• Bulletin of the Korean Chemical Society
• /
• v.31 no.11
• /
• pp.3145-3150
• /
• 2010

Ruthenium catalysts modified by selenium have been introduced as alternative materials to Pt in Direct methanol fuel cells (DMFCs). RuSe nano-particles were synthesized on the Vulcan XC72R carbon supports via polyol method. The prepared catalysts were electrochemically and physically characterized by cyclic voltammetry (CV,) linear sweep voltammetry, methanol tolerance test, X-ray diffraction (XRD), Transmission electron microscopy (TEM), Energydispersive Spectrometer (EDS) and X-ray photoelectron spectroscopy (XPS). Increasing the Se concentration up to 20 at % increased the electro-catalytic activity for the oxygen reduction. By increasing Se amount, Ru metallic form on the surface was increased. The $Ru_{80}Se_{20}$/C catalysts showed the highest oxygen reduction reaction (ORR) activity and outstanding methanol tolerant property in half cell tests as well as single cell test.

• Bulletin of the Korean Chemical Society
• /
• v.31 no.2
• /
• pp.335-338
• /
• 2010

In this study, the atmospheric plasma treatment with $He/O_2$ was conducted to modify the surface chemistry of carbon fibers. The effects of plasma treatment parameters on the surface energetics of carbon fibers were experimentally investigated with respect to gas flow ratio, power intensity, and treatment time. Surface characteristics of the carbon fibers were determined by X-ray photoelectron spectroscopy (XPS), scanning electron microscope (SEM), Fourier transform infrared (FT-IR), Zeta-potential, and contact angle measurements. The results indicated that oxygen plasma treatment led to a large amount of reactive functional groups onto the fiber surface, and these groups can form together as physical intermolecular bonding to improve the surface wettability with a hydrophilic polymer matrix.

• Bulletin of the Korean Chemical Society
• /
• v.24 no.9
• /
• pp.1265-1268
• /
• 2003

The estimation of retention factors by correlation equations with physico-chmical properties maybe helpful in chromatographic work. The physico-chemical properties were water solubility (S), hydrophobicity (P), total energy ($E_t$), connectivity index 1 ($^1{\chi}$), hydrophilic-lipophlic balance (x) and hydrophilic surface area (h) of isoflavones. The retention factors were experimentally measured by RP-HPLC. Especially, the empirical regulations of water solubility and hydrophobicity were expressed in a linear form. The equation between retention factors and various physico-chemical properties of isoflavones was suggested as $k = a_0 + a_1\;log S + a_2log\;P^Q + a_3(E_t) + a_4(^1{\chi}) + a_5(x) + a_6(h)$, and the correlation coefficients estimated were relatively higher than 0.95. The empirical equations might be successfully used for a prediction of the various chromatographic characteristics of substances, with a similar chemical structure.

• Journal of the Korean Society of Tobacco Science
• /
• v.29 no.2
• /
• pp.74-79
• /
• 2007

This study was conducted to evaluate the prediction of sensory property of smoke from leaf chemical property and characterize leaf chemical components for the best tobacco taste's leaves in flue-cured tobacco. For analytical and sensory evaluations, one hundred and forty grades were used. The major leaf chemical components to predict the sensory property of smoke were nicotine for impact, irritation and off taste & odor, and total sugar/nicotine ratio for tobacco taste. Within ${\pm}20%$ range of difference, the predictable probabilities of sensory property of smoke form leaf chemical property were 80.0% for off taste & odor and $91.4{\sim}96.4%$ for impact, irritation and tobacco taste. As a result of K-means cluster analysis on the basis of tobacco taste, the desirable leaf chemical component contents were $2.77{\sim}3.55%$ in nicotine and $5.1{\sim}6.9$ in total sugar/nicotine ratio. This study suggest that the some regression equations may be useful to predict the sensory property of tobacco smoke from a few selected leaf chemical components in flue-cured tobacco and to select the flue-cured tobacco leaves for enhance the tobacco taste of cigarette.

• Proceedings of the Korean Society of Precision Engineering Conference
• /
• 1997.10a
• /
• pp.907-910
• /
• 1997

With increasing the needs for micro and precision parts, micro machining technology has been studied to fabricate a small part with high density such as electronics, optics, communications, and medicine industry more than before. But there are many problems to be solved requiring a high-level technology. So this research presents the new method to fabricate a small part through applying chemical mechanical micro machining (C3M) for the Al wafer. Al(thickness I ,u m) was sputtered on the Si substrate. Al is widely used as a lightweight material. However form defect such as burr has a bad effect on products. To improve machinability of ductile material, oxide layer was formed on the surface of AI wafcr before grooving by chemical reaction with HN03(10wt%). And then workpieces were machined to compare conventional micro-machining process with newly suggested method at different machining condition such as load and feed rate. To evaluate whether or not the machinability was improved by the effect of chemical condition, such as the size, the width of grooves 'and burr generation were measured. Finally, it is confirmed that C3M is one of the feasible tools for micro machining with the aid of effect of the chemical reaction.

