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Thermal Plasma Synthesis of Nano Composite Particles (열플라즈마에 의한 복합 나노 입자 제조)

  • Jeong, Min-Hee;Kim, Heon-Chang
    • Applied Chemistry for Engineering
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    • v.21 no.6
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    • pp.676-679
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    • 2010
  • Nano composite particles were synthesized from a bulk ZrVFe alloy ingot by transferred DC thermal plasma. Effects of plasma gas flow rate on the characteristics of the produced nano composite particles were investigated. The characteristics of the synthesized powder were analyzed by field scanning electron microscopy (FE-SEM), light scattering particle size analyzer (PSA), energy dispersive X-ray spectroscopy (EDS), X-ray diffractometer (XRD), and Brunauer-Emmett-Teller (BET) surface area analyzer. As the flow rate of plasma gas increased from 20 L/min to 40 L/min, the average particle size decreased from 91 nm to 55 nm, the particle size distribution became narrower, the surface area increased from $200\;m^2/g$ to $255\;m^2/g$, the particle composition was nearly unaffected, and the particle crystallinity was improved.

Analysis on Particle Cleaning Capacity of Indoor Air Cleaners for Different Flow Rates Considering Energy Consumption (에너지소비를 고려한 실내공기청정기의 풍량별 입자 청정화능력 분석)

  • Han, Bangwoo;Kang, Ji-Su;Kim, Hak-Joon;Kim, Yong-Jin;Won, Hyosig
    • Particle and aerosol research
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    • v.9 no.3
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    • pp.139-147
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    • 2013
  • The performances of indoor air cleaners including particle cleaning capacity and collection efficiency are usually tested at the condition of the maximum air flow rate of the air cleaners. However, the power consumption of the air cleaners is highly dependent on the air flow rate of the individual air cleaners. Therefore, there seems to be an optimized air flow rate for the air cleaning capacity considering power consumption. In this study, clean air delivery rate(or standard useful area as suggested room size) and power consumption have been investigated for different maximum air flow rates of 15 air cleaners and then compared those for different air flow rate modes of the individual 5 air cleaners selected from the 15 cleaners. For the maximum air flow rate conditions of 15 air cleansers, the power consumption per unit area was less related to the maximum air flow rate. However, for the different air flow rate modes of the selected 5 air cleaners, the lower power consumption per unit area was corresponding to the lower air flow rate mode of the individual air cleaners. When considering the operation time to the desired particle concentrations, there was an optimized one in the medium air flow rate modes for the individual air cleaners. Therefore, not only the maximum air flow rate but also lower air flow rates of individual air cleaners should be considered for estimating air cleaning capacity based on energy consumption per unit area.

Change in the Characteristics of Particle Separation and Particle Size Distribution of Weathered Granite Soil from the Yecheon Area (Eastern South Korea) after Water Washing (물 세척한 예천지역 화강풍화토의 입자분리와 입도분포 변화 특성)

  • Kim, Suk-Joo
    • The Journal of Engineering Geology
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    • v.32 no.2
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    • pp.241-255
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    • 2022
  • In this study, sieve analysis testing was performed on weathered granite soil from Yecheon (eastern South Korea) before and after water washing in accordance with the sieve analysis regulations of KS F 2302. The changes in particle separation and particle size distribution after washing with water were analyzed. Image analysis using an optical microscope revealed that soil particles were separated into smaller particles by water washing. The change in the particle size distribution curve was assessed using five index values. The increase in the fine particle fraction (<0.075 mm) was 13.67%, the increase in the 0.075-0.25 mm fraction was 19.44%, and the mean particle diameter (D50) decreased by 0.663 mm. In addition, the maximum passage width (BM) of the particle size distribution curve increased by 21.08% for the #30 sieve, and the moving area (A) of the particle size distribution curve was 69.28%·mm. These results suggest that washing with water is an effective way to prevent underestimation of the fine particle content in soil.

