• Journal of the Korean Ceramic Society
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• v.42 no.12 s.283
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• pp.800-807
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• 2005

Cathode material, $(Ba_{0.5}Sr_{0.5})_{0.99}Co_{0.8}Fe_{0.2}O_{3-\delta}$, for low temperature SOFC was prepared by the Glycine-Nitrate synthesis Process (GNP). Characteristics of the synthesized powders were studied with controlling the pH of a precursor solution. Highly acidic precursor solution increased a perovskite forming temperature. It is considered that Ba and Sr cannot complex by carboxylic acid group of glycine, because under highly acidic condition the caboxylic group mainly combined with H+ insead of alkaline earth cations. A lack of bond between cations and glycine resulted in selective precipitation of the elements during evaporation of the precursor solution. In case of using precursor solution with pH %2\~3$, a single perovskite phase was obtained at $1000^{\circ}C$. Polarization resistance of $(Ba_{0.5}Sr_{0.5})_{0.99}Co_{0.8}Fe_{0.2}O_{3-\delta}$ was measured by AC impedance spectroscopy from the two electrode symmetric cell. Area specific resistance of the $(Ba_{0.5}Sr_{0.5})_{0.99}Co_{0.8}Fe_{0.2}O_{3-\delta}$ air electrode at $500^{\circ}C\;and\;600^{\circ}C$ were $0.96{\Omega}{\cdot}cm^2\;and\;0.16{\Omega}{\cdot}cm^2$, respectively.

• Applied Chemistry for Engineering
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• v.19 no.3
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• pp.310-315
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• 2008

Herein, we synthesized silica-coated chrome yellow particles having improved chemical resistance. The intermediate with a good dispersion stability was prepared and the chemical resistance of the final product was investigated. The effects of pH and temperature, as the main parameters influencing the formation of particles, the reduced particle size by homogenizer on the silica coating were investigated. The change in the particle morphology by temperature and pH was also studied. As the results, small and monodisperse particles were achieved at low pH and high temperature. Good silica coating was obtained when used reduced size of the particles by homogenizer. Furthermore, the sufficient silica coating by microencapsulation was obtained at 9~10 pH and the temperature above $90^{\circ}C$.

• Proceedings of the Korean Vacuum Society Conference
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• 2014.02a
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• pp.490.2-490.2
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• 2014

Since the general solar cells accept sun light at the front side, excluding the electrode area, electrons move from the emitter to the front electrode and start to collect at the grid edge. Thus the edge of gridline can be important for electrical properties of screen-printed silicon solar cells. In this study, the improvement of electrical properties in screen-printed crystalline silicon solar cells by contact treatment of grid edge was investigated. The samples with $60{\Omega}/{\square}$ and $70{\Omega}/{\square}$ emitter were prepared. After front side of samples was deposited by SiNx commercial Ag paste and Al paste were printed at front side and rear side respectively. Each sample was co-fired between $670^{\circ}C$ and $780^{\circ}C$ in the rapid thermal processing (RTP). After the firing process, the cells were dipped in 2.5% hydrofluoric acid (HF) at room temperature for various times under 60 seconds and then rinsed in deionized water. (This is called "contact treatment") After dipping in HF for a certain period, the samples from each firing condition were compared by measurement. Cell performances were measured by Suns-Voc, solar simulator, the transfer length method and a field emission scanning electron microscope. According to HF treatment, once the thin glass layer at the grid edge was etched, the current transport was changed from tunneling via Ag colloids in the glass layer to direct transport via Ag colloids between the Ag bulk and the emitter. Thus, the transfer length as well as the specific contact resistance decreased. For more details a model of the current path was proposed to explain the effect of HF treatment at the edge of the Ag grid. It is expected that HF treatment may help to improve the contact of high sheet-resistance emitter as well as the contact of a high specific contact resistance.

