• Title/Summary/Keyword: Aromatic species

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Property of Organic Pollutants in Southwest Coastal Sea (서남해 연안에서의 유기오염물질 특성 규명)

  • Lee Mun-Hee;Park Ji-Yeong;Han Sang-Kuk
    • Proceedings of KOSOMES biannual meeting
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    • 2004.05b
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    • pp.85-88
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    • 2004
  • In this study, properties of organic pollutans were examinated using simultaneous determination from Kwang-Yang Bay, Ka-Mac Bay, Ywan-Do, Hae-Nam, Young-Kwang, Mokpo in Southwest coastal sea. As result, score species of organic pollutants detected coastal sea during summer-winter season Many species of Phenols and Phthalates detected regardless of season in several point Especially, Pesticiides reprosented during summer between Kwang-Yang Bay, Ywan-Do, Hae-Nam. But in winter-season, many species of Aromatic compounds analyzed out in Kwang-Yang Bay. This results consider by pollution of organic pollutans from ship, flow hrbor, estuary, bay.

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Acute Toxicity of Heavy Metals, Tributyltin, Ammonia and Polycyclic Aromatic Hydrocarbons to Benthic Amphipod Grandidierella japonica

  • Lee, Jung-Suk;Lee, Kyu-Tae;Park, Gyung-Soo
    • Ocean Science Journal
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    • v.40 no.2
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    • pp.61-66
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    • 2005
  • Benthic amphipod, Grandidierella japonica widely inhabits the Korean coastal waters and is developed as a standard test species for sediment toxicity tests. We exposed G. japonica to various pollutants including 4 kinds of inorganic metals (Ag, Cd, Cu and Hg), tributyltin [TBT], ammonia and 7 polycyclic aromatic hydrocarbon (PAH) compounds (acenaphthene, chrysene, fluoranthene, fluorene, naphthalene, phenanthrene and pyrene) to estimate the no observed effect concentration (NOEC) and the median lethal concentration (LC50) of each pollutant during the 96-hour acute exposure. Among all tested pollutants, TBT was most toxic to G. japonica, and Rg was most toxic among inorganic metals. The toxicity of pyrene to G. japonica was greatest among PAH compounds, followed by fluoranthene, phenanathrene, acenaphthene, fluorene and naphthalene. The toxicity of PAH compounds was closely related to their physico-chemical characteristics such as $K_ow$ and water solubility. G. japonica responded adequately to pollutant concentrations and exposure durations, and the sensitivity of G. japonica to various inorganic and organic pollutants was generally comparable to other amphipods used as standard test species in ecotoxicological studies, indicating this species can be applied in the assessment of environments polluted by various harmful substances.

Changes of General Components and Aromatic Constituents in Codonopsis lanceolata Grown at The Native and Cultivated Area (재배장소에 따른 더덕의 일반성분과 향기성분의 조성변화)

  • 이승필
    • Korean Journal of Plant Resources
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    • v.9 no.3
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    • pp.230-238
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    • 1996
  • The experiment was carried out to find aromatic constituent composition of Codonopsis lanceolata species grown in the native(Mt. lrwol, Youngyang, Kyungpuk Province) and the cultivated(Andong, Kyungpuk Province) areas from 1994 to 1995. The results were as follows : Air temperature and soil temperature at the native area were lower to $2{\sim}3^{\circ}C$, and to $2^{\circ}C$ than the cultivated area. Organic matter contents of plant grown at the native area higher than that of plants at the cultivated area by 4.8%. Crude protein content was higher in plant grown at native area than the plant grown in wild area but in case of crude saponin, plants grown at wild area was higher than that of native area. For inorganic element contents. K content is much higher than in the domesticated area as compared with wild area above ten over. And other elements such as Cu, Mn, Na and Mg were not remarkably different in contents. In the free amino acid compositions, argine was highest compared with other free amino acids, and Arginine content was higher in dometicated area. Recovery yield of essential oil of wild species grown at the cultivated showed 0.005%, but domesticated species was 0.004%. But both species at the native area were the same by 0.004%. Although composition of aromatic constituents in the two areas and species varied, total aromatic constituent was 21 kinds. Most aromatic constituents were aliphatic alcohols such as 1-hexanol, eis-3-hexanol, and trans-2-hexanol occupied by approximately 90% over. But three constituets as amylalcohol, furfuryl acetate, and 2-methoxy-4-vinyl phenol(MVP) were detected only in domesticated species.

