• 한국수산과학회지
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• 제43권3호
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• pp.195-204
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• 2010

Several quality parameters affecting Alaska pollack, Theragra chalcogramma, were measured and modeled kinetically under storage at different temperatures: the K-value, trimethylamine (TMA), volatile basic nitrogen (VBN), Torry meter, pH, acid value (AV), total viable cell count (TVC), and colony forming units (CFU) of Pseudomonas spp. The off-flavor development time (ODT) was also measured using the R-index sensory test and modeled kinetically. Among the quality parameters, the CFU of Pseudomonas spp. was an indicator of the ODT according to a similarity in the Arrhenius temperature dependence, which was derived as a criterion mathematically. The temperature dependence was represented by the Arrhenius's activation energy ($E_a$). On comparing the $E_a$ of the quality factors and the ODT, the similarity in the temperature dependence was found to be high in the order Pseudomonas spp., pH, VBN, TVC, K-value, TMA, AV, and Torry meter. Therefore, Pseudomonas spp. was identified as the primary indicator of ODT.

• 한국에너지공학회:학술대회논문집
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• 한국에너지공학회 1993년도 추계학술발표회 초록집
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• pp.31-36
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• 1993

Three different methods were employed to measure the degree of aerial oxidation in coal and the resulting oxidation/weathering indices were applied to obtain kinetic parameters of aerial oxidation processes, The index (i.e., slurry pH, Free Swelling Index, weight gain) values were subjected to kinetic analysis based on power-law Arrhenius type reaction model. The results show that activation energy of the aerial oxidation in 20-29$0^{\circ}C$ is in the range of 12-16 ㎉/㏖ and the agreement among three techniques is remarkable. The first order kinetic model is suitable in describing low temperature aerial oxidation process, except in the FSI case where the zero order expression is the best one.

• 대한기계학회논문집B
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• 제20권3호
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• pp.979-987
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• 1996

A theoretical study for the laminar round jet diffusion flame impinging on the wall was carried out to predict the characteristics and structure of impinging jet flame and heat transfer to the wall. Finite chemistry via Arrhenius equation was adopted as the combustion model. All the transport properties were considered as the variable depending on the temperature and composition. For the parametric study, the distance from nozzle to perpendicular wall and Reynolds number at nozzle exit were chosen as the major parameters. As the results of the present study, the characteristics of flow field and the distributions of temperature, density and each chemical species were obtained. The heat transfer rate from flame to the wall and the effective heating area were calculated to investigate the influence of the major parameters on the heat transfer characteristics.

• Bulletin of the Korean Chemical Society
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• 제13권4호
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• pp.385-388
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• 1992

The transition probabilities for the thermal intramolecular electron transfer and the optical intervalence transfer band for a symmetric mixed-valence Cu(I)-Cu(II) compound were used to extract the PKS parameters $\varepsilon$ = -1.15, ${\lambda}$ = 2.839, and ${\nu}g$- = 923 $cm^{-1}$. These parameters determine the potential energy surfaces and vibronic energy levels. Three pairs of vibrational levels are below the top of the energy barrier in the lower potential surface. The contribution of each vibrational state to the intramolecular electron transfer was calculated. It is shown that the three pairs of vibrational states below the top of the barrier are responsible for most of the electron transfer at 261-306 K. So the intramolecular electron transfer in this system is a tunneling process. The transition probability exhibits the usual high-temperature Arrhenius behavior, but at lower temperature falls off to a temperature-independent value as tunneling from the lowest levels becomes the limiting process.

• Bulletin of the Korean Chemical Society
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• 제7권1호
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• pp.29-35
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• 1986

An empirical formula for semiconductive metal oxides is proposed relating nonstoichiometric value x to a temperature or an oxygen partial pressure such that experimental data can be represented more accurately by the formula than by the well-known Arrhenius-type equation. The proposed empirical formula is log x = A + $B{\cdot}1000/T\;+\;C{\cdot}$exp$(-D{\cdot}1000/T)$ for a temperature dependence and $log\;{\times}\;=a\;+b{\cdot}log\;Po_2\;+\;c{\cdot}$exp$(-d{\cdot}log\;Po_2)$ for an oxygen partial pressure dependence. The A, B, C, D and a, b, c, d are parameters which are evaluated by means of a best-fitting method to experimental data. Subsequently, this empirical formula has been applied to the n-type metal oxides of $Zn_{1+x}O,\; Cd_{1+x}O,\;and\;PrO_{1.8003-x}$, and the p-type metal oxides of $CoO_{1+x},\; FeO_{1+x},\;and\;Cu_2O_{1+x}$. It gives a very good agreement with the experimental data through the best-fitted parameters within 6% of relative error. It is also possible to explain approximately qualitative characters of the parameters A, B, C, D and a, b, c, d from theoretical bases.

