• 제목/요약/키워드: Arrhenius Relationship

검색결과 93건 처리시간 0.032초

VFD(Vacuum Fluorescent Display) 가속열화시험 응용사례 (Application of Accelerated Degradation Testing for VFD (Vacuum Fluorescent Display))

  • 배석주
    • 한국신뢰성학회지:신뢰성응용연구
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    • 제5권4호
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    • pp.413-425
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    • 2005
  • As an alternative to traditional life testing, degradation tests can be effective in assessing product reliability when measurements of degradation leading to failure can be observed. This article presents an accelerated degradation testing for vacuum fluorescent displays (VFDs). The accelerated degradation model is based on Arrhenius-lifetime relationship for cathode temperatures. We compare the results between accelerated degradation test and test at normal use condition. Accelerated degradation test for display devices is observed as an efficient method to warrantee product reliability to customers, as well as a tool to save time and costs.

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Rubber gaskets for fuel cells-Life time prediction through acid ageing

  • Kim, Mi-Suk;Kim, Jin-Kuk
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2007년도 추계학술대회 논문집
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    • pp.47-51
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    • 2007
  • The present paper reports the life time prediction of Acrylonitrile-Butadiene rubber (NBR) fuel cell gasket materials as a function of operational variables like acid concentration, ageing time and temperature. Both material and accelerated acid-heat aging tests were carried out to predict the useful life of the NBR rubber gasket for use as a fuel cell stack. The acid ageing of the gasket compounds has been investigated at 120, 140 and $160^{\circ}C$, with aging times from 3 to 600 h and increasing acid ($H_2SO_4$) concentrations of 5, 6, 7 and 10 vol%. Material characteristics the gas compound such as cross-link density, tensile strength and elongation at break were studied. The hardness of the NBR rubber was found to decrease with decreasing acid concentration at both 120 and $140^{\circ}C$, but at $160^{\circ}C$ interestingly the hardness of the NBR rubber increased abruptly in a very short time at different acid concentrations. The tensile strength and elongation at break were found to decrease with increase in both the acid concentrate ion & temperature. The life time of the compounds were evaluated using the Arrhenius equation.

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Effect of Temperature Change on the Respiration Characteristics of Vegetables

  • Kawagoe, Yoshinori;Seo, Yasuhisa;Oshita, Sei-Ichi;Sagara, Yasuyuki
    • 한국농업기계학회:학술대회논문집
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    • 한국농업기계학회 1996년도 International Conference on Agricultural Machinery Engineering Proceedings
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    • pp.947-952
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    • 1996
  • The effect of fluctuating temperature on the respiration of vegetables has been investigated. Spinach was selected as the experimental material because of its high respiratory activity and kept under the condition that temperature changed alternately at low and high levels every 4 hours. The low-high level temperature combination was set in $1-10^{\circ}C,{\;}1-20^{\circ}C{\;}and{\;}1-30^{\circ}C$. Respiration was evaluated in terms of quantity of $CO_2$ evolved from spinach. The evolution rate of $CO_2$ was determined by a change in its concentration. The evaluation rate of $CO_2$ followed closely the temperature change. In the temperature combinations at $1-10^{\circ}C{\;}and{\;}1-20^{\circ}C$, the relationship between $CO_2$ evolution rate and temperature was found to be able to express by Arrhenius law, while at $1-30^{\circ}C$, it did not obey the law.

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Aging Effect of Bio-inspired Artificial Basilar Membrane with Piezoelectric PVDF Thin Film

  • Kim, Wan Doo;Park, Su A;Kim, Sang Won;Kwak, Jun-Hyuk;Jung, Young Do;Hur, Shin
    • Elastomers and Composites
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    • 제50권4호
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    • pp.292-296
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    • 2015
  • Biomimetic artificial basilar membrane being a core part of artificial cochlear requires performance evaluation through aging test. To evaluate the aging properties of PVDF piezoelectric membrane used for artificial basilar membrane, its mechanical properties such as tensile strength and elastic modulus and piezoelectric property such as piezoelectric constant were measured. The aging test conditions and acceleration constants were calculated based on Arrhenius model. The changes in tensile strengths and elastic moduli measured were less than 10~20% after aging test equivalent for 10 years. The piezoelectric constants were decreased drastically to 80% of its initial value in the early stage of the aging test and expected to decrease slowly down to 65% over 10 years. The experimental results show the reliability of totally implantable novel artificial cochlear and will contribute its commercialization.

