• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2004.09a
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• pp.334-337
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• 2004

Groundwater chemistry in Namwon area, Korea, was investigated to understand the contribution of geochemical processes on groundwater chemistry. For this study, a total of 279 groundwater samples were collected from 93 wells distributed over the study area. Higher concentrations of major ions are generally encountered in the shallow alluvial wells, suggesting that these chemicals are originated from the surface contamination sources. Mass balance analysis based on reaction stoichiometry reveals that the water chemistry is regulated by three major chemical processes: weathering of silicate/ carbonate minerals, input of C1/SO$_4$ salts, and nitrate generating processes. The results show that mineral weathering is the most dominating factor regulating the groundwater chemistry. However, the groundwaters with the higher salt concentration indicate the larger mineral weathering effect, suggesting that some part of the mineral weathering effect is also associated with the anthropogenic activities such as limes applied to the cultivated lands, carbonates (CaCO$_3$) in the cement materials.

• Analytical Science and Technology
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• v.15 no.4
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• pp.321-328
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• 2002

From May 1999 to July 2000, concentration of 17 metals (Al, Ba, Ca, Cd, Cr, Cu, Fe, K, Mg, Mn, Mo, Na, Ni, Pb, Sr, V, Zn), 4 ions (${NH_4}^+$, $Cl^-$, ${NO_3}^-$, ${SO_4}^{2-}$) and pH in rainwater were investigated. The volume-weighted mean concentrations (VWM) of ${NO_3}^-$ and ${SO_4}^{2-}$ were 16.0 and $17.0{\mu}mol\;L^{-1}$. The average pH was 4.53, which ranged from 3.83 to 6.06. The characteristic variations of these species were investigated in terms of the source of these species by principal component analysis (PCA) and interelement correlation coefficients. The elements were classified into three categories: anthropogenic source (Cd, Cu, Fe, Ni, Pb, V, Zn, ${NH_4}^+$, ${NO_3}^-$, ${SO_4}^{2-}$ and $H^+$), soil and crust dust (Al, Ba, Ca, Fe, Mn) and sea salts (Mg, Na, $Cl^-$). In addition, we compared the concentrations in rainwater, which were taken on the same day in three sites (Higashi-Hiroshima, an urban-facing area and a mountain-facing area of Mt. Gokurakuji) in order to examine the regional effect against the concentrations in them. At the urban-facing area of Mt. Gokurakuji, the concentrations of chemical compositions were higher than other areas.

• Journal of Korean Society for Atmospheric Environment
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• v.8 no.2
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• pp.121-127
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• 1992

This study was carried out to investigate the features of air pollutants in rainwater and trace their transported trajectories from other countries. Chemical analysis data of rainwater and suspended particulates collected at Seoul, Kanghwa, and Taean for three years were used to evaluate the effects of long-range transport of air pollutants. Scavenging theory on washout and rainout effect during a rainy period was applied to estimate whether pollutants in the precipitation were long-range transported or not. On the other hand, precipitation weighted surface wind were evaluated to analyze the effect from local sources on atmospheric concentrations. As a result, contribution of air pollutants caused by anthropogenic sources in the precipitation which was identified to be long range transported was confirmed significantly high and trajectory of these pollutants was to be equivalent to 850mb isobar. Although concentration of acidifying components increased in the precipitation, neutralization by alkaline soil components such as $Ca^{2+}$ and $Mg^{2+}$ was conspicuous especially during Yellow-sand period.

• Proceedings of the Korean Society of Crop Science Conference
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• 2017.06a
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• pp.314-314
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• 2017

