• Title/Summary/Keyword: Aqueous condition

검색결과 512건 처리시간 0.044초

전산모사를 활용한 Fe-Cr-Ni 전주용 수용액의 안정성 분석 (Computational Analysis of Aqueous Solution Stability for Electroformed Fe-Cr-Ni Thin Layer)

  • 전승환;한상선;김마로;최용;이상범
    • 한국표면공학회:학술대회논문집
    • /
    • 한국표면공학회 2014년도 추계학술대회 논문집
    • /
    • pp.214-214
    • /
    • 2014
  • Computational analysis of aqueous solution stability of Fe-Cr-Ni system to find an electroplating condition of Fe-Cr-Ni layer. Aqueous sulfate solution with iron, chromium and nickel ions was selected by using a numerical S/W with which aqueous solution stability was analyzed. Several possible conditions to perform electro-forming of Fe-Cr-Ni were selected with thermo-dynamical data. The Fe-Cr-Ni system was electro-formed which composition and microstructure of the electroplated Fe-Cr-Ni significantly depended on the solution temperature and electro-potential. The final composition of Fe-3%Cr-48%Ni with less than $30{\mu}m$ thick was well electroplated.

  • PDF

효과적인 효소 소화율을 위한 볏짚 전처리 (Pretreatment of Rice Straw for Efficient Enzyme Digestibility)

  • 김성봉;김준석;이상준;이자현;강성우;김승욱
    • 한국신재생에너지학회:학술대회논문집
    • /
    • 한국신재생에너지학회 2010년도 춘계학술대회 초록집
    • /
    • pp.253-253
    • /
    • 2010
  • Rice straw was pretreated with aqueous ammonia in order to enhance enzyme digestibility. Soaking in ammonia aqueous (SAA) was conducted with 15% ammonia, at $60^{\circ}C$. for 24 h. Optimization of both saccharification conditions and enzyme loading of SAA rice straw was carried out. Especially enzyme loading test was performed using statistical method. Moreover proton beam irradiation (PBI) was also performed to overcome the problem which inhibit the enzyme digestibility at 1-25 kGy doses with 45 MeV of beam energy. Optimal condition for enzymatic saccharification was follows; pH 4.8, $50^{\circ}C$, 60 FPU of enzyme activity, 1:4 ratio of celluase and ${\beta}$-glucosidase. Also, optimal doses of PBI on rice straw and SAA-treated rice straw for efficient sugar recovery were found to be 3 kGy, respectively. When saccharification was performed with optimal condition, glucose conversion yield was 89% of theocratical maximum in 48 h, and 3 kGy of PBI was applied to SAA-treated rice straw, approximately 90% of the theoretical glucose yield was obtained in 12 h. The results of X-ray diffractometry (XRD) support the effect of both SAA and PBI on sugar recovery, and scanning electron microscopy (SEM) images unveiled the physical change of the rice straw surface since rugged rice straw surface was observed.

  • PDF

Corrosion Behavior and Oxide Film Formation of T91 Steel under Different Water Chemistry Operation Conditions

  • Zhang, D.Q.;Shi, C.;Li, J.;Gao, L.X.;Lee, K.Y.
    • Corrosion Science and Technology
    • /
    • 제16권1호
    • /
    • pp.8-14
    • /
    • 2017
  • The corrosion behavior of a ferritic/martensitic steel T91 exposed to an aqueous solution containing chloride and sulfate ions is investigated depending on the stimulated all-volatile treatment (AVT) and under oxygenated treatment (OT) conditions. The corrosion of T91 steel under OT condition is severe, while the corrosion under AVT condition is not. The co-existence of chloride and sulfate ions has antagonistic effect on the corrosion of T91 steel in both AVT and OT conditions. Unlike to corrosion resistance in the aqueous solution, OT pretreatment provides T91 steel lower oxidation-resistance than VAT pretreatment. From scanning electron microscopy/energy dispersive X-ray spectroscopy (SEM/EDS) and X-ray diffraction (XRD) analysis, the lower corrosion resistance in the aqueous solution by VAT conditions possibly is due to the formation of pits. In addition, the lower oxidation resistance of T91 steel pretreated by OT conditions is explained as follows: the cracks formed during the immersion under OT conditions accelerated peeling-off rate of the oxide film.

폴리에틸렌 필름에서의 수용성 미끄럼 방지 접착제의 내습 특성 개선 (Improvement of Moisture Resistance of Aqueous Slip-Resistant Adhesive on the Polyethylene Film)

  • 윤영기;조국영;설완호
    • Korean Chemical Engineering Research
    • /
    • 제48권2호
    • /
    • pp.193-197
    • /
    • 2010
  • 현재 포장 공정에서 사용되고 있는 stretch wrapping 공정은 초기 포장기의 장치 구비 등의 가격문제와 사용 후 폐기되는 포장재의 처리문제가 심각하다. 이에 대해 미끄럼 방지 접착제(Slip-resistant adhesive)를 사용하여 물류를 고정하여 운반하는 방식은 간단한 접착제의 도입으로 폐기물 발생이 없고 공정이 간단하며 비용이 매우 낮은 장점을 지닌다. 본 연구에서는 다습한 환경에서 polyethylene 필름 상에 미끄럼 방지 접착제를 적용했을 경우 접착력이 저하되는 것을 peel test를 통해 확인하고 적절한 첨가제의 선정 및 도입을 통해 접착력을 개선하는 연구를 수행하였다. 이를 통해서 maltodextrin의 첨가 시에 내습성에 대한 개선으로 인해 미끄럼 방지 접착력의 저하가 억제되었으며 10 wt% 도입 시에 최적의 성능을 나타내었다.

