• Title/Summary/Keyword: Arc plasma

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Characterization and Formation Mechanism of Zr-Cu and Zr-Cu-Al Metallic Glass Thin Film by Sputtering Process

  • Lee, Chang-Hun;Sun, Ju-Hyun;Moon, Kyoung-Il;Shin, Seung-Yong
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2012년도 제42회 동계 정기 학술대회 초록집
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    • pp.271-272
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    • 2012
  • Bulk Metallic Glasses (BMGs or amorphous alloy) exhibit high strength and good corrosion resistance. Applications of thin films and micro parts of BMGs have been used a lot since its inception in the research of BMGs. However, Application and fabrication of BMGs are limited to make structural materials. Thin films of BMGs which is sputtered on the surface of structural materials by sputtering process is used to improve limits about application of BMGs. In order to investigate the difference of properties between designed alloys and thin films, we identified that thin films deposited on the surface that have the characteristic of the amorphous films and the composition of designed alloys. Zr-Cu (Cu=30, 35, 38, 40, 50 at.%) and Zr-Cu-Al (Al=10 at.% fixed, Cu=26, 30, 34, 38 at.%) alloys were fabricated with Zr (99.7% purity), Cu (99.997% purity), and Al (99.99% purity) as melting 5 times by arc melting method before rods 2mm in diameter was manufactured. In order to analyze GFA (Glass Forming Ability), rods were observed by Optical Microscopy and SEM and $T_g$, $T_x$, ($T_x$ is crystallization temperature and $T_g$ is the glass transition temperature) and Tm were measured by DTA and DSC. Powder was manufactured by Gas Atomizer and target was sintered using powder in large supercooled liquid region ($=T_x-T_g$) by SPS(Spark Plasma Sintering). Amorphous foil was prepared by RSP process with 5 gram alloy button. The composition of the foil and sputtered thin film was analyzed by EDS and EPMA. In the result of DSC curve, binary alloys ($Zr_{62}Cu_{38}$, $Zr_{60}Cu_{40}$, $Zr_{50}Cu_{50}$) and ternary alloys ($Zr_{64}Al_{10}Cu_{26}$, $Zr_{56}Al_{10}Cu_{34}$, $Zr_{52}Al_{10}Cu_{38}$) have $T_g$ except for $Zr_{70}Cu_{30}$ and $Zr_{60}Al_{10}Cu_{30}$. The compositions with $T_g$ made into powders. Figure shows XRD data of thin film showed similar hollow peak.

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Fe4N 나노분말과 Fe17Sm2Nx 자성분말의 자기적 특성 (Magnetic Properties of Fe4N Nanoparticles and Magnetic Fe17Sm2Nx Powders)

  • 오영우;이정구;박상준
    • 한국자기학회지
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    • 제22권3호
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    • pp.79-84
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    • 2012
  • 나노크기의 물질이 가지는 새로운 특성을 응용하는 연구가 매우 활발하게 진행되어 지고 있다. 본 연구에서는 PAD법으로 제조한 ${\alpha}$-Fe 나노분말을 이용하여 높은 포화자화와 기계적인 경도, 화학적 안정성, 작은 입자로 인한 tape noise의 감소 등의 특성을 지니고 있는 질화철인 $Fe_4N$을 합성하고, 이를 환원/확산법과 $N_2$가스 질화법으로 합성한 $Fe_{17}Sm_2N_x$ 자성분말과 자성 특성을 비교하였다. $NH_3+H_2$(부피비 3 : 1) 혼합가스를 이용하였을 경우 $Fe_4N$의 생성 온도와 반응시간 등의 조건 변수를 통해 $400^{\circ}C$에서 4시간 동안 열처리함으로서 단일상의 $Fe_4N$이 생성되는 것을 관찰 할 수 있었으며, 나노크기의 $Fe_4N$ 분말과 마이크론 크기의 $Fe_{17}Sm_2N_x$ 분말의 포화자화의 값은 각각 149, 117 emu/g의 값을 나타내었다.

