• 한국신재생에너지학회:학술대회논문집
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• 2010.06a
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• pp.64.1-64.1
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• 2010

The morphology of mesoporous $TiO_2$ films plays an important role in the operation of a DSSC. For example, the energy conversion efficiency of DSSCs with well-organized mesoporous $TiO_2$ films is much higher than those with traditional films possessing a random morphology. In previous research, well-organized mesoporous $TiO_2$ films have mainly been synthesized using an amphiphilic block copolymer, e.g., a poly(ethylene oxide) (PEO)-based template. A graft copolymer is more attractive than a block copolymer due to its low cost and the ease with which it can be synthesized. In this work, we provide the first report on the successful synthesis of well-organized mesoporous $TiO_2$ films templated by an organized graft copolymer as a structure directing agent. Well-organized mesoporous $TiO_2$ films with excellent channel connectivities were developed via the sol gel processusing an organized PVC-g-POEM graft copolymer synthesized by one-pot ATRP. The careful adjustment of copolymer composition and solvent affinity using a THF/$H_2O$/HCl mixture was used to systematically vary the material structure. The influence of the material structure on solar cell performance was then investigated. A solid-state DSSC employing both the graft copolymer templated organized 700 nm-thick $TiO_2$ films and graft copolymer electrolytes exhibited a solar conversion efficiency of 2.2% at 100 $mW/cm^2$. This value was approximately two-fold higher than that attained from a DSSC employing a random mesoporous $TiO_2$ film. The solar cell performance was maximized at 4.6% when the film thickness was increased to $2.5{\mu}m$. We believe that this graft copolymer-directed approach introduces a new and simple route toward the synthesis of well-organized metal oxide films as an alternative to a conventional block copolymer-based template.

• Clean Technology
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• v.25 no.4
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• pp.283-288
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• 2019

Monodisperse microparticles has been particularly enabling for various applications in the encapsulation and delivery of pharmaceutical agents. The microfluidic devices are attractive candidates to produce highly uniform droplets that serve as templates to form monodisperse microparticles. The microfluidic devices that have micro-scale channel allow precise control of the balance between surface tension and viscous forces in two-phase flows. One of its essential abilities is to generate highly monodisperse droplets. In this paper, a microfluidic approach for preparing monodisperse polycaprolactone (PCL) microparticles is presented. The microfluidic devices that have a flow-focusing generator are manufactured by soft-lithography using polydimethylsiloxane (PDMS). The crucial factors in the droplet generation are the controllability of size and monodispersity of the microdroplets. For this, the volumetric flow rates of the dispersed phase of oil solution and the continuous phase of water to generate monodisperse droplets are optimized. As a result, the optimal flow condition for droplet dripping region that is able to generate uniform droplet is found. Furthermore, the droplets containing PCL polymer by solvent evaporation after collection of droplet from device is solidified to generate the microparticle. The particle size can be controlled by tuning the flow rate and the size of the microchannel. The monodispersity of the PCL particles is measured by a coefficient of variation (CV) below 5%.

• Journal of Digital Convergence
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• v.10 no.5
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• pp.105-116
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• 2012

This thesis is surveying the notions and the countermeasures of the farmers, who produce environmental-friendly crops, on a market and buyers. It ultimately tries to find out ways to increase the sale and the consumption of environmental-friendly crops from the side of the farmers. In chapter 2, analyzing the reality of consuming environmental-friendly crops and consumers inclinations. Also, on the basis of this, in chapter 3, I demonstrate how environmental-friendly producers countermeasures for the consumers are. I try to analyze the trust of the consumer buying environmental-friendly crops, which have been pointed out as a decisive factor for environmental-friendly crops by a lot of researchers, and analyze producers methods dealing with consumers approach to consume environmental-friendly crops. Regarding ways of the reconsideration about the trust, I have shown the problems about the quality authentication, forming consumers trust, and the ways of the consumer management. For the channel and method of the sale I have scrutinized not only a farmers notion about an internet homepage and his or her use but also producers principal sales route, cognition, and correspondence about it. Finally, I have examined the counter plans of the producer to increase sale and to facilitate consumption.