• The Transactions of The Korean Institute of Electrical Engineers
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• v.61 no.10
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• pp.1542-1547
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• 2012

Asynchronous phenomenon occurs on the synchronous generators under power system when a generator's amplitude of electromagnetic force, phase angle, frequency and waveform etc become different from those of other synchronous generators which can follow instantly varying speed of turbine. Because the amplitude of electromagnetic force, phase frequency and waveform differ from those of other generators with which are to be put into parallel operation due to the change of excitation condition for load sharing and the sharing load change, if reactive current in the internal circuit circulates among generators, the efficiency varies and the stator winding of generators are overheated by resistance loss. When calculation method of protection settings and logic for protection of generator asynchronization will be recommended, a distance relay scheme is commonly used for backup protection. This scheme, called a step distance protection, is comprised of 3 steps for graded zones having different operating time. As for the conventional step distance protection scheme, zone 2 can exceed the ordinary coverage excessively in case of a transformer protection relay especially. In this case, there can be overlapped protection area from a backup protection relay and, therefore, malfunctions can occur when any fault occurs in the overlapped protection area. Distance relays and overcurrent relays are used for backup protection generally, and both relays have normally this problem, the maloperation, caused by a fault in the overlapped protection area. Corresponding to an IEEE standard, this problem can be solved with the modification of the operating time. On the other hand, in Korea, zones are modified to cope with this problem in some specific conditions. These two methods may not be obvious to handle this problem correctly because these methods, modifying the common rules, can cause another coordination problem. To overcome asynchronizing protection, this paper describes an improved backup protection coordination scheme using a new logic that will be suggested.

• The Transactions of The Korean Institute of Electrical Engineers
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• v.60 no.11
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• pp.2000-2006
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• 2011

Asynchronous phenomenon occurs on the synchronous generators under power system when a generator's amplitude of electromagnetic force, phase angle, frequency and waveform etc become different from those of other synchronous generators which can follow instantly varying speed of turbine. Because the amplitude of electromagnetic force, phase frequency and waveform differ from those of other generators with which are to be put into parallel operation due to the change of excitation condition for load sharing and the sharing load change, if reactive current in the internal circuit circulates among generators, the efficiency varies and the stator winding of generators are overheated by resistance loss. Where calculation method of protection settings and Logic for Protection of Generator Asynchronization will be recommended, A distance relay scheme is commonly used for backup protection. This scheme, called a step distance protection, is comprised of 3 steps for graded zones having different operating time. As for the conventional step distance protection scheme, Zone 2 can exceed the ordinary coverage excessively in case of a transformer protection relay especially. In this case, there can be overlapped protection area from a backup protection relay and, therefore, malfunctions can occur when any fault occurs in the overlapped protection area. Distance relays and overcurrent relays are used for backup protection generally, and both relays have normally this problem, the maloperation, caused by a fault in the overlapped protection area. Corresponding to an IEEE standard, this problem can be solved with the modification of the operating time. On the other hand, in Korea, zones are modified to cope with this problem in some specific conditions. These two methods may not be obvious to handle this problem correctly because these methods, modifying the common rules, can cause another coordination problem. To overcome asynchronizing protection this paper describes an improved backup protection coordination scheme using a new Logic that will be suggested.

• Journal of Institute of Control, Robotics and Systems
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• v.19 no.8
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• pp.709-717
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• 2013

This paper presents the development of a specialized underwater leg with a manipulator function(convertible-to-arm leg) for the seabed walking robot named CRABSTER200(CR200). The objective functions of the convertible-to-arm leg are to walk on the seabed and to work in underwater for precise seabed exploration and underwater tasks under coastal area with strong tidal current. In order to develop the leg, important design elements including the degree of freedom, dimensions, mass, motion range, joint structure/torque/angular-speed, pressure-resistance, watertight capability and cable protection are considered. The key elements of the convertible-to-arm leg are realized through concept/specific/mechanical design and implementation process with a suitable joint actuator/gear/controller selection procedure. In order to verify the performance of the manufactured convertible-to-arm leg, a 25bar pressure-resistant and watertight test using a high-pressure chamber and a joints operating test with posture control of the CR200 are performed. This paper describes the whole design, realization and verification process for implementation of the underwater convertible-to-arm leg.

