• Title/Summary/Keyword: Apparent charge

Search Result 55, Processing Time 0.026 seconds

Space Charge Behavior of Oil-Impregnated Paper Insulation Aging at AC-DC Combined Voltages

  • Li, Jian;Wang, Yan;Bao, Lianwei
    • Journal of Electrical Engineering and Technology
    • /
    • v.9 no.2
    • /
    • pp.635-642
    • /
    • 2014
  • The space charge behaviors of oil-paper insulation affect the stability and security of oil-filled converter transformers of traditional and new energies. This paper presents the results of the electrical aging of oil-impregnated paper under AC-DC combined voltages by the pulsed electro-acoustic technique. Data mining and feature extractions were performed on the influence of electrical aging on charge dynamics based on the experiment results in the first stage. Characteristic parameters such as total charge injection and apparent charge mobility were calculated. The influences of electrical aging on the trap energy distribution of an oil-paper insulation system were analyzed and discussed. Longer electrical aging time would increase the depth and energy density of charge trap, which decelerates the apparent charge mobility and increases the probability of hot electron formation. This mechanism would accelerate damage to the cellulose and the formation of discharge channels, enhance the acceleration of the electric field distortion, and shorten insulation lifetime under AC-DC combined voltages.

Current Saturation in the Electrical Resistivity Method (전기비저항탐사에서 전류포화현상)

  • Kang, Hye-Jin;Cho, In-Ky
    • Geophysics and Geophysical Exploration
    • /
    • v.13 no.4
    • /
    • pp.370-377
    • /
    • 2010
  • In this study, we investigated the current saturation which forces the apparent resistivity to converge when the conductivity contrast between the anomalous body and background medium is greater than a specific value. Analizing theoretical and numerical solutions for some simple models, we studied the behavior of the surface charge, and how the surface charge cause the current saturation and finally lead to the convergence of the apparent resistivity in the resistivity method. As a consequence of above analysis, we verified that the current saturation makes the apparent resistivity converge to a specific value and the magnitude of the apparent resistivity anomaly be less than that of the ideal conductor or insulator in the resistivity method. In general, current saturation is considered to occur when the conductivity contrast becomes larger than 100.

Charge Determination of Humic Acid and Humic Extract by Spectrophotometry

  • Kam Sang Kyu;Cho Eun Il
    • Environmental Sciences Bulletin of The Korean Environmental Sciences Society
    • /
    • v.2 no.2
    • /
    • pp.139-148
    • /
    • 1998
  • The charge densities of humic acid and humic extract have been determined by back titration using spectrophotometry as the method of end point detection and several cationic polymers of different charge density(copolymers of acylamide and dimethylaminoethylacrylate and polydiallyidimethylammonium chloride, PDDA), and a cationic indicator o-toluidine blue(o-Tb). The charge densities of humic acid and humic extract obtained depend on the charge densities of cationic polymers used. When the polymers of lower charge density are used, lower apparent charge density values are obtained, but for polymers of high charge density(above 2.5 meq/g), the measured values are almost identical, but also are nearly the same as that obtained for PDDA which has a high charge density(about 6 meq/g). For polymers of lower charge density, it is considered that the optimum dosage does not correspond to 1 :1 charge neutralization between anionic and cationic groups. Polymers of high charge density should be used in order to achieve a complete charge neutralization. As humic acid and humic extract are dissociable acids, their ionization is heavily pH dependent and so higher charge density values are obtaines with increasing pH.

  • PDF

Determination of Medium Components in the Flocculating Activity and Production of Pestan Produced by Pestalotiopsis sp. by Using the Plackett-Burman Design