Quantification of Surface Sites of Ideally Shaped Particles (이상적인 외형을 가진 입자의 표면원자 수계산법)

  • 이수재;김수진
    • Journal of the Mineralogical Society of Korea
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    • v.11 no.2
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    • pp.126-134
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    • 1998
  • Surface site and areas of particles are geometrically calculated for the cubic structures to investigate how the surface sites vary with the variation of morphology and particle size. The numbers of surface site and area become smaller when the particles become equi-dimensional shape. The ratios of surface site to surface area are almost constant except the case of anion of fluorite structure. The ratios of the number of surface site to area are almost constant regardless of particle size except the size of up to 5 to 10 times of the unit cell dimension. This quantification method can be used to obtain data related to the surface reaction.

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Fabrication of the Nano-Sized Nickel Oxide Powder by Spray Pyrolysis Process

  • Yu, Jae-Keun;NamGoong, Hyun;Kim, Dong-Hee
    • Korean Journal of Materials Research
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    • v.22 no.8
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    • pp.426-432
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    • 2012
  • This study involves using nickel chloride solution as a raw material to produce nano-sized nickel oxide powder with average particle size below 50 nm by the spray pyrolysis reaction. The influence of the inflow speed of raw material solution on the properties of the produced powder is examined. When the inflow speed of the raw material solution is at 2 ml/min., the average particle size of the powder is 15~25 nm and the particle size distribution is relatively uniform. When the inflow speed of the solution increases to 10 ml/min., the average particle size of the powder increases to about 25 nm and the particle size distribution becomes much more uneven. When the inflow speed of the solution increases to 20 ml/min., the average particle size of the powder increases in comparison to the case in which the inflow speed of the solution was 10 ml/min. However, the particle size distribution is very uneven, showing various particle size distributions ranging from 10 nm to 70 nm. When the inflow speed of solution increases to 50 ml/min., the average particle size of the powder decreases in comparison to the case in which the inflow speed was 20 ml/min., and the particle size distribution shows more evenness. As the inflow speed of the solution increases from 2 ml/min. to 20 ml/min., the XRD peak intensities gradually increase, while the specific surface area decreases. When the inflow speed of solution increases to 50 ml/min., the XRD peak intensities rather decrease, while the specific surface area increases.

Effect of Nozzle Tip Size on the Fabrication of Nano-Sized Nickel Oxide Powder by Spray Pyrolysis Process

  • Kim, Donghee;Yu, Jaekeun
    • Korean Journal of Materials Research
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    • v.23 no.9
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    • pp.489-494
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    • 2013
  • In this study, by using nickel chloride solution as a raw material, a nano-sized nickel oxide powder with an average particle size below 50 nm was produced by spray pyrolysis reaction. A spray pyrolysis system was specially designed and built for this study. The influence of nozzle tip size on the properties of the produced powder was examined. When the nozzle tip size was 1 mm, the particle size distribution was more uniform than when other nozzle tip sizes were used and the average particle size of the powder was about 15 nm. When the nozzle tip size increases to 2 mm, the average particle size increases to roughly 20 nm, and the particle size distribution becomes more uneven. When the tip size increases to 3 mm, particles with an average size of 25 nm and equal to or less than 10 nm coexist and the particle size distribution becomes much more uneven. When the tip size increases to 5 mm, large particles with average size of 50 nm partially exist, mostly consisting of minute particles with average sizes in the range of 15~25 nm. When the tip size increases from 1 mm to 2 mm, the XRD peak intensities greatly increase while the specific surface area decreases. When the tip size increases to 3 mm, the XRD peak intensities decrease while the specific surface area increases. When the tip size increases to 5 mm, the XRD peak intensities increase again while the specific surface area decreases.

Effect of May 31, 2022 Miryang Forest Fire on Fine Particle Concentration in Nearby Urban Areas (2022년 5월 31일 발생한 밀양산불이 인근 도시 지역의 미세먼지 농도에 미치는 영향)