Anthropogenic activities have increased the concentrations of greenhouse gases, such as $CO_2$, $CH_4$, $N_2O$, HFCs, $SF_6$, and PFCs, in the atmosphere. Among others, $N_2O$ is well known as an important greenhouse gas accounting for 7.9% of the total greenhouse effect and the effect of its emission is 310 times greater than that of $CO_2$. Agricultural $N_2O$ emissions are now thought to contribute to about 60% of the global anthropogenic $N_2O$ emission, which have been increased primarily due to fertilizer N consumption and manure management. Therefore, the reduction of $N_2O$ emissions in agriculture is being required. This study was conducted to determine the variation of $N_2O$ emissions by no-tillage (NT) and conventional tillage (CT) practices in the cultivation of soybean from the sandy loam soils under the different kinds of fertilizer treatments June through September 2016 in Cheong-ju, Republic of Korea. An experimental plot, located in the temperate climate zone, was composed of two main plots that were NT and CT, and were divided into four plots, respectively, in accordance with types of fertilizers (chemical fertilizer, liquid pig manure, hairy vetch and non-fertilizer). Among all the treatments, $N_2O$ emission was the highest in August and the lowest in June. When $N_2O$ emissions were evaluated during the growing season (June to September) in all fertilizer treatments, NT with hairy vetch treatment emitted the highest $N_2O$ emission in August, whereas, $N_2O$ emissions was the lowest in NT with non-fertilizer treatment in June, respectively (p = 0.05). Based on the cumulative amount of $N_2O$ emissions during the growing season of soybean, NT had lower $N_2O$ emission than CT by 0.01 - 0.02 kg $N_2O$, although NT had higher $N_2O$ emission than CT by 0.03 kg $N_2O$ in only the chemical fertilizer treatments. As a result, it seems that the applications of liquid pig manure and hairy vetch rather than chemical fertilizer could decrease the $N_2O$ emission in NT, compared to CT.

• Atmosphere
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• v.17 no.2
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• pp.147-157
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• 2007

A weekend effect has been investigated in diurnal temperature range (DTR) for Seoul in Korea using 50-year (1955 ~ 2005) surface measurements of maximum and minimum temperatures, and particle mass concentrations (PM10). The minimum temperature increases by 0.42K per decade, 2 times faster than the maximum temperature during 1955 to 2005, for rapid urbanization has occurred in Seoul. The weekend effect, which is defined as the DTR for Sunday minus the average DTR for Tuseday through Thursday, can be as large as +0.08 K for the recent 20-year period relative to 0.01K for 1955 to 1975. Especially the wintertime DTR tends to have a remarkable positive weekend effect (+0.17K), that is, larger DTR on Sunday compared to weekdays, which seems to be associated with increased maximum temperature and thus an increase in DTR. This result could be explained by relative differences in PM10 concentration between Sunday and weekdays (Tuesday through Thursday), such that PM10 concentration on Sundays appears to be systematically lower about 12% than on weekdays. The annually average weekend DTR increases by 0.2K with $10{\mu}gm^{-3}$ decrease in PM10 concentration in comparison with weekdays. The results could be possible evidence of an anthropogenic link to DTR, one of climate important indicators, since no meteorological phenomenon is supposed to occur over a 7 day cycle.

• Atmosphere
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• v.21 no.3
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• pp.229-241
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• 2011

The continuous urbanizations by a rapid economic growth and a steady increase in population are expected to have a possible impact on meteorology in the downwind region. Long-term (1972~2007) trends of precipitation have been examined in the mid-Korean peninsula for the westerly condition only, along with the sensitivity simulations for a golden day (11 February 2009). During the long-term period, both precipitation amount (PA) and frequency (PF) in the downwind region (Chuncheon, Wonju, Hongcheon) of urban area significantly increased for the westerly and light precipitation ($PA{\leq}1mm\;d^{-1}$) cases, whereas PA and PF in the mountainous region (Daegwallyeong) decreased. The enhancement ratio of PA and PF for the downwind region vs. urban region remarkably increased, which implies a possible urbanization effect on downwind precipitation. In addition, the WRF simulation applied for one golden day demonstrates enhanced updraft and its associated convergence in the downwind area (about 60 km), leading to an increase in the cloud mixing ratio. The sensitivity experiments with the change in surface roughness demonstrates a slight increase in cloud water mixing ratio but a negligible effect on precipitation in the upwind region, whereas those with the change in heat source represents the distinctive convergence and its associated updraft in the downwind region but a decrease in liquid water, which may be attributable to the evaporation of cloud droplet by atmospheric heating induced by an increase in an anthropogenic heat. In spite of limitations in the observation-based analysis and one-day simulation, the current result could provide an evidence of the effect of urbanization on the light precipitation in the downwind region.