Ferrate(VI)를 이용한 다양한 수중 환경에서의 tetracycline의 분해 특성 및 반응 경로 연구 (Degradation characteristics and reaction pathways of tetracycline by ferrate(VI) in various aqueous conditions)

  • 박경덕;김일규
    • 상하수도학회지
    • /
    • 제35권1호
    • /
    • pp.27-37
    • /
    • 2021
  • Tetracycline is one of the most commonly used as antibiotics for the livestock industry and it is still widely used nowadays. Tetracycline and its metabolites are excreted with excrement, which is difficult to completely removed with conventional sewage treatment, therefore it is apprehended that the tetracycline-resistant bacteria occurs. In this study, the oxidant named ferrate(VI) was used to degrade the tetracycline and investigate the reaction between ferrate(VI) and tetracycline under various aqueous conditions. The highest degradation efficiency of tetracycline occurred in basic condition (pH 10.1 ± 0.1) because of the pKa values of tetracycline and ferrate(VI). The results also showed the effect of water temperature on the degradation of tetracycline was not significant. In addition, the dosage of ferrate(VI) was higher, the degradation of tetracycline and the self-degradation of ferrate(VI) also higher, finally the efficiency of ferrate(VI) was lower. The results said that the various mechanisms effects the reaction of ferrate(VI) oxidation, it required the consideration of the characteristics of the target compound for optimal degradation efficiency. Additionally, intermediate products were detected with LC/MS/MS and three degradation pathways were proposed.

Properties of Bubble used in Concrete ac cording to Change in Manufacturing Condition

  • Byoungil Kim
    • Architectural research
    • /
    • 제26권1호
    • /
    • pp.13-20
    • /
    • 2024
  • This study is a research investigation into the properties of bubbles that affect the characteristics of foamed concrete during its production. The study examined the properties of bubbles based on the manufacturing conditions. To investigate these properties, the selected experimental factors included bead size, the length/diameter ratio of the bubble-generating tube, and compressed air. The experimental design used a design of experiments, and the test results were analyzed using analysis of variance. The foaming agent used to generate bubbles was AES (Alcohol Ethoxy Sulfate), and the method employed for bubble manufacture was the pre-foaming method. In the test results, a significant factor affecting the foaming rate of bubbles was the bead size; the highest foaming rate was observed when using 2mm beads. Bead size also primarily influenced the volume change of the aqueous solution, while other factors did not affect the foaming rate and volume change. None of the factors affected the change in bubble size, but compressed air was considered the main factor affecting bubble size and its change. The foaming rate and volume change of the aqueous solution showed a high correlation with each other. Spherical bubbles in the early stage eventually transformed into angular bubbles. Moreover, over time, it was observed that the bubble size increased.

수중 이온 환경이 폐굴껍질에 대한 불소 이온의 흡착 양상에 미치는 영향 (The Influence of Aqueous Ionic, Condition on the Adsorption Features of Fluoride Ion on Waste Oyster Shell)

  • 이진숙;김동수
    • 한국물환경학회지
    • /
    • 제23권3호
    • /
    • pp.314-318
    • /
    • 2007
  • The feasibility of the employment of waste oyster shell as an adsorbent for fluoride ion has been tested by considering the effect ionic condition on the adsorption of fluoride ion on oyster shell. The adsorption capacity of oyster shell for fluoride ion was found not to be significantly influenced by the ionic strength of aqueous environment. The existence of complexing agent such as nitrilotriacetic acid in wastewater decreased the adsorbed amount of fluoride ion by forming a stable complex of $CaT^-$ and the adsorption reaction of fluoride ion on oyster shell was examined to be endothermic. The coexisting heavy metal ionic adsorbate in wastewater hindered the adsorption of fluoride ion, however, its adsorbed amount was increased as the particulate size of adsorbent was decreased. Finally, a serial adsorption column test has been conducted for a practical application of adsorption process and the breakthrough of the column adsorption was observed in 22 hours under the experimental condition.

Liquid ferrate(VI)에 의한 다양한 수중 환경에서의 tetracycline 분해특성 및 중간생성물 연구 (Degradation characteristics and intermediate study of tetracycline in aqueous system by liquid ferrate(VI))

  • 박경덕;강동환;소윤환;조정형;김일규
    • 상하수도학회지
    • /
    • 제34권1호
    • /
    • pp.61-73
    • /
    • 2020
  • Tetracycline is one of the most commonly used antibiotics in domestic and foreign livestock industries to suppress the growth of pathogens. Tetracycline has been reported as a non-biodegradable compound. Therefore it has been not completely removed in the sewage treatment process. In this study, tetracycline was degraded using liquid ferrate (VI). Based on these experiments, the optimal water condition (pH and water temperature) were selected, appropriate liquid ferrate (VI) dosage was calculated, and finally the degradation pathway was estimated with the intermediate products detected by LC/MS/MS. All degradation experiments were completed within 30 seconds and the optimal condition was obtained in basic condition (pH 10) at room temperature (20℃). And the appropriate molar ratio between tetracycline and liquid ferrate (VI) was 12.5:1. Finally, 12 intermediate products were detected with LC/MS/MS and the degradation pathways and the degradation pathways and proposed the degradation pathways.

Molecular Weight Distribution of Regenerated Silk Fibroin in Aqueous Solution

  • Jeong, Jae-Ho;Hur, Won
    • 한국생물공학회:학술대회논문집
    • /
    • 한국생물공학회 2003년도 생물공학의 동향(XIII)
    • /
    • pp.621-625
    • /
    • 2003
  • In order to investigate the properties of aqueous fibroin solution, the molecular weight distribution of silk fibroin was determined by gel filtration chromatography. The molecular weights spreaded from 200 kDa to less than 20 kDa. The distribution of molecular weight was significantly affected when the pH of solubilization solution is less than 1. Distributions of fibroin solution stored at various condition were also investigated.

  • PDF