• Journal of KIISE:Information Networking
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• v.31 no.4
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• pp.414-428
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• 2004

Many portable devices are coming to be commercially successful and provide useful services to mobile users. Mobile devices may request a variety of data types, including text and multimedia data, thanks to the rich content of the Internet. Different types of data and/or different classes of users may need to be treated with different qualities of service. The implementation of service differentiation in wireless networks is very difficult because of device mobility and wireless channel contention when the backoff algorithm is used to resolve contention. Modification of the t)mary exponential backoff algorithm is one possibility to allow the design of several classes of data traffic flows. We present a study of modifications to the backoff algorithm to support three classes of flows: sold, silver, and bronze. For example, the gold c]ass flows are the highest priority and should satisfy their required target bandwidth, whereas the silver class flows should receive reasonably high bandwidth compared to the bronze class flows. The mixture of the two different transport protocols, UDP and TCP, in ad hoc networks raises significant challenges when defining backoff algorithm modifications. Due to the different characteristics of UDP and TCP, different backoff algorithm modifications are applied to each class of packets from the two transport protocols. Nevertheless, we show by means of simulation that our approach of backoff algorithm modification clearly differentiates service between different flows of classes regardless of the type of transport protocol.

• Journal of the Korean earth science society
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• v.27 no.1
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• pp.83-94
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• 2006

The objective of this paper is to extract and analyze the sediment environment change information in the Sachencheon, Gangneung, Korea that was seriously damaged as a result of typhoon Rusa aftermath early in September, 2002 using multi-temporal remote sensing data. For the extraction of change information, an unsupervised approach based on the automatic determination of thresholding values was applied. As the change detection results, turbidity changes right after typhoon Rusa, the decrease of wetlands, the increase of dry sand and channel width and changes of relative level in the stream due to seasonal variation were observed. Sedimentation in the cultivated areas and restoration works also affected the change near the Sacheoncheon. In addition to the change detection analysis, several environmental thematic maps including microtopographic map, distributions of estimated amount of flood deposits and flood hazard landform classification map were generated by using remote sensing and field survey data. In conclusion, multi-temporal remote sensing data can be effectively used for natural hazard analysis and damage information extraction and specific data processing techniques for high-resolution remote sensing data should also be developed.

• The Journal of Korean Institute of Electromagnetic Engineering and Science
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• v.15 no.11
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• pp.1043-1050
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• 2004

In this paper, Phase noise is analyzed and a novel approach of the nonlinear approximation including second order term of phase noise is presented to analyze and quantize system performance. As results, in QPSK-OFDM system, when PLL loop bandwidth is 5.0 Hz, 1.0 kHB, 0.5 kHz respectively, there are about 0.6 dB, 1.0 dB, 1.7 dB SNR penalties at BER=10$\^$-4/ compared with system without phase noise in AWGN channel. In 16QAM modulation, there are about 1.9 dB, 3.2 dB, 6.7 dB SNR penalties at BER=10$\^$-4/ respectively. At QPSK-OFDM system, comparing the previous linear approximation method with our proposed nonlinear approximation method, there is similar BER performance at phase noise variance lower than 0.02, but certain difference occurs as variance increases more than 0.02. Furthermore, analytical BER results closely match with simulation results in the OFDM system employing QPSK and 16qAM modulation. And, BER performance of QPSK-OFDM system is considerably degraded because of the BER error floor if the phase noise variance becomes larger than 0.03.

