• Journal of Korean Society for Atmospheric Environment
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• v.7 no.3
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• pp.197-202
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• 1991

It is observed that the outbreak of dust storms (yellow sand) from Northern China and Mongolia occurs a few times in April 1988 and 1990. It is found that a dust storm initiated with strong gusty winds after the passage of a cold front, particularly after defrost of the ground surface of a source region in the early spring. According to meteorological chart, satellite images and trajectory analyses, dust clouds invaded Korea in April 1988 and 1990 were landing in the sink area after 2 $\sim$ 4 days travelling for 2,000 $\sim$ 3,000 km from a source region. It was also observed that in the west coast total suspended particulated (TSP) were 100 $\sim$ 200 $\mug m^{-3}$ and sulphates $(SO_4=)$ were 3 $\sim$ 10 $\mug m^{-3}$. These values clearly exceed the concentrations of a background level measured in the Arctic and Atlantic Ocean. Trajectory analyses and meteorological analyses suggest that the high values occurred with prevailing westerly flows coming from anthropogenic sources in China. High concentrations of air pollutants occurred in the backside of an anticyclone and in the area "col".col".uot;.

• Journal of Environmental Health Sciences
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• v.29 no.1
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• pp.67-73
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• 2003

This study was carried out to characterize the behavior and sources of particulate trace metal in Daegu city. TSP (Total Suspended Particulate matter) was collected by filters on High Volume Air Sampler from the four areal (reference, residential, commercial, industrial area). The moult were analyzed by AAS after preliminary treatment. The average centration trend of trace metals contained in TSP was shown as follows : Fe > Cu > Pb > Mn > Ni > Cr > Cd. The trace metals showed the highest concentration in the industrial area. This study showed the seasonal variation of trace metals. Fe and Mn showed high concentration in spring, whereas Cr, Ni, Cd and Pb showed high concentration in winter. Also this study showed the regional variation of trace metals. The order of the average concentration of trace metals was : industrial > commercial > residential > reference area. Using Mn as a reference element, the enrichment factor analysis were used for identifying the trace element contributors. The enrichment factors of Cr, Fe < 10 were considered to have a significant dust and soil source and termed nonenriched. Pb, Cd, Cu >>10 were enriched and had a significant fraction which was contributed by anthropogenic sources.

• Journal of Korean Society for Atmospheric Environment
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• v.2 no.2
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• pp.66-74
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• 1986

Rain samples were collected at 10 sites in the Seoul area during the period of August through November, 1985. THe concentrations of the major cations $(H^+, Ca^{++}, MG^{++}, Na^+, K^+, NH_4^+)$ and the major anions $(SO_4^=, NO_3^-, Cl^-)$ were measured to characterize the main sources of chemical ions in rainwater. Correlating concentrations of ions to pH, calculated coefficients ranged from 0.1485 to 0/4296. Sulfate shows the largest coefficient indicating that sulfate is more closely associated with hydrogen ion than other ions. This may suggest that sulfuric acid contributes more to the acidity of rainwater in Seoul. It appears that the major chemicals measured in rainwater are from the anthropogenic sources of air pollution. Predominant chemicals are acidic at the Guro-, the Sinseol-, the Yangnam-, and the Ssangmun-dong with sulfate being the most predominant. IT also indicates that alkaline substances resulting from soil and dust have a significant effect on pH values of rainwater by neutralizing actions. According to Granat-model analysis, it is estimated that the relative contributions to the rainwater acidity in Seoul are 84% from sulfuric acid, 8% from nitric acid and 8% from hydrochloric acid.

• Journal of Korean Society for Atmospheric Environment
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• v.19 no.E2
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• pp.63-73
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• 2003

The atmospheric pollution distribution in the industrial area of Yosu in Korea is calculated using numerical model and the model is validated by comparing the calculations with observed data. The emission of NO$_{x}$ and SO$_{x}$ was estimated for 6 sources, and the emission amount of HC was estimated for 9 anthropogenic sources. The calculated wind speed, wind direction and temperature agreed well with the observed data at two observatories, and the calculated concentration of NO, NO$_2$, $O_3$ and SO$_2$ were also reasonable for 5 monitoring stations. The validity of the model is evaluated using 3 indexes of the EPA, and the model is found to be valid and accurate.ate.

