• 제목/요약/키워드: Anti-corrosion properties

검색결과 121건 처리시간 0.026초

플라즈마 불소화에 의해 제조된 불소 도핑 PVDF의 표면 및 부식방지 특성 (Surface and Corrosion Protection Properties of Fluorine Doped PVDF by Plasma Fluorination)

  • 김석진;임채훈;김대섭;이영석
    • 공업화학
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    • 제32권6호
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    • pp.653-658
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    • 2021
  • Polyvinylidene fluoride (PVDF)는 우수한 가공성을 가지고 있어 코팅 재료로 유망하지만 다른 불소계 고분자에 비하여 소수성이 약하여 부식 방지 등 그 응용에 제한이 있다. 본 연구에서는 PVDF의 부식방지 특성을 향상시키고자 사불화탄소(CF4) 가스를 이용하여 플라즈마 불소화를 수행하였고, 유량에 따른 불소 함량 및 소수성 변화를 고찰하고 부식방지 특성을 확인하였다. PVDF 막 표면의 불소 함량은 사불화탄소 유량이 증가함에 따라 46.70%로 증가하였으나 그 표면자유에너지는 불소함량의 증가와 일치하지 않았다. 한편, PVDF 표면의 표면 거칠기는 불소화 유량에 따라 최대 150% 증가하다가 다시 감소하는 경향을 보였다. 이는 플라즈마 불소화는 불소화 기능기 도입 및 표면식각으로 인하여 표면자유에너지에 영향을 주는 것으로 판단된다. 또한, PVDF 코팅된 철판의 부식 정도는 미처리 철판에 비하여 표면 산소 함량이 49.2%에서 19.0% 이하로 크게 개선되었으며, 특히, 불소화 처리된 PVDF의 산소함량은 13.6%으로 불소화 처리되지 않은 PVDF보다 28.4 % 정도 낮아져 우수한 부식방지 특성을 보이는 것으로 관찰되었다.

Bioinspired Nanoengineering of Multifunctional Superhydrophobic Surfaces

  • Choi, Chang-Hwan
    • 한국표면공학회:학술대회논문집
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    • 한국표면공학회 2015년도 추계학술대회 논문집
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    • pp.102-133
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    • 2015
  • Nature, such as plants, insects, and marine animals, uses micro/nano-textured surfaces in their components (e.g., leaves, wings, eyes, legs, and skins) for multiple purposes, such as water-repellency, anti-adhesiveness, and self-cleanness. Such multifunctional surface properties are attributed to three-dimensional surface structures with modulated surface wettability. Especially, hydrophobic surface structures create a composite interface with liquid by retaining air between the structures, minimizing the contact area with liquid. Such non-wetting surface property, so-called superhydrophobicity, can offer numerous application potentials, such as hydrodynamic drag reduction, anti-biofouling, anti-corrosion, anti-fogging, anti-frosting, and anti-icing. Over the last couple of decades, we have witnessed a significant advancement in the understanding of surface superhydrophobicity as well as the design, fabrication, and applications of superhydrophobic coatings/surfaces/materials. In this talk, the designs, fabrications, and applications of superhydrophobic surfaces for multifunctionalities will be presented, including hydrodynamic friction reduction, anti-biofouling, anti-corrosion, and anti-icing.

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미술작품의 보존을 위한 기화성 방청제 및 방청필름의 적용성 연구 (Applicability of Volatile Corrosion Inhibitor and VCI Films for Conservation of Artworks)

  • 범대건;한예빈
    • 보존과학회지
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    • 제36권2호
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    • pp.82-92
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    • 2020
  • 현대 미술작품은 재료와 제작기법, 종류가 매우 다양하게 사용되고 있으며 특히 조각작품 중 많은 비율을 차지하는 금속의 경우 형태가 다양하고 여러 재질과 혼합된 작품이 다수 존재한다. 이러한 구조적, 재료적 특성은 보존처리 시 기존의 처리 방법을 적용하기 어려운 경우가 많아 보다 다양한 처리 재료 및 방법이 요구된다. 본 연구에서는 금속 작품의 효과적인 보존처리를 위해 방청제(Rust inhibitor, 防錆劑)를 작품에 직접적으로 도포하는 방법이 아닌 기화성 방청제를 적용하였으며, 기화성 방청제 및 이를 함유한 방청필름의 방청효과를 평가하였다. 금속 시편을 대상으로 기화성 방청제를 적용한 방청처리 결과, 시편의 색도 변화는 미미하였으며, 부식 속도는 방청 미처리 시편과 비교하였을 때 절반 정도 감소하는 것을 확인하였다. 방청필름 적용 실험 결과, 방청필름 사용 시 미처리 및 폴리에틸렌 필름을 사용한 시편보다 부식화합물의 발생이 감소하였다. 접촉각 및 표면에너지, 표면전기저항 측정을 통해 표면의 물성을 측정하였으며 방청피막이 형성됨을 확인하였다. 또한 기화성 방청제 및 방청필름을 실제 조각작품에 적용하여 방청효과를 확인하였다.