• Journal of the Korean earth science society
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• v.35 no.1
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• pp.29-40
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• 2014

A DC resistivity survey was performed to detect anomalies beneath concrete pavement. A set of high conductive media and planar electrodes were used to lessen the effect's a high contact resistance of concrete. Results of the resistivity survey were analyzed and compared with those of other geophysical surveys such as Ground Penetration Radar (GPR), Impulse Response (IR), and Multi-channel Analysis of Surface Waves (MASW), which were carried out in the same location. The results of resistivity survey showed a high resistive distribution in the section of sink and pavement where a pattern of reinforcement was observed through the GPR survey. Also, a comparison of results between the IR and resistivity surveys indicated that the high resistivity was produced by the high dynamic stiffness in the reinforced section. The co-Kriging of both the results of DC resistivity and MASW surveys at the same location showed that an integrated geostatistical analysis is able to give more accurate description on the anomalous subsurface region than can a separate analysis of each geophysical approach. This study suggests that the integrated geostatistical approaches were used for a decision-making process based on the geophysical surveys.

• The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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• v.5 no.4
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• pp.257-266
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• 2000

A vertically-averaged, two-dimensional version of the Princeton Ocean Model has been applied to the South Sea to simulate the circulation driven by tides and inflows/outflows across open boundaries. To incorporate both forcing properly, a two-step modeling approach is adopted, in which the tidal circulation is first simulated by specifying the tides along the open boundaries, and then both the calculated tidal currents and the observed steady mean currents are prescribed across the open boundaries. Model results show that the steady, subtidal circulation of the South Sea is different from the residual circulation due to tidal rectification, and subtidal currents become locally as strong as tidal currents. The Cheju Current entering the model domain across the Cheju Strait flows eastward in general while shifting onshore or offshore areas following local isobaths. The Tsushima Current entering across the southern boundary reaches farther to the north in the eastern vicinity of Cheju-Do as compared to that entering across other parts of the southern boundary. The Tsushima Current turns to the east, merges with the Cheju Current, and both the Cheju and Tsushima Current exit to the East Sea through the western channel of the Korea Strait. An intensification of the outflow occurs over the deep trough adjacent to the Tsushima Island, which appears to be due to the formation of the frictional boundary layer in order to remove excess positive relative vorticity generated by an increase in the layer thickness. The circulation driven by both the tidal and inflows/outflows is different from that driven by each forcing separately in coastal areas, which implies that both forcings should be considered simultaneously in the simulation of more realistic coastal circulation.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.37 no.3
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• pp.575-583
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• 2017

Various types of flow patterns around the stepped weir and spillway, such as the skimming flow over such structures and the wave-type flow with a standing undular hydraulic jump and roller downstream of the structures, are developed in open channels. Unsteady three-dimensional numerical simulations are carried out using a hybrid RANS-LES turbulence modeling approach and the volume of fluid method for resolving free surface fluctuations to represent the turbulent flow including the skimming flow and wave-type flow over a stepped weir installed in a rectangular channel. The comparison of numerical results with an existing experimental measurement reveals that the present numerical simulations reasonably well reproduce the turbulent flow passing the stepped weir, in terms of time-averaged velocity profiles at selected locations downstream of the weir, flow topology characterized by the wave-type and skimming flows, the maximum height and length of the standing wave and the length of reattachment of recirculating zone. The numerical result further elucidates the distinct flow behaviors of the wave-type and skimming flow by presenting instantaneous intense variations of free surface and velocity vectors, the distributions of Reynolds shear stress and turbulent kinetic energy and three-dimensional complex features of coherent structures and total pressure distribution.

• Economic and Environmental Geology
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• v.6 no.3
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• pp.171-182
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• 1973

Gemorphological and photogeological techniqes are applied to the problem of geological mapping of a semi-arid area, Albudeite, Southeastern Spain. As a result of this, a geological and surface materials map is made which shows the upper Miocene formation, which mainly consists of marl, limestone and sandstone, is further subdivided into three members, i. e. lower, middle and upper, and the post-Miocene deposits were differentiated into seven stratigraphic units, and mapped. The relationships between geology, landforms and land comlexes previously reognized have been reviewed. The methods adopted have proved to be valuable in interpreting and mapping a compex relationship in which highly variable bedrock outcrops and shallow surface materiales produced under sub-aerial conditios.