• Journal of Environmental Health Sciences
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• v.36 no.1
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• pp.61-71
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• 2010

Intensive measurements of airborne respirable $PM_{2.5}$ and inhalable $PM_{2.5}$ were conducted in the downtown area of Iksan city. The $PM_{2.5}$ and $PM_{2.5}$ samples were collected twice a day in the Iksan city of Korea from October 17 to November 1, 2004. The purpose of the study was to determine the inorganic water-soluble components and trace elements of $PM_{2.5}$ and $PM_{2.5}$ in the atmospheric environment and estimate the contribution rate of major chemical components from a mass balance of all measured particulate species. The chemical analysis for PM samples was conducted for water-soluble inorganic ions using ion chromatography and trace elements using PIXE analysis. The mean concentrations of respirable $PM_{2.5}$ and inhalable $PM_{2.5}$ were $51.4{\pm}29.7$ and $79.5{\pm}39.6\;{\mu}g/m^3$, respectively, and the ratio was 0.62. The ion species of $NO_3$, $SO_4^2$, and $NH_4^+$ were abundant in both $PM_{2.5}$ and $PM_{2.5}$. These components predominated in respirable $PM_{2.5}$ fraction, while $Na^+$, $Mg^{2+}$, $Ca^{2+}$ mostly existed in coarse particle mode. Elemental components of S, Cl, K, and Si were abundant in both $PM_{2.5}$ and $PM_{2.5}$. These elements, except for Si, were considered to be emitted from anthropogenic sources, while Si, Al, Fe, Ca existed mainly in coarse particle mode and were considered to be emitted from crustal materials. The averaged mass balance analysis showed that ammonium nitrate, ammonium sulfate, crustal component, and other trace elements were composed of 18.4%, 13.2%, 4.8%, 3.5% for PM2.5 and 17.0%, 11.6%, 13.7%, 4.4% for $PM_{2.5}$, respectively.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2004.04a
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• pp.499-502
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• 2004

Groundwater chemistry in a coastal region having complex contaminant sources was investigated. Water analysis data for 197 groundwater samples collected from the uniformly distributed sixty-six wells were used. Chemical analysis rand results indicate that groundwaters show wide concentration ranges in major inorganic ions, reflecting complex hydrochemical processes of pollutants. Due to the complexity of groundwater chemistry, Results illustrate that thirty five percent of the wells do not fit for drinking based on nitrate and chloride concentration in the study area. the samples were classified into four groups based on Cl and NO$_3$ concentrations and the processes controlling water chemistry were evaluated based on the reaction stoichiometry. The results explained the importance of mineral weathering, anthropogenic activities (nitrification and oxidation of organic matters), and Cl-salt inputs (seawater, deicer, NaCl, etc.) on groundwater chemistry. It was revealed that mineral dissolution is the major process controlling the water chemistry of the low Cl and NO$_3$ group (Group 1). Groundwaters high in NO$_3$ (Groups 2 and 4) are acidic in nature, and their chemistry is largely influenced by nitrification, oxidation of organic matters and mineral dissolution. In the case of chloride rich waters (Group 3), groundwater chemistry is highly influenced by mineral weathering and seawater intrusion associated with cation-exchange reactions.

• Journal of Korean Society for Atmospheric Environment
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• v.16 no.E2
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• pp.85-96
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• 2000

The concentrations of Pb, Mn, Al and Na were measured from a total of 26 snow samples collected from a 1.5-m deep snow pit in Livingston Island, South Shetland Islands, at the northern tip of the Antarctic Peninsula. Ore sampling location is great concern, because of its proximity to the southern extremity of south America, a candidate for the source regions of pollutant aerosols entering Antarctica. The mean concentrations of Pb and Mn were found to be 4.97 pg g(sup)-1 and 20.6 pgg(sup)-1, respectively. These concentrations levels are similar to those reported for recent snow at other Antarctic sites with pronounced spring maxima for both metals. Contributions form natural sources are estimated to be minor (∼16%) for Pb. For Mn, on the other hand, contribution from rock and soil dusts is found to be very important. Excess Pb over Pb from natural sources is likely to be anthropogenic, especially from South Americal. Our results show that yearly Pb fallout flux is much greater in Antarctic coastal areas than at other Antarctic locations far from the coast , indicating that the transport and deposition patterns of pollutant aerosols are not simple is Antarctica. It is also suggested that the recycling of anthropogenic Pb in seawater to the atmosphere could significantly contribute to the Pb fallout flux in the Antarctic coastal regions.