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Distribution of Polycyclic Aromatic Hydrocarbon at Kongsfjorden in Spitsbergen, Svalbard Islands (북극 스발바드 군도 스피츠베르겐섬 콩스피요르드에서의 다환 방향족 탄화수소화합물의 분포 특성)

  • Kim, Gi Beom;Ha, Seong Yong;An, In Yeong
    • Journal of Environmental Science International
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    • v.13 no.9
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    • pp.819-826
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    • 2004
  • In order to elucidate the polycyclic aromatic hydrocarbon concentration and its origin in arctic area, four arctic brown algae (Laminaria saccharina, L. digita, Alaria esculenta, Desmarestia aculeata), one marine invertebrate (Echinoidea) and sediments were collected from Kongsfjorden in Spitsbergen from the late July to early August, 2003. In case of macroalgae, the young blade part above growth point and the old stipes and blades beneath growth point were separated and analyzed for polycyclic aromatic hydrocarbons (PAHs) in an attempt to check the mechanism of uptake in macroalgae to accumulate PAH. There was no difference in PAH concentrations between sampling sites (Stations B and C), species, and blades beneath and above growth point. PAH concentrations in all samples collected in this study were relatively higher than those reported in other areas of arctic. Especially, station C, which is known as an unpolluted area, showed 10 times higher PAH concentration (8,765 ng/g) in sediment than station A (694 ng/g) around harbor. In addition high PAH concentration, station C had very higher proportion of methylated PAH to parent PAH in sediment than station A. Source analysis using PAH isomer pair ratios as indicators showed that Kongsfjorden area seemed to be relatively contaminated with PAH derived from direct petroleum input.

Comparative Study of Volatile Organic Compound Concentrations in the Yochon Industrial Estate during Spring and Fall (여천 공업단지 봄, 가을 대기 중 휘발성 유기화합물 농도 비교 연구)

  • 김영성;송철한
    • Journal of Korean Society for Atmospheric Environment
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    • v.14 no.2
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    • pp.153-160
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    • 1998
  • The concentrations of volatile organic compounds (VOCs) in the atmosphere were measured from the Yochon Industrial Estate and compared with those from Tongkwangyang and Seoul. The first important phenomenon observed in the air of Yochon was high concentrations of alkenes and in particular, ethylene and propene. For most dominant species, their means and standard deviations were high simultaneously. Concentrations of several major aliphatic species exhibited a similar pattern of diurnal variation, however, with different species combination on each day. Concentrations of several hazardous aromatic species also exhibited a similar pattern of diurnal variation on the same day, which was different from that observed in the diurnal variation of major aliphatic species. It was interpreted that some species were intermittently released from relevant processes. It was also understood that high concentrations and variations of VOC species in Yochon were localized and not related to high average concentrations of ozone in Yochon and Tongkwangyang areas.

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Dietary Intake and Potential Health Risk of Polycyclic Aromatic Hydrocarbons (PAHs) via Various Marine Organisms in Korea

  • Moon Hyo-Bang;Lee Su-Jeong;Park Jong-Soo
    • Fisheries and Aquatic Sciences
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    • v.7 no.3
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    • pp.141-147
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    • 2004
  • Sixteen polycyclic aromatic hydrocarbons (PAHs) were analyzed in seventy marine organisms (40 species) from the Korean coast. PAHs were present in all the organisms. The level of total PAHs in the organisms varied from 0.45 to 224 ng/g dry weight and the carcinogenic PAHs varied from 0.05 to 49.8 ng/g dry weight. The PAHs residues according to the marine organisms showed a highest content in bivalve species, and followed by crustaceans, cephalopods, fish and gastropods. Human dietary intake of total PAHs through marine organism in Korea was estimated to be 4.12 ng/kg body weight/day and 0.67 ng/kg body weight/day for carcinogenic PAHs. The relative contributions of individual species to the total dietary intake of PAHs were in the order of bivalves $(53.4{\%})$, fish $(21.9{\%})$, crustaceans $(15.3{\%})$, cephalopods $(8.8{\%})$ and gastropods $(0.6{\%})$. Daily dietary intake of $PAH_{TEQ}$ expressed as a TEQ value was estimated to be 0.13 pg TEQ/kg body weight/day, which did not exceed a tolerable daily intake (TDI) proposed by the KFDA and the WHO as well as the UK toxicity committee. Lifetime cancer risk due to ingestion of marine species by the Korean adult was evaluated using the equation estimating exposure of food ingestion. Although approximately $23{\%}$ of cumulative frequency of the sampled marine species exceeded the cancer risk guideline, lifetime cancer risk associated with marine organism consumption was negligible. Results indicate that dietary intake of PAHs through the consumption of the Korean marine organisms seems to be safe for human ingestion with negligible cancer risk.

Basauxia and Ashtaangam of Hyphorrycetes from Southeast Asia.

  • Subramanian, C.V.
    • The Korean Journal of Mycology
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    • v.20 no.4
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    • pp.281-284
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    • 1992
  • Two interesting new hyphomycetes collected on rachis of an unidentified palm (Palmao) from Malayasia are described and their taxonomy is discussed in this paper. One of them is unique in producing basauxic conidiophores from conidiophore mother cells that are sessile, simple, cylindrical or cupulate, and solitary, gangliar, acrogenous, dry phragmoconidia. It is classified in a new genus Basauxia, as a new species, B. pulchra. The other hyphomycete is also unique in producing characteristic solitary, eight-celled, eight-armed gangliar conidia on simple conidiophores. A new genus, Ashtaangam is proposed for it in which it is placed as a new species, A. sundaram.

