• Title/Summary/Keyword: Anthropogenic pollution

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Dimethylsulfide (DMS) in Seawater and the Overlying Atmosphere of the Masan Bay (해수 및 대기 중 DMS의 분석 : 마산만을 중심으로)

  • 김기현;오재룡;강성현;이수형;이강웅
    • Journal of Korean Society for Atmospheric Environment
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    • v.12 no.4
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    • pp.495-504
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    • 1996
  • The concentrations of dimethylsulfide (DMS) were determined from both seawater and the overlying atmosphere from a station located in the Masan Bay area during a ten-day field campaign period of January 1996. The resulting data were also used to derive saturation ratios (SR) as well as sea-to-air fluxes of DMS. The concentrations and fluxes of DMS for both reservoirs varied extensively over two to three orders of magnitude: DMS in air and seawater were measured at 9 to 4,300 pptv (mean: 600 $\pm$ 1, 170, N=18) and at 0.24 to 10 nM (4.0 $\pm$ 3.4, N=13), respectively, while its fluxes were found from 0.02 to 23 mol $m^{-2} day^{-1} (3.1 \pm 6.8, N=11)$. A comparative analysis between our data and previously reported ones indicate that its atmospheric concentrations are abnormalously high, but its seawater counterparts are slightly lower than expected. In light of high pollution levels of organic-rich materials in and the associated high biological productivity of the study area, the sea-to-air-fluxes derived are notably low relative to those values typically reported from the coastal areas. These complicated features of DMS distributions/fluxes in the study site indicate that the near-by port- based anthropogenic activities from various industrial plants strongly interfere with natural processes leading to the production and release of DMS. It was however striking to find out relatively strong signals of diel cycle in its saturation ratios, concentration gradients between seawater and atmosphere, and the associated fluxes. Although it is yet difficult to provide meaningful explanations for the observed phenomena, the existence of clear diel cycle in some DMS-related parameters suggests that the natural processes may nonetheless exert important controls on the regional cycling of atmospheric sulfur species, of particular DMS.

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Impact of Northeast Asian Biomass Burning Activities on Regional Atmospheric Environment (동북아시아 지역의 바이오매스 연소 활동이 지역 대기 환경에 미치는 영향)

  • Lee, Kwon-Ho
    • Journal of the Korean Association of Geographic Information Studies
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    • v.15 no.1
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    • pp.184-196
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    • 2012
  • Biomass burning activities(BBA) are caused by both natural and anthropogenic origins. Due to emissions of greenhouse gases and atmospheric aerosols during the burning process, BBA has been known to be one of important sources of atmospheric pollution and the climate change. However, the monitoring of BBA and its effects on atmospheric environment are not simple. This study evaluates the trends of BBA and its impact on atmospheric environment by using earth observing satellite. The results show that the most BBA were found over ever green, green vegetation types, and irrigated land cover types in study region. The trends of BBA and aerosol optical thickness which represents relative aerosol loading in the atmosphere, show similar pattern. Aerosol increases caused by BBA highlight the effectiveness of these mechanisms and would affect the regional atmospheric environment and climate change.

Distribution of TOC and metals in the surface sediments of the Lake Shihwa (시화호 표층 퇴적물의 유기탄소와 금속의 분포)

  • Kim, Kyung-Tae;Kim, Eun-Soo;Cho, Sung-Rok;Park, Jun-Kun;Kim, Jong-Kun;Lee, Jeong-Moo
    • Proceedings of KOSOMES biannual meeting
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    • 2008.05a
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    • pp.159-164
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    • 2008
  • In order to understand the spatio-temporal distribution of geochemical parametrs in surface sediments of the artificial Lake Shihwa in the vicinity of Kyunggi Hay in Korea, surface sediments were sampled at 14 sites in July 2007 and analyzed by CHN analyzer and ICP/MS. Metal concentrations in the sediments tended to be decreasing from the head to the mouth of the Lake Shihwa because of extreme pollutant discharge from various kinds of anthropogenic sources such as the Banweol and Shihwa Industrial Complex and cities. With the deposition of fine-grained sediments, high metal concentrations were also observed in the central part of lake. Although various programs(improvement of wastewater collection and treatment system, sea-lake water exchange etc) to improve the environmental conditions around the Lake Shihwa after dike construction were carried out, it was not dear to reach a good environmental quality. Therefore, further environmental programs should be conducted continuously for environmental improvement.

