system, pyrolysis-melting system, pyrolysis-gasification melting system.

• 한국연소학회:학술대회논문집
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• 2007.05a
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• pp.168-175
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• 2007

Ash melting chamber is one of the key facility of the pyrolysis-melting incineration system, and it should be designed and operated very carefully for avoiding solidification of slag. In this study, an example of numerical and experimental scale-up process of the melting chamber, in which high speed air is injected to the molten slag and generates bubbles, which enhances agitation of the slag and char combustion, is presented. Cold flow test, combustion and melting test in a lab-scale (30 kg/hr) chamber and a pilot scale (200 kg/hr) chamber. Minimum energy for maintaining molten slag is derived, and it was found that the molten slag can be maintained efficiently by concentrating heat into the bubbling slag.

• Proceedings of the IEEK Conference
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• 2001.10a
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• pp.659-663
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• 2001

In Japan, the municipal solid waste, which amounts to 50 million tons, is generated every year and most of it is incinerated. The bottom and fly ashes are disposed to the registered disposal areas under the provisions of The Waste Disposal and Public Cleaning Law. Especially, as the fly ash from the municipal waste incineration (the primary fly ash) contains heavy metals (lead, zinc, etc) and dioxins, it cannot be disposed directly without decontamination, such as moiling, cementation, chelating and dissolving processes provided in the law. However, these procedures for decontamination, except melting, are not enough for dioxins. Even in case of melting, the fly ash from the process (the secondary fly ash) contains high concentration of heavy metals (e.g., Zn; 1-20%, Pb; 1-10%). For these reasons, Metal Mining Agency of Japan (MMAJ), a governmental organization, started a four-year project to develop the treatment technologies of these fly ashes in 1999. The purpose of the project is to establish the integrated technologies to recover the valuable metals from, and to decontaminate, the primary and secondary fly-ashes in the practical scale by utilizing the existing metallurgical processes and facilities, along with the energy saving and the reduction of the environmental impact.

• Proceedings of the Korea Society for Energy Engineering kosee Conference
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• 1998.10a
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• pp.126-133
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• 1998

• 한국연소학회:학술대회논문집
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• 2006.10a
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• pp.168-174
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• 2006

A pilot scale (200kg/hr) pyrolysis melting incineration system is designed and constructed in Korea Institute of Industrial Technology. The incineration process is composed of pyrolysis, gas combustion, ash melting, gas stabilization, waste heating boiler, and bag filter. For each unit process, experimental approaches have been conducted to find optimal design and operating conditions. Especially, a pyrolysis is very important process in that it is a way of energy recirculation and minimizing the waste products. This paper presents major results of the most efficient operating conditions in a pilot scale pyrolysis melting incinerator.