• 한국기계가공학회지
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• 제19권6호
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• pp.67-72
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• 2020

Life tests are essential in reducing the catastrophic damage caused by the accidents of large machinery such as aircraft and ships. However, life tests are challenging to implement due to the high costs and time required to test the life of large machinery parts. Therefore, it is advantageous and convenient to apply accelerated life test techniques for key components to reduce costs and time. In fact, extensive research has already been conducted on these techniques. However, recently, there have been cases in which an experimental value was applied to the shape parameter of the Weibull distribution used in the reliability test, but the test time was not significantly reduced. Therefore, in this paper, the shape parameters are estimated from the probability density function of the Weibull distribution for the analysis of an accelerated life test for bladder accumulators, which are core components of military helicopters. The test time was derived based on the number of samples and confidence level by substituting it into the test time equation. Next, the accelerated life test time was calculated using the steady-state test time with an acceleration factor obtained from the Arrhenius model. The steady-state life test required approximately 15,000 H, whereas the accelerated life test time for one sample at 100 ℃ was 34% shorter than that of the steady-state life test.

• 한국추진공학회지
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• 제14권5호
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• pp.32-44
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• 2010

고체 추진기관 노즐의 2차원 열반응 및 삭마 해석 코드를 활용하여 노즐 부품의 숯 및 삭마현상을 연구하였다. Arrhenius 식을 이용한 내부 열분해 모델 상수는 TGA(열중량분석기) 실험으로 얻었다. 탄소와 $H_2O$, $CO_2$의 산화반응에 의한 화학적 삭마는 Zvyagin이 제안한 삭마모델 과 반응속도 상수를 이용하여 해석을 수행하였다. 삭마에 의한 경계조건 및 격자 이동은 상용해석 프로그램인 MSC-Marc-ATAS에서 적용되는 Rezoning-remeshing 기법을 사용하였다. 해석된 숯 및 삭마 두께는 연소시험 결과 값과 최대 20% 오차를 보였다. 향후 열방호 시스템의 성능을 모사하기 위하여 내부 온도 및 열유속을 실시간 측정하면 3차원 FEM 통합 열구조 해석에 적용될 것으로 기대된다.

• 자원환경지질
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• 제50권6호
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• pp.509-515
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• 2017

일반적으로 석영은 지각을 구성하는 광물 가운데 가장 많은 부분을 차지하고 있으며, 이러한 석영의 용해와 침전에 대한 이해는 암석의 풍화 매커니즘과 열수작용 및 변성환경에서의 암석과 물의 관계를 규명하는데 매우 중요한 역할을 한다. 본 논문에서는 석영의 용해와 침전에 영향을 미치는 다양한 물리화학적 환경을 수식을 이용해 재정리하였으며, 이전의 연구자들이 발표한 연구결과를 바탕으로 물리화학적 조건하에서의 석영 용해에 대해 이론적 접근을 실시하였다. 본 논문을 통해서 석영의 용해 및 침전이 다양한 환경에 영향을 받으며, 특히 이론적 접근을 통해서 석영에 작용된 압력보다는 주변의 pH 및 온도 조건에 더 큰 영향을 받는다는 것을 확인하였다.

• 한국축산식품학회지
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• 제39권6호
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• pp.903-917
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• 2019

This study aimed to extend the shelf-life of coffee-containing milk beverage by adding Theobroma cacao (cacao nibs) extract. To prepare the beverage sample containing cacao nibs extract, 0.8% cacao nibs hydrothermal extract was aseptically injected. Qualitative changes in the beverage samples, including antioxidant effect, peroxide value (POV), caffeine content, and sensory parameters were monitored regularly during storage at 10℃, 20℃, and 30℃ for 4 wk. The inclusion of cacao nibs extract produced higher antioxidant activity compared to the control. As the storage temperature increased, the POV of all samples increased. Samples with cacao nibs extract generally displayed lower POV than the control. The caffeine content of all samples tended to decrease during storage, with the decrease accentuated by higher storage temperatures. In the shelf-life prediction using the Arrhenius model, the kinetic regressions of the cacao nibs extract-added sample and control were Y_POV=1.2212X-2.1141 (r²=0.9713) and Y_POV=1.8075X-2.0189 (r²=0.9883), respectively. Finally, the predicted shelf-life of cacao nibs-added group and control to reach the quality limit (20 meq/kg POV) were approximately 18.11 and 12.18 wk, respectively. The results collectively indicate that the addition of cacao nibs extract extends the shelf-life of the coffee-containing milk beverage and heightened the antioxidant effect.

• Computers and Concrete
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• 제20권6호
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• pp.635-643
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• 2017

The rehabilitation and strengthening of concrete structures using Fiber-Reinforced Polymer (FRP) materials have been widely investigated. As a priority issue, however, the effect of curing conditions on the bonding behavior between FRP and concrete structures is still elusive. This study aims at developing a prediction model to accurately capture the mode-II interfacial debonding between FRP strips and concrete under different curing conditions. Single shear debonding experiments were conducted on FRP-concrete samples with respect to different curing time t and temperatures T. The J-integral formulation and constrained least square minimization are carried out to calibrate the parameters, i.e., the maximum slip $\bar{s}$ and stretch factor n. The prediction model is developed based on the cohesive model and Arrhenius relationship. The experimental data are then analyzed using the proposed model to predict the debonding between FRP and concrete, i.e., the interfacial shear stress-slip relationship. A Finite Element (FE) model is developed to validate the theoretical predictions. Satisfactory agreements are obtained. The prediction model can be used to accurately capture the bonding performance of FRP-concrete structures.