Kinetics of Initial Water Vapor Adsorption by Inonotus obliquus Mushroom Powders

  • Lee, Min-Ji;Seog, Eun-Ju;Lee, Jun-Ho
    • Preventive Nutrition and Food Science
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    • 제12권2호
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    • pp.111-114
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    • 2007
  • Water vapor adsorption kinetics of Inonotus mushroom powders were investigated in temperature and water activity ranges of 20 to 40$^{\circ}C$ and 0.30 to 0.81, respectively. Initial water vapor adsorption rate of mushroom powders increased with increases in temperature and water activity. The temperature dependency of water activity followed the Clausius-Clapeyron equation. The net isosteric heat of sorption increased with an increase in water activity. Water vapor adsorption kinetics of the mushroom powders can be well described by a simple empirical model. Temperature dependency of the reaction rate constant followed the Arrhenius relationship. The activation energy ranged from 56.86 to 91.35 kJ/mol depending on water activity. Kinetic compensation relationship was observed between k$_o$ and E$_a$ with the isokinetic temperature of 790.27 K.

스코치/가황시간의 상관관계에 관한 연구 (Study of the Scorch/Cure time Relationships)

  • 류진호;김창희;오택수
    • Elastomers and Composites
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    • 제31권1호
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    • pp.33-42
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    • 1996
  • NR, NBR, and CR rubber were prepared by mixing filler in various ratios. Their vulcanization characteristics and thermal properties were studied. Vulcanization characteristics were investigated using cure curve that had been obtained from oscillating disk rheometer study. The Arrhenius law is known to describe the relationship between cure time and temperature of most elastomers. Curing could be done by the addition of sulfur, peroxides, and proper acceleratores. The optimum cure time that affects desirable values of modulus and tensile strength of the vulcanizate is taken as t90 as measured by a rheometer. Rubbers were cured in the rheometer at temperatures ranging from $130^{\circ}C\;to\;180^{\circ}C$ in order to check the validity of the curing system used. A linear relationship between ln(ts2) and ln(t90) was found for all elastomers. The term sensitivity has been used to describe the relationship between a change of ts2 to the corresponding change of t90 due to an increment of temperature. This is related to the formula of the compound.

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치환도가 초산 고구마전분의 물리적 특성에 미치는 영향 (Physical Properties of Acetylated Sweet Potato Starches as Affected by Degree of Substitution)

  • 유병승;이혜린
    • 한국식품영양과학회지
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    • 제40권7호
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    • pp.1048-1052
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    • 2011
  • 각기 다른 치환도를 가진 초산 고구마전분 페이스트의 유동특성 및 투과도 그리고, 이들 전분 겔의 냉.해동안정성 및 강도가 치환도의 함수로 분석되었다. 유동특성 측정 결과 power law 모델식과 Casson 모델식에 잘 적용되었으며, 높은 shear-thinning 거동을 가지고 있는 것으로 나타났다. 특정한 온도 범위($25{\sim}70^{\circ}C$)에서 전분 페이스트의 겉보기 점도($\eta_{a,100}$)의 온도 의존성은 Arrhenius 모델식에 잘 적용되었으며 초산 고구마전분이 천연전분에 비해 더 낮은 온도 의존성을 나타내었다. 전분 페이스트 이수현상 측정에서는 초산화에 의해 이수현상이 감소하는 것으로 나타났으며, 치환도가 증가할수록 낮아지는 것으로 나타났다. 겔 강도 측정에서도 초산화에 의해 겔 강도가 감소하는 것으로 나타났으며, 치환도가 증가할수록 겔 강도는 감소하는 것으로 나타났다. 페이스트 투과도(% T) 측정에서 초산전분은 천연전분 보다 투과도가 높은 것으로 나타났다.