• Bulletin of the Korean Chemical Society
• /
• v.33 no.1
• /
• pp.100-104
• /
• 2012

Thrombin is a serine protease that catalyzes the conversion of soluble fibrinogen to insoluble fibrin, and thus induces physiological and pathological blood coagulation. Therefore, it is important to detect thrombin in blood serum for purposes of diagnosis. To achieve this goal, it has been suggested that a 15-mer aptamer strongly binds with thrombin to form a G-quartet structure of the aptamer. Generally, 5'-end thiol-functionalized aptamer has been used as an anti-thrombin binder. Herein, we evaluate the possibility of utilizing a 3'-SH aptasensor for thrombin detection using SPR spectroscopy, and compare the enhancement of the electrochemical signal of the thrombin-aptamer bound on a porous gold substrate. Although the two aptamers have similar configurations, in SPR analysis, the 3'-SH aptamer was a effective aptasensor as well as 5'-SH aptamer. Results from electrochemical analysis showed that the porous gold substrate acted as a good substrate for an aptasensor and demonstrated 5-fold enhancement of current change, as compared to gold thin film.

• Journal of the Korea Institute of Building Construction
• /
• v.13 no.6
• /
• pp.522-529
• /
• 2013

As concrete forms, panel forms made of plywood used to be widely used, but recently a system form made of aluminum has been broadly adopted because of the advantages it offers in terms of constructability and economy. However, an aluminum form reacts with concrete, which is alkali, and creates hydrogen gas. As a result, air pockets occur on the concrete's surface, and its finishability deteriorates. Therefore, this research analyzed the relationship between the distribution of voids and surface roughness and the damage degree and number of uses of the aluminum form. The analysis of the distribution of voids shows that the number of voids of 0.1~1 mm, which are considered to have occurred because of chemical reaction, was 200~500 on the coating plywood, but was 1 500~2 000 on the aluminum form after 3 uses, and impossible to count after a higher number of uses. Surface roughness was $1.7{\sim}3.2{\mu}m$ on the coating plywood form, but was about $2.6{\mu}m$ after the first use and about $6.8{\mu}m$ after 10 uses, a 2.6-fold increase. Distribution of voids did not show a particular tendency depending upon the degree of damage to the concrete form, but surface roughness showed an increasing tendency as the degree of damage grows. Therefore, when using aluminum forms, surface maintenance should be carried out completely, such as prevention of damages to the form surface coating materials and spreading of separating materials on forms.

• Bulletin of the Korean Chemical Society
• /
• v.35 no.2
• /
• pp.392-396
• /
• 2014

New organic-inorganic composite of 2,4-dihydroxybenzophenone (BP-1) encapsulation into dodecylbenzenesulfonate (DBS) modified layered double hydroxide (LDH) was successfully prepared. The surface, structural, thermal and absorption properties of the BP-1/DBS-LDH nanohybrid was characterized by BET analysis, scanning electron microscopy (SEM), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), thermogravimetric analysis (TG) and diffuse reflectance UV-Vis absorbance spectra (DRUV-vis). The interlayer configuration of composite and the adsorption mechanism of BP-1 on MgAl-DBS-LDH were discussed. It was suspected that DBS anions located in the form of monolayer arrangement with a $75^{\circ}$ anti parallel angle between dodecylbenzenesulfonate chain axis. The diffuse reflectance UV-Vis absorbance results revealed that the UV absorbing wavelength of BP-1/DBS-LDH evidently extends to about 400 nm, which shows that the BP-1/DBS-LDH has the potential application as a UV absorber.

• Environmental Engineering Research
• /
• v.25 no.3
• /
• pp.274-280
• /
• 2020

The marine sediment sustains from the anoxic condition due to increased nutrients of external sources. The nutrients are liberated from the sediment, which acts as an internal source. In hypoxic environments, anaerobic respiration results in the formation of several reduced matters, such as N₂ and NH₄⁺, N₂O, Fe²⁺, H₂S, etc. The experimental results have shown that nitrogen and sulfur played an influential, notable role in this biogeochemical cycle with expected chemical reductions and a 'diffusive' release of present nutrient components trapped in pore water inside sediment toward the bulk water. Nitate/ammonium, sulfate/sulfides, and ferrous/ferric irons are found to be the key players in these sediment-waters mutual interactions. Organonitrogen and nitrate in the sediment were likely to be converted to a form of ammonium. Reductive nitrogen is called dissimilatory nitrate reduction to ammonium and denitrification. The steady accumulation in the sediment and surplus increases in the overlying waters of ammonium strongly support this hypothesis as well as a diffusive action of the involved chemical species. Sulfate would serve as an essential electron acceptor so as to form acid volatile sulfides in present of Fe³⁺, which ended up as the Fe²⁺ positively with an aid of the residential microbial community.

• Bulletin of the Korean Chemical Society
• /
• v.33 no.2
• /
• pp.464-468
• /
• 2012

Three solvent systems, chlorobenzene (ink 1), chlorobenzene/o-dichlorobenzene (ink 2) and chlorobenzene/tetrahydronaphthalene (ink 3), were compared as printable inks for the fabrication of polymer light-emitting diodes (PLEDs) using poly[2-methoxy-5-(2-ethylhexyl-oxyl)-1,4-phenylenevinylene (MEH-PPV) as an emissive material and an inkjet printer (Fujifilm Dimatix DMP-2831). Ink 1 clogged the printer's nozzle and gave non-uniform film. Inks 2 and 3 were used to fabricate PLEDs with ITO/PEDOT:PSS/MEH-PPV/LiF/Al configurations. The best performance (turn-on voltage, 3.5 V; luminance efficiency, 0.17 cd/A; luminance, 1,800 cd/m) was obtained when ink 3 was used to form the emissive layer (thickness, 49 nm), attributable to the better morphology and suitable thickness of the MEH-PPV layer.