박막증착시 티타늄 표면의 마손저항도와 세포독성에 관한 연구 (A STUDY ON THE RESISTANCE OF WEAR AND CYTOTOXICITY OF THE TITANIUM SURFACE AFTER FILM DEPOSITIONS)

  • 김형우;김창회;김영수
    • 대한치과보철학회지
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    • 제39권1호
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    • pp.84-95
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    • 2001
  • Titanium is widely used in dentistry for its low density, high strength, fatigue resistance, corrosion resistance, and biocompatibility. But it has a tendency of surface damage under circumstance of friction and impact for its low hardness of the surface. Coating is one of methods fir increasing surface hardness. Its effect is to improve surface physical characteristics without change of titanium. Diamond-like carbon and titanium nitride are known for its high hardness of the surface. So that this study was aimed at the wear test and the cytotoxicity test of the commercially pure titanium and Ti-6Al-4V alloy which were deposited by diamond-like carbon film or titanium nitride film to acertain improvement of the surface hardness and the biocompatibility. A disk (25mm diameter, 2mm thickness) was made of commercially pure titanium and Ti-6Al-4V alloy and these substrates were deposited by diamond-like carbon film or titanium nitride film. Diamond-like carbon film was deposited by the method of radiofrequency plasma assisted chemical vapor deposition and titanium nitride film was deposited by the method of reactive arc ion plating. Then these substrates were tested about wear characteristics by the pin-on-disk type wear tester in which ruby ball was used as a wear causer under the load of 32N, The fracture cycles were measured by rotating the substrates until their films were fractured. The wear volume was measured after 150 cycles and 3,000 cycles using surface profiler. The cytotoxicity test was peformed by the method of the MTT assay. The results were as follows : 1. In the results of the wear volume test, commercially pure titanium and titanium alloy which were coated by diamond-like carbon film or titanium nitride aim had higher resistance against wear than the substrates which were not coated by any films (P<0.05). 2. In the results of the fracture cycle test and the wear volume test, diamond-like carbon film had higher resistance against wear than titanium nitride film (P<0.05). 3. In both coatings of diamond-like carbon aim and titanium nitride film, Ti-6Al-4V alloy had higher resistance against wear than commercially pure titanium (P<0.05) 4. In the results of the cytotoxicity test, diamond-like carbon film and titanium nitride film had little cytotoxicity as like commercially pure titanium or Ti-6Al-4V alloy (P>0.05).

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멀티패스 레이저 클래딩에 있어서 중첩률의 기준에 따른 클래드 층의 특성 비교 (Comparison of clad layer characteristics with overlapping criterion in multi pass laser cladding)

  • 김종도;이은진;황준구
    • Journal of Advanced Marine Engineering and Technology
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    • 제40권9호
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    • pp.768-773
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    • 2016
  • 엔진 밸브 시트와 페이스는 엔진 성능에 영향을 미치므로 내마모성, 내열성 및 내식성이 요구된다. 이러한 특성을 갖는 표면층을 형성하기 위해 일반적으로 PTA 프로세스를 사용하고 있지만 넓은 열 영향부와 높은 모재 희석 등과 같은 문제가 발생한다. 이러한 단점을 개선한 레이저 클래딩은 희석률이 낮고 열 영향 및 열 변형을 최소화하므로 더욱 우수한 클래드 층을 형성할 수 있다. 하지만 레이저 빔의 특성상 넓은 면적을 클래딩 할 경우, 1 패스 클래드 층의 중첩이 불가피하다. 중첩률 기준을 빔 사이즈와 클래드 층 폭으로 나누어 멀티패스 클래드 층을 형성한 결과, 기준에 관계없이 중첩률이 증가할수록 클래드 층의 폭이 감소하고 높이가 증가하였다. 하지만 빔 사이즈 기준 중첩률 조건으로 형성된 멀티패스 클래드 층이 다른 기준보다 모재 희석이 감소하여 더욱 높은 경도 값을 나타내었다. 결론적으로, 중첩률 기준을 클래드 층 폭으로 할 경우, 클래드 층 형상에 영향을 주는 공정변수가 변할 때 마다 폭의 길이가 달라지기 때문에 빔 사이즈를 중심으로 중첩률을 정의하였다.