• Journal of the Korean GEO-environmental Society
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• v.11 no.1
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• pp.53-59
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• 2010

In seawater deposition condition, the corrosion and chemical attack of grouts are similar to those of concrete structure. Used in domestic MSG (Micro Silica Grouting) mixtured large amounts of silicate materials containing as cement powder is $8,000cm^2/g$ of the specific surface area or more due to the high hydration activity and high-strength, high durability, and features, $C_3A$ content of less than 5% to meet the standards chemical attack of seawater was evaluated as a cement material. Therefore, in this paper, with excellent seawater attack resistant MSG in combination with rapid hardening mineral was used, those of seawater characteristics were evaluated experimentally. Typically, sodium-silicate minerals or rapid hardening cements are used in domestic. About the homogel specimens with combination of MSG and rapid hardening agents for compressive strength, weight and length change characteristics were evaluated experimentally, and so we could present the excellent seawater resistant grouts combination.

• Computers and Concrete
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• v.26 no.3
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• pp.203-211
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• 2020

Turkey is located in one of the most seismically active regions of in Europe. The majority of the population living in big cities are at high seismic risk due to insufficient structural resistance of the existing buildings. Such a seismic risk brings the need for a comprehensive seismic evaluation based on the risk analysis in Turkey. Determining the seismic resistance level of existing building stock against the earthquakes is the first step to reduce the damages in a possible earthquake. Recently in January 2020, the Elazig earthquake brought the importance of the issue again in the public. However, the excessive amount of building stock, labor, and resource problems made the implementation phase almost impossible and revealed the necessity to carry out alternative studies on this issue. This study aims for a detailed investigation of residential buildings in Antalya, Turkey. The approach proposed here can be considered an improved state of building survey methods previously identified in Turkey's Design Code. Antalya, Turkey's fifth most populous city, with a population over 2.5 Million, was investigated as divided into sub-regions to understand the vulnerability, and a threshold value found for the study area. In this study, 26,610 reinforced concrete buildings between 1 to 7 stories in Antalya were examined by using the rapid visual assessment method. A specific threshold value for the city of Antalya was determined with the second level examination and statistical methods carried out in the determined sub-region. With the micro zonation process, regions below the threshold value are defined as the priority areas that need to be examined in detail. The developed methodology can be easily calibrated for application in other cities and can be used to determine new threshold values for those cities.

• Journal of Welding and Joining
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• v.28 no.1
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• pp.66-71
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• 2010

With large specific strength and outstanding corrosion resistance and erosion resistance in sea water, titanium and titanium alloy are widely used in heat exchanger production. In particular, pure titanium demonstrates outstanding molding performance and may be considered optimal for production of heat exchanger. Since titanium is very vulnerable to oxidation and embrittlement during welding, processes with less heat input are widely used, and laser welding is widely applied by considering production performance and shield etc in atmosphere. So far, 1st report and 2nd report compared and analyzed embrittlement degrees by bead colors of weldment through oxygen and nitrogen quantitative analysis and hardness measurement, and evaluated welding performance and mechanical properties of butt welding. This study evaluated field applicability of lap welding to heat exchange plate of LPG re-liquefaction device for ships through tensile stress test, hardness test and internal pressure test etc after deducing optimal weding condition and applying to actual heat exchange plate. In bead overlap area, the experiment produced sound welds with no porosity or defect by increasing and decreasing laser power, and tensile-shear test results indicated virtually the same tension and yield strength as base metal. As a result of measuring hardness at lateral cross section and bead overlap zone of actual heat exchanger welds, hardness difference within 20Hv was produced at base metal, HAZ and weldment, and as a result of pneumatic and hydraulic pressure test, no leakage occurred.

• Food Science and Preservation
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• v.8 no.4
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• pp.434-441
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• 2001

The purpose of this research is the establishment of optimal processing and the quality improvement of confectionary analysis of the damaged starch content of flour. I studied the rheological and bread making properties of the dough containing different damaged starch content. I examined rheological and physico- chemical characteristic farinograph, extensograph and amylograph with DNS, CWRS and SW containing 6.5%, 8.2%, 9.0%, 9.0% and 10.5% of damaged starch. And I measured the hardness and specific volume and performed the functional survey by rheometer for quality control. In the amylogram, at the damaged starch content 9.5% at such the maximum viscosity was 900 B.U. the volume of bread fermention tolerance were increased. In addition, the extensegram after 135 min showed that maximum resistance of the dough were 570 B.U at the damaged starch contents of 9.5% and the bread had homogeneous air cells and internal structures at the damaged starch contents of 9.5% at which the area(A), resistance(R) and R/E value of the dough were highest.