다양한 온도, pH, 압력 조건하에서의 석영용해속도에 대한 이론적 접근 (Theoretical Approach of the Quartz Dissolution Rate under Various Temperature, pH and Applied Stress Conditions)

  • 최정해
    • 자원환경지질
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    • 제50권6호
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    • pp.509-515
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    • 2017
  • 일반적으로 석영은 지각을 구성하는 광물 가운데 가장 많은 부분을 차지하고 있으며, 이러한 석영의 용해와 침전에 대한 이해는 암석의 풍화 매커니즘과 열수작용 및 변성환경에서의 암석과 물의 관계를 규명하는데 매우 중요한 역할을 한다. 본 논문에서는 석영의 용해와 침전에 영향을 미치는 다양한 물리화학적 환경을 수식을 이용해 재정리하였으며, 이전의 연구자들이 발표한 연구결과를 바탕으로 물리화학적 조건하에서의 석영 용해에 대해 이론적 접근을 실시하였다. 본 논문을 통해서 석영의 용해 및 침전이 다양한 환경에 영향을 받으며, 특히 이론적 접근을 통해서 석영에 작용된 압력보다는 주변의 pH 및 온도 조건에 더 큰 영향을 받는다는 것을 확인하였다.

꽃양배추 색소 추출액의 유동특성 (Flow Properties of Red Flower Cabbage Pigment Solutions)

  • 임종환;이정주
    • 한국식품과학회지
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    • 제33권2호
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    • pp.221-225
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    • 2001
  • 꽃양배추색소추출액의 농도를 1-65%로 조절하여 그 유동 특성을 원뿔형 회전점도계를 사용하여 $20-50^{\circ}C$의 온도범위에서 조사하였다. 꽃양배추색소추출액의 유동특성은 단순 power law model을 사용하여 설명할 수 있었다. 실험범위 내에서 꽃양배추색소추출액의 유동거동지수(n)와 점조도지수(K)는 각각 0.841-0.998 및 $0.008-31.525\;Pa{\cdot}s^n$의 값을 나타냈다. 겉보기점도의 온도의존성은 Arrhenius식에 의해 결정할 수 있었으며, 활성화에너지는 용액의 농도와 전단속도에 따라 9.36-52.48 kJ/mol의 값을 나타냈다. 전단속도 $100\;s^{-1}$에서 측정한 보기점도에 대한 용액의 농도와 온도의 영향을 다음과 같은 단일지수모델식으로 표시할 수 있었다; ${\ln}\;{\eta}_a\;=\;6.11\;-\;3103.94(1/T)\;-\;0.03C$.

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자동차 엔진 개스킷용 아크릴 고무의 물리적 특성과 수명 예측에 관한 연구 (A Study on Physical Properties and Life Time Prediction of ACM Rubber for Automotive Engine Gasket)

  • 이형석;도종환;안원술;김철
    • Elastomers and Composites
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    • 제47권3호
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    • pp.254-258
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    • 2012
  • 자동차 엔진 개스킷용 아크릴 고무(ACM)의 재료 특성과 수명 예측에 관하여 연구하였다. 클로린 가교사이트를 포함하는 ACM (Chlorine Cure-Site ACM)과 카르복실기 가교사이트를 포함하는 ACM (Carboxyl Cure-Site ACM)을 이용하여 최적상태의 배합물을 제작하여 특성을 살펴보았다. 엔진용 개스킷의 주요한 특성인 열과, 엔진오일에서의 압축영구줄음율을 시험 평가한 결과 Carboxyl Cure-Site ACM 배합물이 상대적으로 더 우수한 것으로 나타났다. Carboxyl Cure-Site ACM 고무 재료에 대한 수명을 예측하기 위해 가속열노화시험을 수행하여 시간-온도 환산식인 아레니우스(Arrhenius) 관계식을 구하였다.