Valorization of Cork Waste to Improve the Anti-Corrosion Properties of Concrete Reinforcements

  • Belkhir, S.;Bensabra, H.;Chopart, J.P.
    • Corrosion Science and Technology
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    • 제21권2호
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    • pp.100-110
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    • 2022
  • Corrosion of steel reinforcement is the most important mode of concrete structures damages. It strongly depends on the composition and physicochemical properties of the cementitious medium. The use of waste materials as lightweight aggregates in concrete is environmentally recommended in polluted environments such as marine and/or industrial atmospheres in order to reduce its porosity and ensure the requested protection of reinforcing steel. The present study investigated the effect of waste cork addition on corrosion resistance of steel rebar in mortar specimen prepared in the laboratory. The main objective of this study was to improve the corrosion resistance of reinforcing steel. Another objective of this study was to valorize this ecological product and preserve the environment. Results obtained from various electrochemical tests indicated that the presence of a fine cork powder substantially improved the corrosion resistance of steel in the mortar contaminated by chloride ions. This improvement was reflected by a notable decrease in corrosion current density and a shift of corrosion potential of the steel towards more noble values. Moreover, the presence of a fine cork powder in the mortar had no adverse effect on its mechanical properties.

합금도금강판 내식성 향상을 위한 UV 경화형 유무기 하이브리드 코팅 (Improvement of anti-corrosive property for alloy plated steel sheet by UV curable organic-inorganic hybrid coatings)

  • 박종원;이경황;나현주;박병규;남영섭;홍신협
    • Corrosion Science and Technology
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    • 제12권1호
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    • pp.27-33
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    • 2013
  • According to its merits about high curing speed and low emission of volatile organic compounds, UV curable inorganic-organic coating technology has been developed as an alternative for toxic and carcinogenic chromate-based treatments for years. It is consistently observed that ultra-thin films offer excellent corrosion protection as well as paint adhesion to metals. Based on the tetra-ethylorthosilicate(TEOS) and methacryloxypropyl trimethoxysilane(MPTMS), inorganic sol was synthesized and formed hybrid networks with UV curable acrylic monomer, 6-hexanediol diacrylate(HDDA), trimethylolpropane triacrylate(TMPTA), pentaerylthritol triacrylate(PETA). Several methods were used to test their properties such as salt spray test, potentiodynamic measurement, tape peel test, etc. It was shown that anti-corrosive property and stability of storage were affected by the molecular ratios of inorganic and organic compounds. It was not only the stability of storage, but had a excellent anti-corrosive, paint adhesive, and anti-solvent properties in a final molar ratios of 0.6/0.04/0.86/0.005 (TEOS/MPTMS/Acetone/HNO3) and 0.08/0.106/0.081/0.02 (TMPTA/HDDA/PETA/photo initiator).

STS 316L 소결체의 부식 저항 특성에 미치는 금속산화물 첨가의 영향 (The Effect of Oxides Additives on Anti-corrosion Properties of Sintered 316L Stainless Steel)

  • 이종필;홍지현;박동규;안인섭
    • 한국분말재료학회지
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    • 제22권4호
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    • pp.271-277
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    • 2015
  • As wrought stainless steel, sintered stainless steel (STS) has excellent high-temperature anti-corrosion even at high temperature of $800^{\circ}C$ and exhibit corrosion resistance in air. The oxidation behavior and oxidation mechanism of the sintered 316L stainless was reported at the high temperature in our previous study. In this study, the effects of additives on high-temperature corrosion resistances were investigated above $800^{\circ}C$ at the various oxides ($SiO_2$, $Al_2O_3$, MgO and $Y_2O_3$) added STS respectively as an oxidation inhibitor. The morphology of the oxide layers were observed by SEM and the oxides phase and composition were confirmed by XRD and EDX. As a result, the weight of STS 316L sintered body increased sharply at $1000^{\circ}C$ and the relative density of specimen decreased as metallic oxide addition increased. Compared with STS 316L sintered parts, weight change ratio corresponding to different oxidation time at $900^{\circ}C$ and $1000^{\circ}C$, decreased gradually with the addition of metallic oxide. The best corrosion resistance properties of STS could be improved in case of using $Y_2O_3$. The oxidation rate was diminished dramatically by suppression the peeling on oxide layers at $Y_2O_3$ added sintered stainless steel.