Mo-Hf-C계 합금의 열처리에 따른 미세조직 변화에 관한 연구 (A Study on the Change of Microstructures by Heat-treatment in Mo-Hf-C Alloys)

  • 윤국한;김형기;이종무;박원구;최주
    • 한국재료학회지
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    • 제3권2호
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    • pp.111-120
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    • 1993
  • 플라즈마 아크 용해에 의해 0.31-1.14at%Hf과 0.08-1.00at%C의 조성을 갖는 Mo시편을 제조하여, 열처리에 따른 미세조직 변화를 광학현미경, AES(Auger Electron Spectroscopy)및 투과전자현미경(TEM)으로 조사하였다. 산소함량이 약 830ppm인 초기분말을 압분체로 성형하여 용해한 결과, 산소함량 약 40-130ppm의 시편으로 제조할 수 있었으며, 이때 Hf및 C의 첨가량이 증가할수록 시편의 결정립은 미세화되었다. Mo-1.14at% Hf-1.00at % C 조성의 시편을 열처리한 결과 130$0^{\circ}C$에서 결정립내의 편상의 ${\beta}$-Mo 탄화물(molybdenum carbide)이 열역학적으로 더욱 안정한 $\alpha$-Mo 탄화물로 변태되기 시작하고, 1400-150$0^{\circ}C$온도 구간에서는 급내에 의해 고용되어 있던 Hf과 C이 반응하여 미량의 Hf탄화물이 석출되었으며, 150$0^{\circ}C$에서는 결정립계에 Hf 탄화물이 편석되었다. 1500-170$0^{\circ}C$에서는 결정립계에 편석된 Hf탄화물이 분해되고 열역학적으로 더욱 안정한 Hf 산화물(Hafnium oxide)이 석출되었으며, 결정립내에도 미세한 Hf 산화물이 석출되었다.

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Ecosysteme de I′Etang de Berre (Mediterranee nord-occidentale) : Caracteres Generales Physiques, Chimiques et Biologiques

