• Title/Summary/Keyword: Aromatic species

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솔잎 퇴적물에서 추출한 방향족 탄화수소물질 분해 박테리아의 동정 (Characterization of Aromatic Hydrocarbon Degrading Bacteria Isolated from Pine Litter)

  • 송윤재
    • 한국미생물·생명공학회지
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    • 제37권4호
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    • pp.333-339
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    • 2009
  • 새로운 pine needle agar를 이용하여 15종의 박테리아를 솔잎퇴적물에서 추출하여 동정하였다. 이들 박테리아는 lignin biodegradation에서 주로 유도되는 방향족 탄화수소물질을 $\beta$-ketoadipate pathway의 ortho-cleavage를 이용하여 분해하는 것으로 밝혀졌다. 나아가서 이들 박테리아에 의한 여러 종의 방향족 탄화수소물질 분해에 관해서도 조사하였다. 본 연구는 솔잎 퇴적물에 존재하는 박테리아 종들이 방향족 탄화수소물질을 분해할 수 있는 대사능력을 가지고 있다는 것을 검증하였다.

Complexation of Co-contaminant Mixtures between Silver(I) and Polycyclic Aromatic Hydrocarbons

  • Yim, Soo-Bin
    • 한국환경과학회지
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    • 제12권8호
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    • pp.871-879
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    • 2003
  • The complexation of co-contaminant mixtures between Ag(I) and polycyclic aromatic hydrocarbon (PAH) molecules (naphthalene, pyrene, and perylene) were investigated to quantify the equilibrium constants of their complexes and elucidate the interactions between Ag(I) and PAH molecules. The apparent solubilities of PAHs in aqueous solutions increased with increasing Ag(I) ion concentration. The values, K$_1$ and K$_2$ of equilibrium constants of complexes of Ag(I)-PAHs, were 2.990 and 0.378, 3.615 and 1.261, and 4.034 and 1.255, for naphthalene, pyrene, and perylene, respectively, The K$_1$and K$_2$ values of PAHs for Ag(I) increased in the order of naphthalene < pyrene < perylene and naphthalene < pyrene ≒ perylene, respectively, indicating that a larger size of PAH molecule is likely to have more a richer concentration of electrons on the plane surfaces which can lead to stronger complexes with the Ag(I) ion. For the species of Ag(I)-PAH complexes, a 1:1 Ag(I) : the aromatic complex, AgAr$\^$+/, was found to be a predominant species over a 2:1 Ag(I) : aromatic complex, Ag$_2$Ar$\^$++/. The PAH molecules with four or more aromatic rings and/or bay regions were observed to have slightly less affinity with the Ag(I) ion than expected, which might result from inhibiting forces such as the spread of aromatic $\pi$ electrons over o wide molecular surface area and the intermolecular electronic repulsion in bay regions.

브루나이 열대우림 내 주요 3개 수종 고사목의 초기 질량 감소율과 탄질율 변화 (The initial mass loss rates and the changes in carbon/nitrogen ratio of dead woods for the three dominant tree species in tropical rainforests of Brunei Darussalam)

  • 노유진;장민주;손요환
    • 환경생물
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    • 제39권2호
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    • pp.218-224
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    • 2021
  • 본 연구에서는 열대우림인 브루나이 MDF와 PSF의 주요 수종(D. aromatic, D. rappa, C. arborescens)을 대상으로 초기 분해 단계의 수종별 질량 감소율과 탄질율의 변화를 파악하였다. 2019년 5월에 총 48개의 고사목 시료(15 cm ×4.8 cm ×5 cm)를 산림 지표면에 배치하고 16개월 후 수거하였다. 분해 전 수종별 고사목의 밀도(g cm-3)는 0.64±0.01 (D. aromatic), 0.60±0.00 (D. rappa), 0.44±0.02 (C. arborescens) 등이었으며, 16개월 동안 수종별 연간 질량 감소율(%)은 6.37 (D. aromatic), 8.17 (D. rappa), 18.53 (C. arborescens) 등으로 나타났다. 부후등급은 C. arborescens에서 III등급이 약 25%로 높았으며 흰개미의 분해 흔적이 나타났다. 한편, 16개월 후 탄질율은 D. aromatic과 D. rappa에서 통계적으로 유의하게 감소하였으나, C. arborescens에서는 감소하는 경향이 유의하지 않았다. 이러한 연구 결과는 열대우림 내 고사목의 초기 분해는 밀도와 같은 수종의 물리적 특성에 따라 차이가 나타날 수 있으며, 주요 분해자의 유형에 따라 탄질율의 변화에도 상대적으로 차이가 있을 수 있음을 시사하는 것이다.