고내식성 내지문 EGI 강판 개발 (Development of Anti-Fingers Printed EGI Steel Sheet With High Corrosion Resistance)

  • 김형준
    • 한국표면공학회지
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    • 제26권6호
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    • pp.307-315
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    • 1993
  • A study on a new anti-finger printed EGI steel sheet with high corrosion resistance has been carried out to meet the recent requirement of high quality and performance of the pure zinc electrogalvanized steel sheet. The substrate was the pure zinc electrogalvanized sheet with the metallic coating of 20g/$\m^2$. The two differ-ent processes for inorganic(chromating) and organic(resin) coating were applied. One was a two coat/two bake type to separately treat chromating and resin coating which is now widely used. The other was a one coat/one bake type to simultaneously treat them which is newly developed in this study. The solution for the one coat/one bake type was an aqua-base coating agents which was composed of inorganic and organic components. The new anti-finger printed EGI steel sheet with the Cr and resin coating weight of 13mg/$\m^2$ and 800mg/$\m^2$, respectively shows the superior corrosion resistance besides the good paintability, formability fingerprint resistance and earth characteristics properties.

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시멘트 혼입 폴리머와 에폭시수지를 복합한 상하수 시설용 방수${\cdot}$방식공법 성능평가에 관한 연구 (A study on the Property Evaluation of Waterproofinging and AntiCorrosion Systems Compositing Polymer Cement and Epoxy Resins)

  • 배기선;장종호;장성주;오상근
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2004년도 춘계 학술발표회 제16권1호
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    • pp.164-167
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    • 2004
  • The purpose of this study is to investigate the properties of composite systems using polymer cement and epoxy resins for waterproofing and anti-corrosion to concrete structures such as water supply facilities and sewage-works. In this study these engineering properties of composite systems using polymer-modified mortar and epoxy resins were examined and could be confirmed to satisfy the guidelines of KS. Especially, it was turn out that the adhesion properties was excellent and high crack-resistance up to 1.49mm will be perform.

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Zn, PTFE 복합 코팅에 의한 SS400 강의 해수 부식 특성 변화 연구 (Investigation of Corrosion Characteristics with Zn, PTFE Hybrid Coating for SS400 in Sea Water)

  • 한민수;박재철;장석기;김성종
    • Corrosion Science and Technology
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    • 제10권6호
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    • pp.205-211
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    • 2011
  • The severe corrosion environment makes the steel product lifecycle short while Cu-alloys with anti-corrosion characteristic used in sea water are too expensive. This study shows that the Cu-alloy(Cu-37.25% Zn-0.67%Al) used in sea water environment can be superseded by SS400 with various coating process, evaluating electrochemical characteristics. Three coating processes were applied to SS400 such as PTFE + Zn coaing, Zn + PTFE coating and only Zn electrogalvanizing coaing. Various electrochemical experiments such as open circuit potential measurments, potentiodynamic polarization tests and analyses of Tafel constants. Mechanical properties were also measured by tensile test and hardness tests. As a result, Zn + PTFE coating for SS400 steel presented the excellent anti-corrosion characteristic in sea water.

내식성 향상을 위한 기능성 타이타늄 표면 개질 (Surface Modification of Functional Titanium Oxide to Improve Corrosion Resistance)

  • 박영주;정찬영
    • Corrosion Science and Technology
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    • 제20권5호
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    • pp.256-265
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    • 2021
  • Titanium is applied in various industries due to its valuable properties and abundant reserves. Generally, if a highly uniform oxide structure and a high-density oxide film is formed on the surface through anodization treatment, the utility value such as color appearance and corrosion inhibition efficiency is further increased. The objective of this study was to determine improvement of water-repellent property by controlling titanium oxide parameters such as pore size and inter-pore distance to improve corrosion resistance. Oxide film structures of different shapes were prepared by controlling the anodization processing time and voltage. These oxide structures were then analyzed using a Field Emission Scanning Electron Microscope (FE-SEM). Afterwards, a Self-Assembled Monolayer (SAM) coating was performed for the oxide structure. The contact angle was measured to determine the relationship between the shape of the oxide film and the water-repellency. The smaller the solid fraction of the surface, the higher the water-repellent effect. The surface with excellent hydrophobic properties showed improved corrosion resistance. Such water-repellent surface has various applications. It is not only useful for corrosion prevention, but also useful for self-cleaning. In addition, a hydrophobic titanium may open up a new world of biomaterials to remove bacteria from the surface.