  • Byung-Il Jeon
    • Journal of Environmental Science International
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    • v.32 no.1
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    • pp.37-46
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    • 2023
  • This study investigated the effect of May 31, 2022 Miryang wildfire on fine particle concentrations in Busan and Gimhae, which are neighboring urban areas. In addition, fine particle characteristics and air pollution concentrations were investigated in Miryang, where haze occurred. The Miryang city wildfire that occurred on May 31, 2022, at 0925 LST, was driven by strong north winds and increased fine particle concentrations in Dongsangdong and Jangyoodong, Gimhae City, which are approximately 35 km to the southeast and south, respectively, of the wildfire occurrence site. Furthermore, the fine particle concentration in Myeongjidong, which is approximately 50 km south-southeast of the wildfire site, exhibited a temporary increase at 1400 LST owing to the effects of wildfire smoke. On the morning of June 1, the day after the fire, the Miryang area had very bad visibility because of the smoke from the fire. Therefore the PM10 and PM2.5 concentrations in Naeildong, 3 km south of the wildfire site, were 276 ㎍/㎥ and 222 ㎍/㎥, respectively, at 1200 LST. In addition, the gases O3, CO, and SO2 showed high concentrations at the time of haze generation. This study provides insights into policy making in response to the rapid increase in fine dust when wildfire occurs near cities.

A Simulation Method for Modeling the Morphology and Characteristics of Electrospun Polymeric Nanowebs

  • Kim Hyungsup;Kim Dae-Woong;Seo Moon Hwo;Cho Kwang Soo;Haw Jung Rim
    • Macromolecular Research
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    • v.13 no.2
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    • pp.107-113
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    • 2005
  • We developed an algorithm to simulate the generation of virtual nanowebs using the Monte Carlo method. To evaluate the pore size of the simulated multi-layered nanoweb, an estimation algorithm was developed using a ghost particle having zero volume and mass. The penetration time of the ghost particle through the virtual nanoweb was dependent on the pore size. By using iterative ghost particle penetrations, we obtained reliable data for the evaluation of the pore size and distribution of the virtual nanowebs. The penetration time increased with increasing number of layers and area ratio, whereas it decreased with increasing fiber diameter. Dimensional analysis showed that the penetration time can be expressed as a function of the fiber diameter, area ratio and number of layers.

Monitoring Airborne Nanoparticle Concentrations by Task in a Laboratory Making Carbon Nanotube Films (탄소나노튜브 필름 제조 실험실의 세부작업별 공기 중 나노입자 노출 농도)

  • Ha, Ju-Hyun;Shin, Yong-Chul
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.20 no.4
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    • pp.248-255
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    • 2010
  • Airborne nanoparticle concentrations in three metrics (particle surface area concentration, particle number concentration, and particle mass concentrations) were measured by task in a laboratory making carbon nanotubes (CNTs) films using three direct reading instruments. Because of the conducted other researcher's experiment before the tasks, airborne nanoparticle surface area and number concentrations are the highest at the first time conducted weighing and mixing by sonication task, respectively. Because of the mist generated during mixing by sonication, the highest airborne nanoparticle surface area and PM1 concentrations were measured in the task among the total. Nanoparticle surface area concentrations at the researchers' breathing zones had high correlation (r=0.93, p<0.01) with those measured at an area in the laboratory. This result indicates that nanoparticles generated during the experiment contaminated the whole room air. When the experiment performed all the fume hoods weren't operated and making CNTs films task were conducted in the out of the fume hoods. In conclusion, researchers performing making CNTs film experiments were exposed to airborne nanoparticles generated during the experiment without adequate controls. We recommend that adequate controls should be implemented so that workers' exposures to airborne nanoparticle are limited to minimum levels.

Optimal Design of Location Management Using Particle Swarm Optimization (파티클군집최적화 방법을 적용한 위치관리시스템 최적 설계)

  • Byeon, Ji-Hwan;Kim, Sung-Soo;Jang, Si-Hwan;Kim, Yeon-Soo
    • Korean Management Science Review
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    • v.29 no.1
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    • pp.143-152
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    • 2012
  • Location area planning (LAP) problem is to partition the cellular/mobile network into location areas with the objective of minimizing the total cost in location management. The minimum cost has two components namely location update cost and searching cost. Location update cost is incurred when the user changes itself from one location area to another in the network. The searching cost incurred when a call arrives, the search is done only in the location area to find the user. Hence, it is important to find a compromise between the location update and paging operations such that the cost of mobile terminal location tracking cost is a minimum. The complete mobile network is divided into location areas. Each location area consists of a group of cells. This partitioning problem is a difficult combinatorial optimization problem. In this paper, we use particle swarm optimization (PSO) to obtain the best/optimal group of cells for 16, 36, 49, and 64 cells network. Experimental studies illustrate that PSO is more efficient and surpasses those of precious studies for these benchmarking problems.