• 제목/요약/키워드: Anti-wear

검색결과 142건 처리시간 0.037초

Dithiophosphate Group을 함유한 디올유도체의 합성 및 내마모성-말단 알킬기 및 몸체 알킬기의 탄소사슬에 따른 영향 (Synthese and Anti-wear Properties of Diol Derivatives Containing Dithiophosphate Group-effect on Main Alkyl Chain and Side Alkyl Chain)

  • 고경민;한혜림;김영운;강호철;정노희
    • 공업화학
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    • 제29권4호
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    • pp.405-412
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    • 2018
  • 알칸디올로부터 유래된 주사슬의 탄소수가 6, 9, 11인 bis[3-(dialkyloxylphosphorothionyl)thio-2-methylpropanyloxy]alkane (BAPA)를 합성하였으며, 이를 zinc dialkyl dithiophosphates (ZDDP)와 비교하여 마모억제성능을 살펴보았다. 탄소 주사슬의 길이에 따른 BAPA의 내마모성능을 확인하기 위하여 4-ball 시험을 하였다. 기유무게의 1% 농도로 첨가제를 넣고 WSD (wear scar diameter)를 측정하였고, 각 0.472, 0.459, 0.480 mm로 나타났다. 또한 BAPA 화합물 중 bis[methacryloyloxy]nonane (BMOO9)의 곁사슬인 dialkyl dithiophosphoric acid (DDP)의 탄소수를 4, 8, 12로 변화시켜 합성하여, 4-ball 시험을 하였다. 그 결과로 WSD의 값은 각각 0.537, 0.459, 0.531 mm로 측정되었다. 곁사슬이 짧으면 필름이 얇게 형성되고, 길면 필름형성을 방해하여 탄소수가 8개일 때의 값이 제일 좋게 나타났다. ZDDP의 경우 동일한 조건에서 WSD의 값이 0.563 mm로 측정되었고, 합성한 BAPA의 화합물이 마모억제용 첨가제로 더 우수한 성능을 갖는다는 것을 확인하였다.

석출상이 분산제어된 내마모성 니켈기 윤활합금 연구 (A Study on Ni Base Anti-galling alloy with Finely Dispersed Precipitates)

  • 김용규;김경탁
    • 한국주조공학회지
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    • 제26권4호
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    • pp.191-196
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    • 2006
  • The effects of Bi and Te on the anti-galling behaviors of Ni base alloy were investigated by SEM, galling test and wear test. Anti-galling characteristics depended on the structure of matrix and distribution of Bi-rich phase which was precipitated at grain boundary. The addition of 5 wt% Bi markably enhanced anti-galling properties. The addition of Te caused Bi-rich precipitates to disperse finely and casting structure to form equiaxed type. From the above tests, the concentration of 5 wt% Bi and 1 wt% Te was selected to optimize in this alloy.

탄소 섬유 복합재의 마찰 및 마모 특성에 미치는 속도 효과 (Effect of sliding velocity on the wear and friction characteristics of a carbon fiber composites)

  • 고성위;양병춘
    • 수산해양기술연구
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    • 제40권4호
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    • pp.337-343
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    • 2004
  • 탄소 섬유강화 에폭시기지 복합재의 경면 가공한 스테인레스 강 상대재와 마찰과 마모에 바탕을 둔 연구에서 다음과 같은 결론을 얻었다. (1) 일방향 탄소섬유 강화 복합재의 마모 거동에 미치는 미끄럼 방향의 효과는 다르며 작용하는 마모 메커니즘의 형태에 의존한다. (2) 상온에서 경면 가공한 스테인리스 스틸에 대하여 미끄럼이 일어나면 AP 방향에서 높은 마모 저항과 낮은 마찰계수가 관찰되었다. (3) 복합재의 비마모율은 미끄럼 속도가 증가하면 N방향과 P방향에서는 감소하는 경향을 보이며, AP 방향에서는 증가하다가 감소한다. 이것은 마모 메카니즘의 영향으로 속도가 증가하면 마모 이착막의 생성이 빨라져 이착막 속의 탄소섬유가 윤활제의 역할을 하기 때문이다. (4) 복합재의 마찰계수는 미끄럼 속도가 증가하면 3방향 모두 증가하다가 일정한 값에 수렴하면 N방향이 가장 크며, P방향과 AP방향 순이다. 이는 N방향에서 마찰초반에 발생한 섬유의 쟁기질에 의한 상대재 표면의 손상과 돌기변형에 따른 것이며, AP방향의 마찰계수가 가장 낮다.