  • Moon, Seong-Hoon;Hong, Soon-Duck;Kwon, Gi-Seok;Suh, Hyun-Hyo;Kim, Hee-Sik;An, Keug-Hyun;Oh, Hee-Mock;Mheen, Tae-Ick;Yoon, Byung-Dae
    • Journal of Microbiology and Biotechnology
    • /
    • v.8 no.4
    • /
    • pp.341-346
    • /
    • 1998
  • Optimization for the production of Pest an was followed by the Plackett-Burman Design, using modified Czapek-dox medium as the starting point. At the flask level, $K_2HPO_4$, $MgSO_4{\cdot}7H_2O$, and aeration variables positively affected the Pestan production, DCW (dry cell weight), apparent viscosity, and flocculating activity response. KCI and $FeSO_4{\cdot}7H_2O$ negatively affected the Pestan production, DCW, apparent viscosity, and flocculating activity response. Aeration variable was shown to have a positive effect on only the flocculating activity response among Pestan production, DCW, and apparent viscosity responses. In comparison of the positive and negative variables media conditions, Pestan production and flocculating activity differed by about 9 and 125 times, respectively. In particular, at the jar fermentor level, the aeration variable was the most important factor of the all responses (pestan production, DCW, apparent viscosity, flocculating activity, and anionic charge density). The flocculating activity and apparent viscosity of Pestan were closely related to the molecular chain length and charge density.

  • PDF

Electron Tunneling and Electrochemical Currents through Interfacial Water Inside an STM Junction

  • Song, Moon-Bong;Jang, Jai-Man;Lee, Chi-Woo
    • Bulletin of the Korean Chemical Society
    • /
    • v.23 no.1
    • /
    • pp.71-74
    • /
    • 2002
  • The apparent barrier height for charge transfer through an interfacial water layer between a Pt/Ir tip and a gold surface has been measured using STM technique. The average thickness of the interfacial water layer inside an STM junction was controlled by the amount of moisture. A thin water layer on the surface was formed when relative humidity was in the range of 10 to 80%. In such a case, electron tunneling through the thin water layer became the majority of charge transfers. The value of the barrier height for the electron tunneling was determined to be 0.95 eV from the current vs. distance curve, which was independent of the tip-sample distance. On the other hand, the apparent barrier height for charge transfer showed a dependence on tip-sample distance in the bias range of 0.1-0.5 V at a relative humidity of approximately 96%. The non-exponentiality for current decay under these conditions has been explained in terms of electron tunneling and electrochemical processes. In addition, the plateau current was observed at a large tip-sample distance, which was caused by electrochemical processes and was dependent on the applied voltage.

A study on the apparent and partial molal volumes of n-Alkyl amine hydrochloride in water (n-Alkyl amine 鹽酸鹽의 水溶液 中에서의 apparent 및 partial molal volumes에 관한 硏究)

  • Yoon Sang Ki
    • Journal of the Korean Chemical Society
    • /
    • v.13 no.2
    • /
    • pp.121-129
    • /
    • 1969
  • The apparent and partial molal volumes({\phi}\nu$and $V^{\circ}$) of a series of homologous n-alkylamine hydrochlorides $C_nH_{2n+1}NH_3^+Cl^-$, where n varies from zero to four, have been determined by means of a float method at 30$^{\circ}C$ to the fifth decimal place down to 0.01M in aqueous solutions. The experimental results indicate that the partial molal volumes of the salts are almost additive for successive homologues depending on the increment of molecular weight ($CH_2$). It has been observed that the concentration dependence of the ${\Phi}v$ are linear in general and limiting slopes are positive and relatively close to the theoretical values. Anionic partial molal volume of chlorides anion $V^{\circ}_{Cl^-}$ is found to be 18.6 ml $mole^{-1}$, which is in good agreement with the results of other workers. {\phi}\nu$ data also show that in solution the hydrophobic effect of ions are in competition with the charge effect, but the latter, that is, electrostriction seemed to be considerably predominant.