In Vitro Mechanistic Studies of Photogenotoxicity of Polycyclic Aromatic Hydrocarbons

  • Park, Jong-Hoon
    • 한국독성학회:학술대회논문집
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    • 한국독성학회 2003년도 추계학술대회
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    • pp.106-106
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    • 2003
  • Many polycyclic aromatic hydrocarbons (PAH) are acutely toxic to fish and other aquatic organisms in the presence of environmentally realistic intensities of solar ultraviolet radiation (SUVR). The phototoxicity of polycyclic aromatic hydrocarbons (PAHs) occurs through photodynamic activation of PAH compounds. Oxygen molecules react as quenchers with excited triplet states of PAHs producing reactive oxygen species (ROS).(omitted)

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Accumulation and Characterization of Polycyclic Aromatic Hydrocarbons in Seafood from the Coastal Areas of Korea

  • Moon Hyo-Bang;Choi Hee-Gu;Kim Sang-Soo;Lee Pil-Yong
    • Fisheries and Aquatic Sciences
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    • 제5권2호
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    • pp.127-135
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    • 2002
  • Twenty seafood samples, which are common edible species and commercially important items in Korea, were purchased at the local fisheries markets and were analyzed for polycyclic aromatic hydrocarbons (PAHs) using gas chromatography coupled to mass spectrometer detector (GC/MSD). The levels of sixteen PAHs in seafood from Korean coasts were 161 to 2,243 pg/g wet weight. The highest concentration was found at saury (Coloabis saira) and the lowest level was found at jacopever (Sebastes schlegeli). The concentrations of potentially carcinogenic PAHs of six species were in the range of 9 to 123 pg/g wet weight. The residues of PAHs in fishes from Korean coasts were slightly low or relatively moderate to other countries. There was no correlation between PAH residues and lipid contents in seafood samples. The predominant contributors in fish samples were lower-molecular-weight two and three ring aromatic PAHs such as naphthalene, acenaphthene, fluorene and phenanthrene. Filter-feeding organisms like shrimp, crab and topshell were dominated by three- and four-ring aromatic PAHs. The PAH profiles in marine sediments, bivalves, fishes, shrimp, crab and topshell according to exposure pathway were compared through factor analysis. The PAH profiles were clearly classified by the difference of species or environmental matrices. This result suggests that most of PAHs within the same samples behave identically in marine environment.

Status, Distribution, Conservation and Use Value of Medicinal and Aromatic Plants (MAPs) in Sagarmatha National Park, Nepal

  • Gaire, Damodar
    • Journal of Forest and Environmental Science
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    • 제30권3호
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    • pp.253-258
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    • 2014
  • The study attempts to assess the status, distribution, conservation and use value of Medicinal and Aromatic Plant (MAPs) in the Sagarmatha National Park. Altogether 62 species of MAPs belonging to 47 genera and 33 families have been recorded in the study area. 10 species, belonging to 9 families are categorized as the potential species. Out of the these species, most potential in local but threatened species are Allium hypsistum Stearn, Cordyceps sinensis Sacc, Dactylorhiza hatagirea Soo, Nardostachys grandiflora DC, Aconitum orochryseum, Ephedra gerardiana Wall. Ex. Stapf, Swertia multicaulis D. Don, Picrorhiza scrophulariflora Penne, Rheum australe. D. Don, Malva verticillataL and Swertia pedicallata Benerji. By analysis of data using Simpson's diversity index (SI) and Shannon weaver function (H'), there was high diversity (more heterogeneous) MAPs species composition in the Manjo Gate to Large Dobhan. (0.98349). Less diversity (less heterogeneous) MAPs species composition was in Tyanboche to Pangoche (0.90419). Similarly, the Shannon weaver function shows that in plots laying out in Mongla to Phorche are evenly distributed than others However, higher MAPs species (i.e., 31) was found in the way of Manjo Gate to Larja Dobhan than others.