ANTIWEAR FILM FORMATION BY COMPONENTS OF PASSENGER CAR MOTOR OILS

  • Yamaguchi, E.S.;Roby, S.H.;Francisco, M.M.;Ruelas, S.G.
    • 한국윤활학회:학술대회논문집
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    • 한국윤활학회 2002년도 proceedings of the second asia international conference on tribology
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    • pp.267-268
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    • 2002
  • Engine testing of new low-sulfur, low-phosphorus anti wear components is expensive and time consuming so bench testing of potential candidates is highly desirable as a first step evaluation. Electrical contact resistance (ECR) has been shown to be a convenient method to assess antiwear film formation in a ball-on-flat bench wear test. Correlation of the bench test to fired engines was demonstrated for lubricants varying only in the type of detergent. Previous papers have examined film formation by one and two component formulations of zinc dialkyldithiophosphate (ZnDTP) and detergents. In this study, the ECR technique is systematically extended to formulations including ZnDTP, detergent, and dispersant. Both type and level of components are considered and the implications for engine performance are discussed.

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탄화물 강화 Ni-Grain Roll개발 (Development of the Carbide Reinforced Ni-Grain Roll)

  • 서용찬;정봉호;이형철;김윤기
    • 한국소성가공학회:학술대회논문집
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    • 한국소성가공학회 2004년도 제5회 압연심포지엄 신 시장 개척을 위한 압연기술
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    • pp.223-230
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    • 2004
  • In order to improve the productivity and quality of the hot rolled products, many morden mills have continuously required advanced roll materials. The introduction of HSS rolls in early stands of the Hot Strip Mill brought the excellent performance in wear resistance and surface roughness. Ni-grain rolls used in the later stands was needed to improve the roll performance. Therefore, the carbide reinforced Ni-grain roll was developed. The present paper will describe the development of carbide reinforced rolls made by INI STEEL and the results of mill tests. The wear resistance was increased upto $40\%$ and the anti-accident ablility was remarkably improved compared to the normal Ni-rain roll.

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태양전지의 반사방지막을 위한 Silica 코팅의 트라이볼로지 및 광학적 특성 평가 (Tribological and Optical Characteristics of Silica Coating for Anti-reflection Coating of Solar Cell)

  • 김해진;김대은
    • 정보저장시스템학회논문집
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    • 제6권2호
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    • pp.68-73
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    • 2010
  • The interest in acquiring high efficiency solar cells has been steadily increasing due to various advantages such as low-cost installation, pollution free and everlasting energy generation. In order to raise the cell efficiency, there has been a lot of effort to develop effective anti-reflection coatings. In this work, the main objective was to investigate the effects of particle size and annealing temperature of silica anti-reflection coatings to maximize the cell efficiency as well as reliability. It was shown that the light transmittance could be increased by a few percent over a certain range of wavelength using the silica coating. Also, the tribological properties of the coating could be improved through the annealing process, which led to better reliability of the coating.

MoS2/Montmorillonite Nanocomposite: Preparation, Tribological Properties, and Inner Synergistic Lubrication

  • Cheng, Lehua;Hu, Enzhu;Chao, Xianquan;Zhu, Renfa;Hu, Kunhong;Hu, Xianguo
    • Nano
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    • 제13권12호
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    • pp.1850144.1-1850144.13
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    • 2018
  • A nano-$MoS_2$/montmorillonite K-10 (K10) composite was prepared and characterized. The composite contains two types of 2H-$MoS_2$ nanoparticles. One is the hollow spherical $MoS_2$ with a size range of 75 nm, and the other is the spherical nano cluster of $MoS_2$ with a size range of 30 nm. The two kinds of nano-$MoS_2$ were formed via assembly of numerous $MoS_2$ nano-platelets with a size of ~10 nm. A tribological comparison was then made among nano-$MoS_2$/K10, K10, nano-$MoS_2$ and a mechanical mixture of K10 and nano-$MoS_2$. K10 reduced the wear but slightly increased the friction. Nano-$MoS_2$ remarkably reduced both friction and wear. The mechanical mixture demonstrated better wear resistance than nano-$MoS_2$, indicating a synergistic anti-wear effect of nano-$MoS_2$ and K10. The synergistic effect was reinforced using nano-$MoS_2$/K10 instead of the mechanical mixture. A part of the $MoS_2$ in the contact region always lubricated the friction pair, and the rest formed a tribofilm. K10 segregated the friction pair to alleviate the ablation wear but magnified the abrasive wear. S-$MoS_2$ protects K10 and they together function as both a lubricant and an isolating agent to reduce the ablation and abrasive wear.