  • Kim, Ki-Tai
    • 환경생물
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    • 제22권2호
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    • pp.247-258
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    • 2004
  • Climatological, hydrological and planktonical research studies, measurements of primary production and photosynthetic efficiency from December 1976 to December 1978 have been carried out in two brackish lakes: Lake Etang de Berre and Lake Etang de Vaine located in the French Mediterranean coast, in the region of Carry-le-Rouet located on the north-west Mediterranean near Marseilles, and in fresh water inflows from 4 Rivers (Touloubre, Durance, Arc, Durancole) to Lake Etang de Berre. Physico-chemical parameters were measured for this study: water temperature, salinity, density, pH, alcalinity, dissolved oxygen (% saturation), phosphate, nitrate, nitrite, silicate etc. Diverse biological parameters were also studied: photosynthetic pigments, phaeopigments, specific composition and biomass of phytoplankton, primary pelagic production etc. Climatical factors were studied: air-temperature, solar-radiation, evaporation, direction (including strength) of winds, precipitation and freshwater volume of the four rivers. The changes in Lake ‘Etang de Berre’ ecosystem depend on the quality of the water in the Durance River, and on the effects of seawater near the entrance of the Caronte Canal. The water quality of the lake varies horizontally and vertically as a result of atmospheric phenomena, maritime currents and tides. The distribution of water temperatures is generally heterogeneous. Southeasterly winds and the Northeasterly Mistral wind are important in the origins of circulated and mixed water masses. These winds are both frequent and strong. They have, as a result, a great effect on the water environment of Lake Etang de Berre. In theory, the annual precipitation in this region is well over eight times the water mass of the lake. The water of the Durance River flows into Lake Etang de Berre through the EDF Canal, amounting to 90% of the precipitation. However, reduction of rainfall in dry seasons has a serious effect on the hydrological characteristics of the lake. The temperature in the winter is partially caused by the low temperature of fresh water, particularly that of the Durance River. The hydrological season of fresh and brackish water is about one month ahead of the hydrological season of sea water in its vicinity. The salinity of Lake Etang de Berre runs approximately 3$\textperthousand$, except at lower levels and near the entrance to the Caronte Canal. However, when the volume of the Durance River water is reduced in the summer and fall, the salinity rises to 15$\textperthousand$. In the lake, the ratio of fresh water to sea water is six to one (6:1). The large quantities of seston conveyed by rivers, particularly the Durance diversion, strongly reduce the transparency in the brackish waters. Although the amount of sunshine is also notable, transparency is slight because of the large amount of seston, carried chiefly by Tripton in the fresh water of the Durance River. Therefore, photosynthesis generally occurs only in the surface layer. The transparency progressively increases from freshwater to open seawater, as mineral particles sink to the bottom (about 1.7kg $m^{-2}a^{-1}$ on the average in brackish lakes). The concentration of dissolved oxygen and the rate of oxygen saturation in seawater (Carry-le-Rouet) ranged from 5.0 to 6.0 $m\ell$ㆍ.$1^{-1}$, and from 95 to 105%, respectively. The amount of dissolved oxygen in Etang de Berre oscillated between 2.9 and 268.3%. The monographs of phosphate, nitrate, nitrite and silicate were published as a part of a study on the ecology of phytoplankton in these environments. Horizontal and vertical distributions of these nutriments were studied in detail. The recent diversion of the Durance River into Lake Etang de Berre has effected a fundamental change in this formerly marine environment, which has had a great impact in its plankton populations. A total of 182 taxa were identified, including 111 Bacillariophyceae, 44 Chlorophyceae, and 15 Cyanophyceae. The most abundant species are small freshwater algae, mainly Chlorophyceae. The average density is about $10^{8}$ cells $1^{-1}$ in Lake Etang de Berre, and about double that amount in Lake Etang de Vaine. Differences in phytoplankton abundance and composition at the various stations or at various depths are slight. Cell biovolume V (equivalent to true biomass), plasma volume VP (‘useful’ biomass) and, simultaneously. the cell surface area S and S/V ratio through the measurement of cell dimensions were computed as the parameters of phytoplankton productivity and metabolism. Pigment concentrations are generally very high on account of phytoplankton blooms by Cyanophyceae, Chlorophyceae and Cryptophyceae. On the other hand, in freshwaters and marine waters, pigment concentrations are comparatively low and stable, showing slight annual variation. The variations of ATP concentration were closely related to those of chlorophyll a and phytoplankton blooms only in marine waters. The carbon uptake rates ranged between 38 and 1091 mg$Cm^{-2}d^{-1}$, with an average surface value of 256 mg; water-column carbon-uptake rates ranged between 240 and 2310 mg$Cm^{-2}d^{-1}$, with an average of 810, representing 290 mg$Cm^{-2}$, per year 45 000 tons per year of photosynthetized carbon for the whole lake. Gross photosynthetic production measured by the method of Ryther was studied over a 2-year period. The values obtained from marine water(Carry-le-Rouet) ranged from 23 to 2 337 mg$Cm^{-2}d^{-1}$, with a weighted average of 319, representing about 110 gCm$^{-2}$ per year. The values in brakish water (Etang de Berre) ranged from 14 to 1778 mg$Cm^{-2}d^{-1}$, with a weighted average of 682, representing 250 mg$Cm^{-2}$ per year and 38 400 tons per year of photosynthesized carbon for the whole lake.