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Induction of Reactive Oxygen Species and Malignant Transformation by Tcdd Through Metabolic Formation of Catechol Estrogens

  • Na, Hye-Kyung;Chen, Zhi-Hua;Kim, Jung-Hwan;Surh, Young-Joon
    • Proceedings of the Korean Society of Toxicology Conference
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    • 2003.10b
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    • pp.188-188
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    • 2003
  • 2,3,7,8-Tetrachlorodibenzo-p-dioxin (TCDD), a prototype of halogenated aromatic hydrocarbons, is a persistent environmental contaminant and one of the most powerful tumor promoters. The molecular mechanism underlying induction of tumor promotion by TCDD has not been elucidated.(omitted)

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Monitoring of Polycyclic Aromatic Hydrocarbons in Sediments and Organisms from Korean Coast

  • Moon Hyo-Bang;Choi Hee-Gu;Kim Sang-Soo;Jeong Seung-Ryul;Lee Pil-Yong;Ok Gon
    • Fisheries and Aquatic Sciences
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    • v.4 no.4
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    • pp.219-228
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    • 2001
  • Surface sediments (0- 5 cm), mussels (Mytilus coruscus and M. edulis) and oysters (Crassostrea gigas) were sampled at 20 stations in Korean coast during a period of February to July 2000. Samples were analyzed for polycyclic aromatic hydrocarbons (PAHs) content using gas chromatography coupled to mass spectrometer detector (GC/MSD). The sediment $\sum PAH$ concentration varied from 7 to 1,214 ng/g dry weight and the level of carcinogenic PAHs of six species ranged from 1 to 563 ng/g dry weight in surface sediments. In organisms, the levels of $\sum PAH$ were in the range of 63-876 ng/g dry weight and the concentrations of carcinogenic PAHs of six species were in the range of 4-582 ng/g dry weight. The highest PAH concentrations in sediments and organisms were in samples from Station 5 in Pohang coast and Station 8 in Jinhae coast, respectively. $\sum PAH$ concentrations in sediments and organisms collected from Korean coast were slightly low or comparable to those in other countries. The contribution of ring aromatic groups to sum of 16 PAHs in sediments and organisms showed a similar pattern for most stations. In sediments, the predominant contributions were four and five ring aromatics like fluoranthene, pyrene, benzo[a]anthracene, chrysene, benzo[b]fluoranthene, benzo[k]fluoranthene and benzo[a]pyrene. In the organisms, four ring aromatics like fluoranthene, pyrene, benzo[a]anthracene and chrysene were predominant PAH species. Several molecular indices such as phenanthrene/anthracene, fluoranthene/pyrene and LMW/HMW ratio were used to identify the origin of PAH contamination in sediments. The results indicate that PAHs of Korean coast were mainly of pyro1ytic contaminants with slight petrogenic input. A high correlation within individual PAH compound in marine sediments was observed, while correlation in organisms showed a highly significant relationship for heavier molecular weight PAHs.

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A Preliminary Statistical Stduy of Polycyclic Aromatic Hydrocarbons and Inorganic Elements Data for Extimation Ambient PM-10 Sources -Near the Huge Young-Tong Construction Area during Feb. 1996 to June 1996- (대기 중 PM-10의 오염원 추정을 위한 다환방향족탄화수소와 무기원소자료의 예비통계분석 -1996년 2월~6월까지 대규모 영통건설지역 주변을 중심으로-)

  • 손정화;황인조;김동술
    • Journal of Korean Society for Atmospheric Environment
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    • v.16 no.1
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    • pp.11-22
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    • 2000
  • Polycyclic aromatic hydrocarbons(PAHs) have known as potentially hazardous air pollutants(HAPs0 to human health because of its carcinogenic and mutagenic behaviors. The purpose of this study was to determine the level of 6 PAHs(Fluoranthene, Pyrene, Benzo[a]anthracene, Chrysene, Benzo[b]fluoranthene, and Benzo[a]pyrene) as well as 10 inorganic elements(Cr, Na, K, Zn, Pb, Fe, Cu, Ti, Al and Cd) in the ambient PM-10. The total of 115 samples had been collected from February, 1996 to June, 1996 on quartz fiber by a PM-10 high volume air sampler near the Yong-Tong Apartment complexes. A statistical analysis was performed for the PAHs and inorganic elements data set using a principal component analysis in order to identify qualitatively the potential sources of PM-10. A total of 6 principal components were separated by intensive data pretrement and transformation processes, such as soil, refuse incineration, oil burning, coal burning, field burning, vehicle emission sources. The results showed that PAHs were associated with various burning activities like refuse and field burning, coal burning, and oil burning emissions in the study area. These derived sources were well matched with the previously known source profiles in terms of compositonal order and level of measured species. The combination data set consisted of both organic and inorganic species might provide more powerful source signature and might increase the number of potentially derived sources than PAHs or inorganic data alone.

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