• Proceedings of the Korea Water Resources Association Conference
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• 2023.05a
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• pp.177-177
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• 2023

The impacts of dams on transboundary flow are complex and challenging to project and manage, given the potential moderating influence of a broad range of anthropogenic and natural factors. This study presents a global meta-analysis of 168 studies that examines the effect magnitude of dams on downstream seasonal, annual flow, and hydrological extremes risk on 39 hotspot transboundary river basins. The study also evaluates the impact of 13 factors, such as climate, basin characteristics, dams' design and types, level of transboundary cooperation, and socioeconomic indicators, on the heterogeneity of outcomes. The findings reveal that moderators significantly influence the impact of dams on downstream flow, leading to considerable heterogeneity in outcomes. Transboundary cooperation emerges as the key factor that determines the severity of dams' effect on both dry and wet season's flows at a significance level of 0.01 to 0.05, respectively. Specifically, the presence of water-supply and irrigation dams has a significant (0.01) moderating effect on dry-season flow across basins with high transboundary cooperation. In contrast, for wet-season flow, the basin's vulnerability to climate extremes is associated with a large negative effect size. The various moderators have varying degrees of influence on the heterogeneity of outcomes, with the aridity index, population density, GDP, and risk level of hydro-political tension being the most significant factors for dry-season flow, and the risk level of hydro-political tension and basin vulnerability to climate extremes being the most significant for wet-season flow. The results suggest that transboundary cooperation is crucial for managing the impacts of dams on downstream flow, and that various other factors, such as climate, basin characteristics, and socioeconomic indicators, have significant moderating effects on the outcomes. Thus, context-specific approaches are necessary when predicting and managing the impacts of dams on transboundary flow.

• Atmosphere
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• v.20 no.4
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• pp.495-503
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• 2010

Satellite data have an intrinsic problem due to a number of various physical parameters, which can have a similar effect on measured radiance. Most evaluations of satellite performance have relied on comparisons with limited spatial and temporal resolution of ground-based measurements such as soundings and in-situ measurements. In order to overcome this problem, a new way of satellite data evaluation is suggested with statistical tools such as empirical orthogonal function(EOF), and singular value decomposition(SVD). The EOF analyses with OMI and OMI HCHO over northeast Asia show that the spatial pattern show high correlation with population density. This suggests that human activity is a major source of as well as HCHO over this region. However, this analysis is contradictory to the previous finding with GOME HCHO that biogenic activity is the main driving mechanism(Fu et al., 2007). To verify the source of HCHO over this region, we performed the EOF analyses with vegetation and HCHO distribution. The results showed no coherence in the spatial and temporal pattern between two factors. Rather, the additional SVD analysis between $NO_2$ and HCHO shows consistency in spatial and temporal coherence. This outcome suggests that the anthropogenic emission is the main source of HCHO over the region. We speculate that the previous study appears to be due to low temporal and spatial resolution of GOME measurements or uncertainty in model input data.

• Atmosphere
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• v.20 no.1
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• pp.13-26
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• 2010

The Urban Canopy Model (UCM) implemented in WRF model is applied to improve urban meteorological forecast for fine-scale (about 1-km horizontal grid spacing) simulations over the city of Seoul. The results of the surface air temperature and wind speed predicted by WRF-UCM model is compared with those of the standard WRF model. The 2-m air temperature and wind speed of the standard WRF are found to be lower than observation, while the nocturnal urban canopy temperature from the WRF-UCM is superior to the surface air temperature from the standard WRF. Although urban canopy temperature (TC) is found to be lower at industrial sites, TC in high-intensity residential areas compares better with surface observation than 2-m temperature. 10-m wind speed is overestimated in urban area, while urban canopy wind (UC) is weaker than observation by the drag effect of the building. The coupled WRF-UCM represents the increase of urban heat from urban effects such as anthropogenic heat and buildings, etc. The study indicates that the WRF-UCM contributes for the improvement of urban weather forecast such nocturnal heat island, especially when an accurate urban information dataset is provided.

• Korean Journal of Fisheries and Aquatic Sciences
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• v.46 no.6
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• pp.862-867
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• 2013

Since the industrial revolution, seawater has increased in temperature and acidity due to the increase in anthropogenic carbon dioxide in the atmosphere. To understand the effect of elevated $CO_2$ on the early life stages of fish, we reared fertilized eggs of black sea bream Acanthopagrus schlegelii under three $CO_2$ concentrations (400, 850 and 1550 ppm) for 3 weeks. The standard length and wet weight of black sea bream larvae declined with enhanced $CO_2$ concentration in the rearing water (P<0.05). However, chemical analysis using ICP-OES on internal tissues of black sea bream larvae indicated that the whole-body calcium concentration increased with $CO_2$ concentration in the rearing water. These conflicting results suggest that future experiments should examine the acid-base balance to investigate the formation of bone and otolith during larval growth.