• Journal of Environmental Science International
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• v.4 no.1
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• pp.63-70
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• 1995

Continuous measurements of ground-level ozone (O3) were made in five minutes intervals in the rural area of Korea from July 1993 to June 1994. This site is located in Chongwon, near latitude 36.4$^{\circ}$N, longitude 127.6$^{\circ}$E. The results show that the one-year mean value was 17 ppb, and monthly mean ranged from 6 to 47 ppb. A pronounced maximum in summer and a minimum in winter were found, and these were related to anthropogenic emission and photochemical reaction. Diurnal variations of ozone minimum at 07:00 - 08:00. During the period when ozone concentration was very high (> 80 ppb), the stable winds were from N and UW; on the other hand, when ozone concentration was very low, air movement in the large scale was from the North Pacific Ocean. This suggests that in the rural area the long range transport of anthropogenic pollutants from distant sources can contribute to the larger contribution than the generation of ozone from local sources in the rural area.

• Journal of the Korean Society of Marine Environment & Safety
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• v.24 no.7
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• pp.907-915
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• 2018

With the increase of metal usage in various industries, metal pollution and ecological toxicity in the environmental system have become a significant concern. A geo-statistical index has been widely used to determine contamination level with normalization through a background value. In this study, geo-statistical indexes such as an enrichment factor, accumulation index, and potential ecological risk index were used to assess metal pollution in soil at locations associated with shipbuilding manufacturing industries. Metal contamination, especially of Cu and Pb, was observed in some samples located closer to manufacturing sites. Enrichment factor and accumulation (IGEO) values were indicative of concerning levels of soil contamination in specific samples, and the soil contamination could be induced by anthropogenic sources. In further study, after more detailed sampling for soil and potential pollution sources, high interpretation techniques such as Pb isotope analysis and X-ray analysis will be needed to investigate source identification.

• Economic and Environmental Geology
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• v.56 no.1
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• pp.75-85
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• 2023

The potential sources and spatial distribution of heavy metals and polycyclic aromatic hydrocarbons (PAHs) were investigated in the leaf plants of Al-Zubair city. A total of 14 samples of conocarpus lancifolius plant leaf were collected and analyzed for their heavy metals and PAHs content using inductively coupled plasma mass spectrometry (ICP-MS) and a 7890 Agilent capillary gas chromatograph (GC) respectively. Bioaccumulation factor calculation revealed the highest pollution of heavy metals , due to the activity of a petrochemical in the area. The diagnostic ratio of Ant/(Phe+Ant), BaA/BaA+Chr), In/(In+BghiP), Flu/Pyr, FlA/FlA+Pyr), FlA/FlA+Pyr), ∑LMW/∑HMW are commonly used for determining the origin and source of PAHs in various environmental media. The diagnostic ratio indicated the anthropogenic origin. PAHs with five-to-six membered rings were dominant in the plant leaf, which likely results from anthropogenic activities. The leaves of C. lancifolius have a preponderance of high molecular weight PAHs compared to low molecular weight PAHs, indicating a combustion origin (car exhaust, petroleum emissions, and fossil fuel). C. lancifolius leaves are a reliable indication of atmospheric PAHs absorption. The background level of heavy metals in the city (or the near environment) is in the order of Fe > Cu > Ni > Cr. On the other hand, the bioaccumulation in plant leaves showed greater tendencies as follows: Co>Cd>Zn=As>Cu>Mn>Ni>Pb>Cr>Fe. Cobalt showed high bioaccumulation, indicating strong uptake of Co by plant leaves. These findings point to human activity and car emissions as the primary sources of roadside vegetation pollution in Al-Zubair city.