• 한국철도학회:학술대회논문집
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• 한국철도학회 2008년도 춘계학술대회 논문집
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• pp.923-931
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• 2008

Coupling rubber pad are important components in railway vehicles. It can be used for reduce shock, vibration and noise. Simple tension, equi-biaxial tension and pure shear test were performed to acquire the coefficient of rubber material which were Mooney-Rivlin and Ogden model. The finite element analysis was executed to evaluate the behavior of deformation and stress distribution by using the commercial finite element analysis code. Useful life evaluation are very important in design procedure to assure the safety and reliability of the rubber components. In this paper, useful life prediction of rubber pad for railway vehicle were experimentally investigated. Accelerated heat-aging test for rubber material were carried. Compression set results changes as the threshold are used for assessment of the useful life and time to threshold value were plotted against reciprocal of absolute temperature to give the Arrhenius plot.

• 한국응용과학기술학회지
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• 제2권2호
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• pp.31-38
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• 1985

The transesterification reaction between ethanolamine and methyl-methacrylate was kinetically investigated in the presence of various metal acetate catalysts at $110^{\circ}C$. The transesterification was found to obey first-order kinetice with respect to the concentration of ethanolamine and methyl-methacrylate, respectively. By the Arrhenius plot, the activation energy has been calculated as 11.9 Kcal with lead acetate catalyst, 14.7 Kcal without catalyst. The reactivities has highest value where the electronegativity and instability constant (Kij) values for the metal acetate catalysts are about 1.6.

• International Journal of Railway
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• 제1권3호
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• pp.122-127
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• 2008

Rubber components are widely used in many application such as vibration isolators, damping, ride quality. Rubber spring is used in primary suspension system for railway vehicle. Characteristics and useful life prediction of rubber spring was very important in design procedure to assure the safety and reliability. Non-linear properties of rubber material which are described as strain energy function are important parameter to design and evaluate of rubber spring. These are determined by physical tests which are uniaxial tension, equi-biaxial tension and pure shear test. The computer simulation was executed to predict and evaluate the load capacity and stiffness for rubber spring. In order to investigate the useful life, the acceleration test were carried out. Acceleration test results changes as the threshold are used for assessment of the useful life and time to threshold value were plotted against reciprocal of absolute temperature to give the Arrhenius plot. By using the acceleration test, several useful life prediction for rubber spring were proposed.

• 한국철도학회:학술대회논문집
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• 한국철도학회 2006년도 추계학술대회 논문집
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• pp.104-111
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• 2006

The non-linear properties of rubber material which are described as strain energy function are important parameter to design and evaluate of rubber spring. These are determined by material tests which are uni-axial tension and bi-axial tension. The computer simulation using the nonlinear element analysis program executed to predict and evaluate the load capacity and stiffness for chevron spring. In order to investigate the heat-aging effects on the rubber material properties, the acceleration test were carried out. Compression set results changes as the threshold are used for assessment of the useful life and time to threshold value were plotted against reciprocal of absolute temperature to give the Arrhenius plot. By using the compression set test, several useful life prediction for rubber material were proposed.

• 대한전기학회논문지:전기물성ㆍ응용부문C
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• 제51권10호
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• pp.473-478
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• 2002

Accelerated thermal aging conditions of polymeric materials were studied by Kissinger equation with TGA analysis. The activation energy was obtained from the slope of straight line of each specimen at the different TGA heating rate. Estimating activation energy from Kissinger equation was acquired, and the resulting calculation showed that 3.59, 3.0, 3.86, 3.73 for the PEEK, polyimide, polysulfone and Viton, respectively. The studied polymeric specimens are used for electrical penetration assembly in nuclear power plant. Accelerated aging time and temperature were also determined corresponding to actual service temperature and 41 years.

• 한국염색가공학회지
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• 제12권5호
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• pp.295-300
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• 2000

The melting behavior of hydrated polyacrylonitrile (PAN) and the rheological properties of hydrated PAN melt were investigated using DSC md modified capillary rheometer. With increasing the water content, Tm of the hydrated PAN was rapidly decreased and finally levelled off above a critical water content. However, the melt viscosity was further decreased even above the critical water content. The hydrated PAN melt showed a typical shear thinning behavior. In arrhenius plot, when the hydrated PAN melt was supercooled, it exhibited a different dependency on temperature from that above melting temperature.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2003년도 추계학술대회 논문집 Vol.16
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• pp.583-586
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• 2003

BiSrCaCuO superconducting thin films have been fabricated by co-deposition using the faraday cup. Despite setting the composition of thin film Bi2212, Bi(2201, 2212, 2223) phase were appeared. It was confirmed the obtained field of stabilizing phase was represented in the diagonal direction of the right below end in the Arrhenius plot of temperature of the substrate and $PO_3$, and it was distributed in the rezone.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2007년도 하계학술대회 논문집 Vol.8
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• pp.484-485
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• 2007

BiSrCaCuO superconducting thin films have been fabricated by co-deposition using the faraday cup. Despite setting the composition of thin film Bi2212, Bi(2201, 2212, 2223) phase were appeared. It was confirmed the obtained field of stabilizing phase was represented in the diagonal direction of the right below end in the Arrhenius plot of temperature of the substrate and $PO_3$, and it was distributed in the rezone.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2009년도 제38회 동계학술대회 초록집
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• pp.143-143
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• 2010

다결정 실리콘 (Poly-Si)은 LPCVD를 이용하여 $750^{\circ}C$에서 증착하였다. 증착된 실리콘 박막은 실란, 수소 및 헬륨 가스를 이용하여 증착하였다. 성장된 poly-Si의 특성은 Raman spectroscopy 및 SEM을 이용하여 분석하였다. 헬륨 가스의 양을 15 sccm으로 고정하고 실란과 수소의 가스비를 60:0에서 20:40까지 가변시켰다. 활성화 에너지는 전류-전압 측정을 통해 Arrhenius plot을 이용하여 계산하였다. 박막 트랜지스터는 quartz 기판 위에 제작되었다. 게이트 절연막으로 TEOS $SiO_2$를 이용하였으며 source 및 drain 전극으로 Al을 이용하였다. 이 때 제작된 박막 트랜지스터의 전류 점멸비, 전계 효과 이동도, SS 및 문턱 전압은 각각 $10^5$, $76\;cm^2/V-s$, 167 mV/decade 및 1.43 V이었다.

• Bulletin of the Korean Chemical Society
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• 제16권10호
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• pp.972-976
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• 1995

A trace amount of 4-biphenylcarboxylate having a pre-twisted biphenyl moiety was attached to a poly(methyl methacrylate) side chain and the fluorescence properties of the chromophore were investigated in various solvents such as ethyl acetate and butyl chloride. At room temperature, the polymer exhibited a distinct red shift of the short wavelength emission (325 nm) and an enhanced emission intensity around 430 nm upon excitation at the absorption red edge. The temperature dependence of the intensity ratio (R) of the 325 nm emission to the 430 nm emission was observed when exciting at the red edge over the temperature range between -20 and 60 ℃. However, the temperature dependence was not observed when exciting at the shorter wavelength. The Arrhenius plot of the R value shows the activation energy of 6.0 kJ/mol which is in good agreement with the energy required for the twist of the biphenyl moiety. Together with the results of red edge excitation effects it was concluded that the pre-twisted geometry of the biphenyl moiety is preserved by the restriction of the polymer chain to facilitate the formation of the twisted intramolecular charge transfer (TICT) state upon excitation.