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137Cs, 40K and 210Po in abiotic components of aquatic ecosystems two rivers in the Can Gio biosphere reserve, Vietnam

  • Ilya G. Sidorov ;Nataliya N. Tereshchenko ;Andrey A. Korotkov;Olga D. Chuzhikova-Proskurnina;Nguyen Trong Hiep ;Aleksandr V. Trapeznikov
    • Nuclear Engineering and Technology
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    • v.54 no.11
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    • pp.4265-4271
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    • 2022
  • Determination of 137Cs, 40K and 210Po in water, bottom sediments and suspended matter of river systems of the Can Gio Biosphere Reserve, Vietnam was carried out. The average activity concentration of 137Cs in waters of Ca Gau and Long Tau was 0.89 ± 0.14 and 1.08 ± 0.15 Bq m-3 and was comparable to the levels of this radioisotope in waters of the East Sea. The activity concentration of 137Cs in bottom sediments was 2.23 ± 0.81 and 3.63 ± 1.24 Bq kg-1. The activity concentration of 137Cs in water and bottom sediments could be characterized as low. So, the water areas of the Ca Gau and Long Tau rivers could be attributed to areas with insignificant pollution by technogenic radionuclides. The 210Po activity concentration in bottom sediments of the Ca Gau and Long Tau rivers ranged from 9.2 ± 1.2 to 25.5 ± 2.1 Bq kg-1, which is typical for river bottom sediments. Such values indicate the absence of anthropogenic enhancement of the entry of this radionuclide into the Can Gio river systems. The 40K activity concentration varied within 467 ± 42-651 ± 39 Bq kg-1 and represented typical values of potassium content in the bottom sediments of coastal water bodies, subject to a significant influence of the lithogenic component of suspended matter.

DNA barcoding of fish diversity from Batanghari River, Jambi, Indonesia

  • Huria Marnis;Khairul Syahputra;Jadmiko Darmawan;Dwi Febrianti;Evi Tahapari;Sekar Larashati;Bambang Iswanto;Erma Primanita Hayuningtyas Primanita;Mochamad Syaifudin;Arsad Tirta Subangkit
    • Fisheries and Aquatic Sciences
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    • v.27 no.2
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    • pp.87-99
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    • 2024
  • Global climate change, followed by an increase in anthropogenic activities in aquatic ecosystems, and species invasions, has resulted in a decline in aquatic organism biodiversity. The Batanghari River, Sumatra's longest river, is polluted by mercury-containing illegal gold mining waste (PETI), industrial pollution, and domestic waste. Several studies have provided evidence suggesting a decline in fish biodiversity within the Batanghari River. However, a comprehensive evaluation of the present status of biodiversity in this river is currently lacking. The species under investigation were identified through various molecular-based identification methods, as well as morphological identification, which involved the use of neighbor-joining (NJ) trees. All collected specimens were initially identified using morphological techniques and subsequently confirmed with molecular barcoding analysis. Morphological and DNA barcoding identification categorized all specimens (1,692) into 36 species, 30 genera and 16 families, representing five orders. A total of 36 DNA barcodes were generated from 30 genera using a 650-bp-long fragment of the mitochondrial cytochrome oxidase subunit I (COI) gene. Based on the Kimura two-parameter model (K2P), The minimum and maximum genetic divergences based on K2P distance were 0.003 and 0.331, respectively, and the average genetic divergence within genera, families, and orders was 0.05, 0.12, 0.16 respectively. In addition, the average interspecific distance was approximately 2.17 times higher than the mean intraspecific distance. Our results showed that the COI barcode enabled accurate fish species identification in the Batanghari River. Furthermore, the present work will establish a comprehensive DNA barcode library for freshwater fishes along Batanghari River and be significantly useful in future efforts to monitor, conserve, and manage fisheries in Indonesia.

Investigation on Characteristics of High PM2.5 Pollution Occurred during October 2015 in Gwangju (광주 지역에서 2015년 10월에 발생한 PM2.5 고농도 사례 특성 분석)

