서울시 산성비의 원인물질에 관한 연구

Investigation on Source Strength to Acid Rain in the Seoul Area

  • 발행 : 1986.09.01

초록

Rain samples were collected at 10 sites in the Seoul area during the period of August through November, 1985. THe concentrations of the major cations $(H^+, Ca^{++}, MG^{++}, Na^+, K^+, NH_4^+)$ and the major anions $(SO_4^=, NO_3^-, Cl^-)$ were measured to characterize the main sources of chemical ions in rainwater. Correlating concentrations of ions to pH, calculated coefficients ranged from 0.1485 to 0/4296. Sulfate shows the largest coefficient indicating that sulfate is more closely associated with hydrogen ion than other ions. This may suggest that sulfuric acid contributes more to the acidity of rainwater in Seoul. It appears that the major chemicals measured in rainwater are from the anthropogenic sources of air pollution. Predominant chemicals are acidic at the Guro-, the Sinseol-, the Yangnam-, and the Ssangmun-dong with sulfate being the most predominant. IT also indicates that alkaline substances resulting from soil and dust have a significant effect on pH values of rainwater by neutralizing actions. According to Granat-model analysis, it is estimated that the relative contributions to the rainwater acidity in Seoul are 84% from sulfuric acid, 8% from nitric acid and 8% from hydrochloric acid.

키워드

참고문헌

  1. EPA-600/9-79036, Acid Rain U.S. EPA
  2. Water, Air and Soil pollution v.16 Acidic Precipitation; Considerations for an air quality standard Evans,L.S.(et al.)
  3. US GPO 1982-0-377-082/1146 WMO;EPA;NOAA
  4. Environ. Sci. Technol. v.16 no.2 Acid Precipitation in Historical Perspective Cowling,E.B.
  5. Water Resources Research v.10 no.6 Acid Precipitation in the Northeastern United States Cogbill,C.V.;Likens,G.E.
  6. Environ. Sci. Technol. v.16 no.3 Effects of Acid Precipitation Glass,N.R.(et al.)
  7. JAPCA v.34 no.10 Acid Rain Effects Research-A Status Report Lefohn,A.S.;Brocksen,R.W.
  8. Atmospheric Environment v.15 no.6 Relationships between Sulfate and Nitrate Ion Concentrations and Rainfall pH for Use in Modeling Applications McNaughton,D.F.
  9. WMO-No. 299, Operations Manual for Sampling and Analysis Techniques for Chemical Constituents in Air and Precipitation WMO
  10. Tellus v.30 The Collection of Precipitation for Chemical Analysis Galloway,J.N.;Likens,G.E.
  11. Water, Air and Soil Pollution v.6 Calibration of Collection Procedures for the Determination of Precipitation Chemistry Galloway,J.N.;Likens,G.E.
  12. Air Chemistry and Radioactivity Junge,C.E.
  13. Standard Methods(15th ed.) APHA
  14. Methods of Sampling and Analysis of Precipitation Water Adapted on the Survey Toshiichi Okita
  15. 衛生試驗法 注解 日本樂學會(編)
  16. Analytical Methods for Atomic Absorption Spectrophotometry Perkin-Elmer
  17. Environ. Sci. Technol. v.12 no.9 Vermeulen,A.J.
  18. Atmospheric Environment v.15 no.7 Recent Acidification of Precipitation in North America Likens,G.E.;Butler,T.J.
  19. Atmospheric Environment v.17 no.1 Acidity of Rain in Europe Kallend,A.S.(et al.)
  20. Tellus v.31 no.5 Error Analysis Applied to Indirect Methods for Precipitation Acidity Liljestrand,H.M.;Morgan,J.J.
  21. Ph.D. Thesis, California Inst. of Tech. Atmospheric Transport of Acidity in Southern Calfornia by Wet and Dry Mechanism Liljestrand,H.M.
  22. Aquatic Chemistry Stumm,W.;Morgan,J.J.
  23. Journal of Meteorology v.15 no.5 The Concentration of Chloride, Sodium, Potassium, Calcium, and Sulfate in Rain Water over the United States Junge,C.E.;Werby,R.T.
  24. Water, Air and Soil Pollution v.6 Chemical Composition of Acid Precipitation in Central Texas Cooper,H.B.H.(et al.)
  25. Atmospheric Environment v.7 no.8 The Relationship of Sulfur Emissions to Sulfate in Precipitation-Ⅱ Gas Phase Process Oppenheimer,M.
  26. 大氣汚染學會誌 v.18 no.1 前橋市に 降つたPH2.86 の雨について 關口恭一(外)
  27. EPA910/9-83-105, Measurements of the Chemical Composition of Western Washington Rainwater, 1982-1983 U.S.EPA
  28. Atmospheric Environment v.16 no.7 Chemistry of Atmospheric Precipitation in the North-Central United States Munger,J.W.
  29. Tellus v.24 On the Relation between pH and the Chemical Composition in Atmospheric Precipitation Granat,L.
  30. Atmospheric Environment v.17 no.8 Observations on the Chemical Composition of Rain Using Short Sampling Times During A Single Event Seymour,M.D.;Stout,T.
  31. Atmospheric Environment v.16 no.9 Review of Questions Regarding Rain Acidity Data Hansen,D.A.;Hidy,G.M.
  32. EPA-600/3-83-004, Acidity, Nutrients, and Minerals in Atmospheric Precipitation over Florida: Deposition Patterns, Mechanisms, and Ecological Effects U.S. EPA
  33. Atmospheric Environment v.17 no.4 Source Contributions to Acid Precipitation in Texas Feeley,J.A.;Liljestrand,H.M.
  34. Environ. Sci. & Technol. v.12 no.12 Chemical Composition of Acid Precipitation in Pasadena Calif. Liljestrand,H.M.;Morgan,J.J.
  35. 이화여대 논문집 서울에 있어서 산성강우에 관한 연구 박봉규
  36. 석사논문 사상공단 주변지역의 산성강우현상에 관한 연구 허철구
  37. 자연보존 김준호
  38. 서울시의 산성물질강하현상에 관한 연구 손동헌(외)
  39. 강수물 성분변화에 의한 대기오염도의 간접측정 및 평가에 관한 연구 최덕일(외)
  40. 중앙일보
  41. Handbook of Chemistry and Physics(46th ed.) Weast,R.C.(et al.)
  42. 동아일보