• 대한기계학회논문집A
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• 제30권12호
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• pp.1534-1542
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• 2006

In this paper, the concept of accelerated life test, which is a popular research field nowadays, is applied to the shot peened material. To predict the efficient and exact room temperature fatigue characteristics from the high temperature fatigue data, the adequate accelerated model is investigated. Ono type rotary bending fatigue tester and high temperature chamber were used for the experiment. Room temperature fatigue lives were predicted by applying accelerated models and doing reliability evaluation. Room temperature fatigue tests were accomplished to check the effectiveness of predicted data and the adequate accelerated life test models were presented by considering errors. Experimental result using Arrhenius model, fatigue limit obtain almost 5.45% of error, inverse power law has about 1.36% of error, so we found that inverse power law is applied well to temperature-life relative of shot peened material.

• 한국수소및신에너지학회논문집
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• 제31권5호
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• pp.419-428
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• 2020

The kinetics of direct methanation over activated charcoal-supported molybdenum catalyst at 30 bar was studied in a cylindrical fixed-bed reactor. When the temperature was not higher than 400℃, the CO conversion increased with increasing temperature according to the Arrhenius law of reaction kinetics. While XRD and Raman analysis showed that Mo was present as Mo oxides after reduction or methanation, TEM and XPS analysis showed that Mo₂C was formed after methanation depending on the loading of Mo precursor. When the temperature was as high as 500℃, the CO conversion was dependent not only on the Arrhenius law but also on the catalyzed reaction by nanoparticles, which came off from the reactor and thermocouple by metal dusting. These nanoparticles were made of Ni, Fe, Cr and alloy, and attributed to the formation of carbon deposit on the wall of the reactor and on the surface of the thermocouple. The carbon deposit consisted of amorphous and disordered carbon filaments.

• 한국식품과학회지
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• 제33권2호
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• pp.221-225
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• 2001

꽃양배추색소추출액의 농도를 1-65%로 조절하여 그 유동 특성을 원뿔형 회전점도계를 사용하여 $20-50^{\circ}C$의 온도범위에서 조사하였다. 꽃양배추색소추출액의 유동특성은 단순 power law model을 사용하여 설명할 수 있었다. 실험범위 내에서 꽃양배추색소추출액의 유동거동지수(n)와 점조도지수(K)는 각각 0.841-0.998 및 $0.008-31.525\;Pa{\cdot}s^n$의 값을 나타냈다. 겉보기점도의 온도의존성은 Arrhenius식에 의해 결정할 수 있었으며, 활성화에너지는 용액의 농도와 전단속도에 따라 9.36-52.48 kJ/mol의 값을 나타냈다. 전단속도 $100\;s^{-1}$에서 측정한 보기점도에 대한 용액의 농도와 온도의 영향을 다음과 같은 단일지수모델식으로 표시할 수 있었다; ${\ln}\;{\eta}_a\;=\;6.11\;-\;3103.94(1/T)\;-\;0.03C$.

• Food Science and Biotechnology
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• 제15권1호
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• pp.33-38
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• 2006

This study was performed to provide basic rheological data of dandelion root concentrates in order to predict their processing aptitude and usefulness as functional foods material. The hot water and 70% ethanol extracts of dandelion root were concentrated at 5, 20, and 50 Brix, and their static viscosity, dynamic viscosity, and Arrhenius plots were investigated. Almost all hot water concentrates showed the typical flow properties of a pseudoplastic fluid, but evaluation using the power law model indicated that the 70% ethanol concentrates showed a flow behavior close to a Newtonian fluid. The apparent viscosity of hot water and 70% ethanol concentrates decreased with increasing temperature. Yield stresses of hot water and 70% ethanol concentrates by Herschel-Bulkley model application were in the range of 0.026 - 1.368 Pa and 0.022 - 0.238 Pa, respectively. The effect of temperature and concentration on the apparent viscosity was examined by Arrhenius equation. The activation energies of hot water and 70% ethanol concentrates were in the range of $8.762-23.778{\times}10^3\;J/mol{\cdot}kg$ and $3.217-20.384{\times}10^3\;J/mol{\cdot}kg$ with increasing concentration, respectively. Storage (G') and loss (G") moduli were generally increased with increasing frequency. For the 70% ethanol concentrates, G" predominated over G' at all applied frequencies and so they showed the typical flow behavior of a low molecular solution. However, for the hot water concentrates, G' predominated over G" at more than 1.9 rad/sec (cross-over point) and so they showed the typical flow behavior of a macromolecular solution.