방향성 한방식물체 조추출물의 에짚트숲모기(Aedes aegypti)에 대한 기피활성에 관한 연구 (Repellent activity of aromatic medicinal plant extracts against Aedes aegypti(Diptera: Culicidae))

  • 최한영;양영철
    • 환경위생공학
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    • 제17권3호
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    • pp.110-114
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    • 2002
  • The repellent activity of methanol extracts from 8 aromatic medicinal plant species and a steam distillate against blood-starved Aedes aegypti (L.) females was laboratory examined by skin test and compared with that of N,N-diethyl-m-toluamide (deet). Reponeses varied according to Plant species. At a dose of $0.1mg/\textrm{cm}^2$, potent repellency against adult mosquitoes was obtained with extracts of Cinnamomum camphora (94.1 %) Cinnamomum cassia bark (91.2%), Eugenia caryophyllata flower bud (72.2%), and Tilia amurensis (69.4%). Repellent activity of these plant extracts was comparable to that of deet (83.4%). The plants described merit further study as potential mosquito-repellent agents.

Molecular approaches for improvement of medicinal and aromatic plants

  • Kumar, Jitendra;Gupta, Pushpendra Kumar
    • Plant Biotechnology Reports
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    • 제2권2호
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    • pp.93-112
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    • 2008
  • Medicinal and aromatic plants (MAPs) are important sources for plant secondary metabolites, which are important for human healthcare. Improvement of the yield and quality of these natural plant products through conventional breeding is still a challenge. However, recent advances in plant genomics research has generated knowledge leading to a better understanding of the complex genetics and biochemistry involved in biosynthesis of these plant secondary metabolites. This genomics research also concerned identification and isolation of genes involved in different steps of a number of metabolic pathways. Progress has also been made in the development of functional genomics resources (EST databases and micro-arrays) in several medicinal plant species, which offer new opportunities for improvement of genotypes using perfect markers or genetic transformation. This review article presents an overview of the recent developments and future possibilities in genetics and genomics of MAP species including use of transgenic approach for their improvement.

에틸렌 난류확산 화염에 관한 실험적 연구 (Experimental Study on Turbulent Ethylene Diffusion Flame)

  • 양고수;김용문
    • 한국연소학회지
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    • 제4권2호
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    • pp.23-33
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    • 1999
  • A turbulent non-premixed ethylene flame, which was set up in a vertical wind tunnel, was examined to understand the effect of turbulent mixing on formations of soot and gaseous species in the flames. Temperature and velocity profiles were measured using uncoated thermocouples and LDV system. Gaseous samples were withdrawn by using a water cooled stainless iso-kinetic gas sampling probe. The samples for inorganic compounds and light hydrocarbons were collected with sampling bottles and were analyzed by a gas chromatography. The samples for aromatic hydrocarbons were collected on a sorbent tube and were analyzed on a GC/MS system. Some of main results were followed. CO and $CO_2$ were measured relatively in early part of flame and the concentration of CO was greater than that of $CO_2$ all over the early flame region due to the scavenging of the oxidizing species OH by soot particles. Aromatic hydrocarbons were measured at x/D=122 along the radial direction and main important species were benzene, xylene, toluene, styrene, indene, naphthalene. The peak points of these compounds occurred at r/D=0.8 apart from the center of flame, around in which the concentration of $C_2H_2$ decayed relatively rapidly from the maximum value.

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MODELLING STUDY OF THE EFFECT OF CHEMICAL ADDITIVES ON SOOT PRECURSORS REDUCTION

  • Park, J.K.
    • International Journal of Automotive Technology
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    • 제7권4호
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    • pp.501-508
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    • 2006
  • The effect of chemical additives, such as dimethyl ether(DME), ethanol, carbon disulfide on the soot formation were examined numerically. ill this study, the Frenklach soot mechanism was used as a base mechanism to predict the soot formation in the ethane flame. The combination of Westbrook's DME mechanism, Marinov's ethanol mechanism, and chemical kinetic mechanism for hydrogen sulfide and carbon disulfide flames was made with the base mechanism because the DME, ethanol, $CS_2$ additives are added into the ethane fuel. CHEMKIN code was used as a numerical analysis software to simulate the effect of chemical additives on reduction of the polycyclic aromatic hydrocarbons(PAH's) which are soot precursors. From the numerical results it is observed that addition of DME, ethanol and $CS_2$ into ethane fuel can reduce PAH species significantly. That means theses additives can reduce soot formation significantly. Results also strongly suggest suppression of soot formation by these additives to be mainly a chemical effect. Hand OH radicals may be the key species to the reduction of PAH species for additives.