$MoS_{2}$와 PTFE 코팅재료에 의한 자동차 피스톤 운동의 윤활특성 연구 (A Study on the Lubricational Characteristics of Automotive Piston Motions With $MoS_{2}$ and PTFE Coating Materials)

  • 오성모;문상돈
    • 한국공작기계학회논문집
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    • 제16권2호
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    • pp.57-62
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    • 2007
  • The lubricational characteristics about friction wear has an effect on the material quality of surface. In this paper, we studied the lubricational characteristics through the surface modification experiment by spray coating the surface with $MoS_{2}$ and PTFE solid lubricants. In the case of $MoS_{2}$ and PTFE coating, the friction coefficient of Journal is lower than that for noncoating so the friction characteristics is excellent. In particular, the beginning characteristics of $MoS_{2}$ coating is excellent, and in the case of PTFE coating, seizure dose not appear seizure. $MoS_{2}$ and PTFE coating are excellent in the extreme pressure at high load. The wear characteristics is excellent in the following order; PTFE < $MoS_{2}$ < Non Coating. For Non coating, seizure appears at the beginning due to the heat, but in the case of $MoS_{2}$ and PTFE coating, it will have the excellent heat stability even at high temperature.

왁스와 오일 또는 흑연의 함침에 의한 나일론의 마찰특성 향상에 관한 연구 (A Study on the Improvement of Frictional Properties of Nylon Impregnated with Wax and Oil or Graphite)

  • 강석춘;정대원
    • 한국자동차공학회논문집
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    • 제10권6호
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    • pp.142-149
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    • 2002
  • The frictional properties of nylon can be improved by the impregnation of lubricants like wax, oil or graphite. The inclusion of these lubricants, on the other hand, decreases the mechanical properties of nylon, such as tensile strength, hardness and impact strength. As an attempt to maximize frictional properties, while minimizing a decrease in the mechanical properties, various kinds of nylon containing 3 wt% wax and varying contents of oil or graphite were prepared. It was found that the synergy effects to improve both friction and anti-wear properties is evidenced by impregnating a combination of wax/oil or wax/graphite. The wear rate of a nylon containing 3 wt% of wax and 1.5 wt% of oil turned out to be 1/4 of that of nylon impregnated with 8 wt% wax or 8 wt% oil. The latter showed the lowest wear rate among the nylons prepared with a single lubricant. In addition, the friction coefficient of the developed nylon was found to be very similar to the nylon with 8 wt% wax only.

자동차 엔진 프론트부의 PTFE 오일씰의 성능평가 (Performance Evaluation of PTFE Oil-seal for Automotive Engine Front Part)

  • 최현진;박철우;이종철;김종갑;최성대
    • 한국자동차공학회논문집
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    • 제19권2호
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    • pp.66-71
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    • 2011
  • This study analyzed the mechanical characteristics and evaluated their subsequent performance for two types of seals which reinforced characteristics with lower friction and anti-wear functions among the foremost important features in the automotive engine seals; one with the addition of glass fiber to PTFE(Polytetrafluoro ethylene); the other with the addition of self-lubricant molybdenumin addition to the glass fiber. Based on the configuration design of seal installed to the front part in the automotive engine, this study carried out interpretations on the stress and reaction for those two types of oil seals to compare the maximum stress and contact load generated from the seal steel, rubber and PTFE lip. This study also verified the stress concentration and anti-wear performance through the coefficient of friction, torque and durability test by producing two types of PTFE seals actually.