• 한국세라믹학회지
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• 제36권2호
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• pp.167-171
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• 1999

130$0^{\circ}C$, 10시간 산소 분위기에서 소결한 이산화티탄의 소결체를 이용하여 수소 환원 속도를 조사하였다. 10% 수소(Ar balnce)를 분당 300ml 흘리면서 1200, 1250 및 130$0^{\circ}C$에서 각 4~20시간 환원하여 얻어진 시편의 환원 전과후의 무게 감소 및 환원 층의 두께를 측정하여 수소환원 속도가 평가되었다. 이산화티탄의 소결체가 수소환원 될 때 환원 생성물의 생성은 parabolic rate 법칙을 잘 만족하고 있음을 관찰할 수 있었으며, 이로부터 확산이 환원속도를 지배하고 있음을 알수 있었다. 얻어진 환원속도 상수의 Arrhenius plot로부터 계산된 겉보기 활성화 에너지는 약 210$\pm$10 kJ/mol 이었다.

• 대한기계학회논문집
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• 제14권6호
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• pp.1552-1560
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• 1990

본 연구에서는 로터강(Cr-Mo-V 강)과 저탄소합금강(A517-F강)의 CT시험편을 대상으로 한 고온피로 시험결과를 토대로 차원해석법을 도입시켜 고온하의 균열성장률 을 유도한 다음 온도(T)와 응력확대계수범위(.DELTA.K,T)인 아레니우스 형태의 식을 유도하 였다.그리고 유도된 균열 성장 법칙을 파리스식과 비교 검토하여 본 연구에서 유도 된 이 균열성장법칙의 타당성을 검토하고자 한다.

• Food Science and Biotechnology
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• 제15권2호
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• pp.264-269
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• 2006

Basic rheological data of dandelion leaf concentrates were determined to predict processing aptitude and usefulness of dandelion leaf concentrates as functional food materials. Hot water and 70% ethanol extracts of dandelion leaves were concentrated at 5, 20, and 50 Brix, and their static and dynamic viscosities, and Arrhenius plots were investigated. Most concentrated dandelion leaves extracted with hot water and 70% ethanol showed flow behaviors close to Newtonian fluid based on power law model evaluation. Apparent viscosity of concentrated dandelion leaves extracted with hot water and 70% ethanol decreased with increasing temperature. Yield stresses of concentrated dandelion leaves extracted with hot water and 70% ethanol by Herschel-Bulkley model application were 0.020-0.641 and 0.017-0.079 Pa, respectively. Activation energies of concentrated dandelion leaves extracted with hot water and 70% ethanol were $2.102-32.669{\times}10^3$ and $1.657-5.382{\times}10^3\;J/mol{\cdot}kg$ with increasing concentration, respectively. Loss modulus (G") predominated over storage modulus (G') at all applied frequencies, showing typical flow behavior of low molecular solution. G' and G" of concentrated dandelion leaves extracted with hot water slowly increased with increasing frequency compared to those of concentrated dandelion leaves extracted with 70% ethanol.

• 한국안전학회지
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• 제29권1호
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• pp.7-14
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• 2014

Inverter module, which feeds the converted power to the traction motor for EMU. Consists of the power semiconductors with their gate drive unit(GDU)s and the control computer for driving, voltage, current and speed controls. Electrolytic condenser, connected to the gate drive unit and a core component to drive the power semiconductor, has problems such as reduction in lifetime and malfunction caused by electrical and mechanical characteristic changes from heat generation during high speed switching for generation of stable power. In this study, To check the service life of electrolytic condenser, the test was carried out in two ways. First, In the case of accelerated life testing of condenser, the Arrhenius model is a way of life testing. Another way is to analyze the reliability of the failure data by the method of parametric data analysis. Eventually, life time by accelerated life test than a method of failure data analysis(Weibull distribution) was found to be slightly larger output.

• 대한화학회지
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• 제10권4호
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• pp.153-157
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• 1966

순수한 nickel의 酸化에 대하여 大氣中에서와 各種 酸素壓力下 $500^{\circ}{\sim}800^{\circ}C$에서 石英製 微量天秤을 使用하여 그 速度를 測定하였다. Nickel의 速度常數는 Parabolick rate Law에 의하여 계산하였다. 活性化 에너지는 Arrhenius式에 의하여 구하였으며 ${\Delta}E^*=35.4{\pm}$1.5 Kcal/mole을 얻었다. Nickel酸化에서 酸化速度常數는 酸素壓力의 1/4.93乘에 比例함을 확인하였고 Nickel의 酸化機構는 Oxide Film에 용해되어 과잉으로 存在하는 酸素에 의해서 形成된 陽이온 Vacancy (空位)에 依存한다는 結論에 도달하였다.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2016년도 제50회 동계 정기학술대회 초록집
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• pp.142.1-142.1
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• 2016

We present bulk diffusion rates of hydroxide ions in amorphous solid water (ASW) at 135 ~ 160 K. Previous researches showed that the diffusion mechanism of hydroxide is different from one of hydronium ions, and this implies that they have different diffusion rates. In ultra-high vacuum (UHV) chamber, low-energy scattering (LES) was used to measure ion population and temperature-programmed desorption (TPD) was conducted for measuring ASW thicknesses. To determine the diffusion rates, a simple model for $H_2O/NaOH/H_2O$ sandwich films was developed using Fick's second law. The measured surface population of hydroxide ions as a function of time was well fitted to the model, and the rates were well agreed to an Arrhenius equation.