  • Yu, Geun-Hye;Park, Seung-Shik;Jung, Sun A;Jo, Mi Ra;Lim, Yong Jae;Shin, Hye Jung;Lee, Sang Bo;Ghim, Young Sung
    • Journal of Korean Society for Atmospheric Environment
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    • v.34 no.4
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    • pp.567-587
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    • 2018
  • A severe haze event occurred in October 2015 in Gwangju, Korea. In this study, the driving chemical species and the formation mechanisms of $PM_{2.5}$ pollution were investigated to better understand the haze event. Hourly concentrations of $PM_{2.5}$, organic and elemental carbon, water-soluble ions, and elemental constituents were measured at the air quality intensive monitoring station in Gwangju. The haze event occurred was attributed to a significant contribution (72.3%) of secondary inorganic species concentration to the $PM_{2.5}$, along with the contribution of organic aerosols that were strongly attributed to traffic emissions over the study site. MODIS images, weather charts, and air mass backward trajectories supported the significant impact of long-range transportation (LTP) of aerosol particles from northeastern China on haze formation over Gwangju in October 2015. The driving factor for the haze formation was stagnant atmospheric flows around the Korean peninsula, and high relative humidity (RH) promoted the haze formation at the site. Under the high RH conditions, $SO{_4}^{2-}$ and $NO_3{^-}$ were mainly produced through the heterogenous aqueous-phase reactions of $SO_2$ and $NO_2$, respectively. Moreover, hourly $O_3$ concentration during the study period was highly elevated, with hourly peaks ranging from 79 to 95ppb, suggesting that photochemical reaction was a possible formation process of secondary aerosols. Over the $PM_{2.5}$ pollution, behavior and formation of secondary ionic species varied with the difference in the impact of LTP. Prior to October 19 when the influence of LTP was low, increasing rate in $NO_3{^-}$ was greater than that in $NO_2$, but both $SO_2$ and $SO{_4}^{2-}$ had similar increasing rates. While, after October 20 when the impact of haze by LTP was significant, $SO{_4}^{2-}$ and $NO_3{^-}$ concentrations increased significantly more than their gaseous precursors, but with greater increasing rate of $NO_3{^-}$. These results suggest the enhanced secondary transformation of $SO_2$ and $NO_2$ during the haze event. Overall, the result from the study suggests that control of anthropogenic combustion sources including vehicle emissions is needed to reduce the high levels of nitrogen oxide and $NO_3{^-}$ and the high $PM_{2.5}$ pollution occurred over fall season in Gwangju.

Distribution and Sources of Pb in Southern East/Japan Sea Sediments using Pb isotopes (동해 남부 해역 퇴적물에서 Pb동위원소를 이용한 Pb의 기원 추적 연구)

  • Choi Man Sik;Cheong Chang-Sik;Han Jeong Hee;Park Kye-Hun
    • Economic and Environmental Geology
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    • v.39 no.1 s.176
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    • pp.63-74
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    • 2006
  • In order to identify the Pb pollution and its sources in continental shelf and slope areas, Pb concentration and Pb isotope ratios ($^{207}Pb/^{206}Pb\;and\;^{208}Pb/^{206}Pb$) were determined far 6 box corer sediments collected from the southern East/japan Sea. Pb concentration, and $^{207}Pb/^{206}Pb\;and\;^{208}Pb/^{206}Pb$ ratios were constant at around $25\pm5 ppm$ and 0.842 and 2.092 from 1700 to 1930 year, respectively and increased steadily up to $40\pm5 ppm$ and 0.867 and 2.123 at the beginning of 1990s', respectively. The increase of concentration and isotope ratios in the labile fraction (leached by 2M HC1+0.5M $HNO_3$) explains their increase in bulk sediments, while Pb concentration and isotope ratios in the residual fraction were nearly constant during 300yrs. Temporal variation of Pb isotope ratios was explained by simple two end-members mixing of geo-genic and anthropogenic sources because isotope ratios and the inverse of Pb concentration showed the good linear relationships. Using Pb isotope ratios, we can constrain two Pb sources in the study area. The one is atmospheric particulates, compared with mean values of isotope ratios in atmospheric particulates collected at Jeju and Oki ;stands, based on the history of Pb emmission in Korea and China, and judged by oceanographic processes capable of homogenizing many sources. The other is local sources related to iron mills, refineries of Pb ore and of petroleum located at the coast of the study area. Isotope ratios of anthropogenic Pb can be estimated using two end-members mixing equation and were $0.879\pm0.005\;and\;2.144\pm0.008$ before 1950s' while they increased up to $0.900\pm0.008\;and\;2.162\pm0.011$ after 1980s', respectively.

Hydrogeochemical Characteristics of Groundwater in Kwangiu City (광주광역시 지하수의 수리지화학적 특성 연구)

  • 이인호;조병욱;이병대;성익환;임용수
    • Journal of Soil and Groundwater Environment
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    • v.7 no.3
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    • pp.115-132
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    • 2002
  • To distinguish the anthropogenic inputs from the chemical weathering with water-rock interaction on the chemical compositons of groundwater in Kwangju city, four different water groups were established based on the landuse type, lithology and topology. The sample from greenbelt area belongs to Group Ⅰ, whereas those from green buffer zone, urban area and industrial area belong to Group II, Group Ⅲ and Group Ⅳ, respectively. The geology of this city mainly consists of biotite granite and granitic gneiss. The concentration of main cations is subject to the behavior of feldspars, micas and carbonate minerals. Cl$\^$-/ and NO$_3$$\^$-/ are supplied by anthropogenic inputs such as domestic sewage whose concentration of these anions is highest in the Group Ⅲ samples. With the Piper diagram, the groundwaters of Group Ⅲ are mainly plotted in CaSO$_4$-CaCl$_2$ type, whereas those of other groups are plotted in Ca(HCO$_3$)$_2$ type, The calculation for the activities of ions and saturation indices of some minerals shows that most of the minerals are undersaturated and plotted in the area of equlibrium with kaolinite. Three factors were extracted from the factor analysis for chemical data. Factor 1 controlled by HCO$_3$$\^$-/, Ca$\^$2-/, SO$_4$$\^$2-/, Mg$\^$2+/ and Na$\^$+/, explains the dissolution of carbonate minerals. mica and plagioclase. Factor 2, controlled by Cl$\^$-/ and NO$_3$$\^$-/, explains the influence of artificial pollution. Factor 3, controlled by Mn, Fe and Zn is subject to the industrial waste water, but the evidence is not clear. Factor 1 is dominant in the Group I and II, indicating that those samples are subjected to natural chemical weathering, The higher scores of factor 2 in the Group Ⅲ samples indicate the potential artificial pollution.