  • PDF

Space Charge Phenomena in Polyimide Films and Effects of Absorbed Water (폴리이미드 박막의 공간전하현상 및 수분의 영향)

  • Yun, Ju-Ho;Choi, Yong-Sung;Hwang, Jong-Sun;Lee, Kyung-Sup
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 2008.04c
    • /
    • pp.82-85
    • /
    • 2008
  • Polyimide is widely used as a high-temperature insulating material. Space charge distributions in polyimide (PI) films strongly depend upon electric field, temperature, water content and so on. We observed space charge distributions in PI films with various water contents. When a dc field was applied to as-received PI films or water-treated PI films, positive and negative homo space charges were observed near the respective electrodes at 333 K. In dried PI films, the homo space charges were much reduced, and positive and negative hetero space charges in the bulk were clearly observed. The space charge amounts in water-treated PI films were smaller than in as-received ones, while the current density in water-treated PI film was larger than that in as-received one by two or more orders of magnitude. These suggest not only that the charge injection from the electrode is enhanced by absorbed water but also that absorbed water makes carriers mobile. The decay of space charge was also faster in water-treated PI than in as-received or dried one. This also supports the enhancement of apparent mobilities of carriers in PI by absorbed water.

  • PDF

Space Charge Phenomena in Polyimide Films (폴리이미드 박막의 공간전하현상)

  • Yun, Ju-Ho;Choi, Yong-Sung;Lee, Kyung-Sup
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 2007.11a
    • /
    • pp.311-312
    • /
    • 2007
  • Polyimide is widely used as a high-temperature insulating material. Space charge distributions in polyimide (PI) films strongly depend upon electric field, temperature, water content and so on. We observed space charge distributions in PI films with various water contents. When a dc field was applied to as-received PI films or water-treated PI films, positive and negative homo space charges were observed near the respective electrodes at 333 K. In dried PI films, the homo space charges were much reduced, and positive and negative hetero space charges in the bulk were clearly observed. The space charge amounts in water-treated PI films were smaller than in as-received ones, while the current density in water-treated PI film was larger than that in as-received one by two or more orders of magnitude. These suggest not only that the charge injection from the electrode is enhanced by absorbed water but also that absorbed water makes carriers mobile. The decay of space charge was also faster in water-treated PI than in as-received or dried one. This also supports the enhancement of apparent mobilities of carriers in PI by absorbed water.

  • PDF

A Study on the Management Service Charge in Multi-Family Housing : The Opinions of the Residents and Housing Managers in Condominium (아파트의 입주자관리 서비스 비용 부과 방식에 대한 연구 - 분양아파트 거주자와 관리자의 의견을 중심으로 -)

  • Chae Hye-Won;Rhee Kyung-Hee
    • Journal of Families and Better Life
    • /
    • v.24 no.1 s.79
    • /
    • pp.43-53
    • /
    • 2006
  • The purpose of this study was to explore the attitudes about the management service charge in multi-family housing. Recently, increasing needs of urban families in residential housing management services were apparent in many studies, but the way that they charge for the management services was not dear. Research method was social survey with questionnaire from 484 residents and 84 housing managers of multi-family housing in Seoul and new town area. Research results showed that residents recognized the management services should be free of charge or imposed actual expenses, but managers recognized the management services as charged services. To provide efficient housing management services for residents in multi-family housing, human resources should be inputted. Therefore, this study suggested that the participation of residents in housing management service is recommendable as a way of lessen the economic burden of management service charge, but also to have an opportunity to interest in their community activities.

Studies on the Charge-transfer Complex including Aflatoxin $B_1$ -Part I. Charge-transfer Complex with Benzene- (Aflatoxin $B_1$ Charge-transfer Complex에 관(關)한 연구(硏究) -제1보(第一報) Benzene과의 Charge-transfer Complex-)

  • Noh, Ick-Sam;Lee, Kang-Heup
    • Applied Biological Chemistry
    • /
    • v.17 no.2
    • /
    • pp.143-148
    • /
    • 1974
  • The interaction of the carcinogenic mycotoxin, Aflatoxin $B_1$, with the electron-donating molecule, benzene, was studied spectrophotometrically. The formation of charge-transfer complex between Aflatoxin $B_1$ and benzene in the presence of zinc chloride was observed and the apparent equilibrium constant of this charge-transfer complex was found to be 0.198 (liter $mole^{-1}$). It is assumed that, as the result of this study, some charge-transfer complexes could be formed between the weak electron-accepting Aflatoxin $B_1$ and strong electron-donating molecules, and the spectral changes occurred in the binding of Aflatoxin $B_1$ with proteins or DNA is attributed to the existence of charge-transfer type interaction.

  • PDF