Composition and pollution characteristics of TSP, PM2.5 atmospheric aerosols at Gosan site, Jeju Island (제주도 고산지역 TSP, PM2.5 대기에어로졸의 조성 및 오염 특성)

  • Lee, Soon-Bong;Kang, Chang-Hee;Jung, Duk-Sang;Ko, Hee-Jung;Kim, Haeng-Bum;Oh, Yong-Soo;Kang, Hae-Lim
    • Analytical Science and Technology
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    • v.23 no.4
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    • pp.371-382
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    • 2010
  • TSP and PM2.5 atmospheric aerosols have been collected at Gosan site of Jeju Island, and their compositions were analyzed to understand the pollution characteristics. The composition ratios of nss (non-sea salt)-$SO_4^{2-}$ and $NH_4^+$ were higher in Gosan site than those in other Korean background and urban sites. However the composition ratio of $NO_3^-$ was conversely lower in Gosan site. From the study of aerosol components according to particle sizes, the anthropogenic nss-$SO_4^{2-}$, $NO_3^-$ and $NH_4^+$ components were mostly existed in the fine particles. But the nss-$Ca^{2+}$, $Na^+$, $Cl^-$ and $Mg^{2+}$ originated from soil and marine sources were distributed relatively in the coarse particles. In the seasonal comparison, the concentrations of nss-$Ca^{2+}$, Al, Fe, Ca and $NO_3^-$ increased in spring season, and nss-$SO_4^{2-}$ showed higher concentration in summer and spring seasons. Based on the factor analysis, the atmospheric aerosols in Gosan site have been found to be influenced largely by anthropogenic sources, and next by marine and soil sources. The backward trajectory analyses showed that the concentrations of nss-$SO_4^{2-}$, $NO_3^-$, Pb and nss-$Ca^{2+}$ increased when the air mass moved from Chinese continent to Jeju area. On the other hand, their concentrations decreased when the air mass moved in from the North Pacific Ocean.

Retrieval of the Variation of Optical Characteristics of Asian Dust Plume according to their Vertical Distributions using Multi-wavelength Raman LIDAR System (다파장 라만 라이다 관측을 통한 황사의 이동 고도 분포에 따른 광학적 특성 변화 규명)

  • Shin, Sung-Kyun;Park, Young-San;Choi, Byoung-Choel;Lee, Kwonho;Shin, Dongho;Kim, Young J.;Noh, Youngmin
    • Korean Journal of Remote Sensing
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    • v.30 no.5
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    • pp.597-605
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    • 2014
  • The continuous observations for atmospheric aerosols were conducted during 3 years (2009 to 2011) by using Gwangju Institute of Science and Technology (GIST) multi-wavelength Raman lidar at Gwangju, Korea ($35.10^{\circ}N$, $126.53^{\circ}E$). The aerosol depolarization ratios calculated from lidar data were used to identify the Asian dust layer. The optical properties of Asian dust layer were different according to its vertical distribution. In order to investigate the difference between the optical properties of each individual dust layers, the transport pathway and the transport altitude of Asian dust were analyzed by Hybrid Single Particle Lagrangian Integrated Trajectory (HYSPLIT) model. We consider that the variation of optical properties were influenced not only their transport pathway but also their transport height when it passed over anthropogenic pollution source regions in China. The lower particle depolarization ratio values of $0.12{\pm}0.01$, higher lidar ratio of $67{\pm}9sr$ and $68{\pm}9sr$ at 355 nm and 532 nm, respectively, and higher ${\AA}ngstr\ddot{o}m$ exponent of $1.05{\pm}0.57$ which are considered as the optical properties of pollution were found. In contrast with this, the higher particle depolarization ratio values of $0.21{\pm}0.09$, lower lidar ratio of $48{\pm}5sr$ and $46{\pm}4sr$ at 355 nm and 532 nm, respectively, and lower ${\AA}ngstr\ddot{o}m$ exponent of $0.57{\pm}0.24$ which are considered as the optical properties of dust were found. We found that the degree of mixing of anthropogenic pollutant aerosols in mixed Asian dust govern the variation of optical properties of Asian dust and it depends on their altitude when it passed over the polluted regions over China.