• Transactions of the Korean Society of Automotive Engineers
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• v.13 no.4
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• pp.113-120
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• 2005

In order to investigate the characteristics of penatration and the effect of surface treatment in A15052-H34, Al5082-Hl31 and titanium alloy laminates which were treated by anodizing and PVD(Physical Vapor Desposition) method, ballistic tests were conducted. Thickness of surface membrane in A15052-H34, Al5082-Hl31, were $25{\mu}m$ and that of titanium $0.9{\mu}m$ respectively. Surface hardness test was conducted using micro Vicker's hardness tester. Resistance to penetration is determined by the protection ballistic limit(V50), a statistical velocity with $50\%$ probability for complete penetration. Fracture behaviors and ballistic tolerance, described by penetration modes, are observed from the results of V50 test and Projectile Through Plate(PTP) test at velocities greater than protection ballistic limit, respectively. Present experimental results derived from this research help to optimize laminate impact behavior by varing the laminate thickness and surface treated materials.

• Journal of the Korean institute of surface engineering
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• v.57 no.1
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• pp.8-13
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• 2024

Anodizing of Al6061 alloy was conducted in two different electrolytes of 20% sulfuric acid and 8% sulfuric acid + 3 % oxalic acid solutions at a constant current or decreasing current density conditions, and its dielectric breakdown voltage was measured. The surface morphology of anodic oxide films was observed by TEM and thermal treatment was carried out at 400 ℃ for 2 h to evaluate the resistance of the anodic oxide films to crack initiation. The anodic oxide film formed in 8% sulfuric acid + 3 % oxalic acid solution showed higher dielectric breakdown voltage and better resistance to crack initiation at 400 ℃ than that formed in 20% sulfuric acid solution. The dielectric breakdown voltage increased 6 ~12% by applying decreasing current density comparing with a constant current density.

• Journal of the Korean institute of surface engineering
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• v.35 no.6
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• pp.401-407
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• 2002

Most of organic compounds discharged from industrial wastewater are treated by chemical oxidation, adsorption and biodegradable process. This process has been demanded a new advanced environmental wastewater treatment process. From this point of view, an electrochemical oxidation process using electrocatalysts has been developed for the destruction of organic compounds. Through this study, a ruthenium oxide/iridium oxide supported on titanium expanded metal was fabricated by thermal decomposition method and its performance was excellent during this experiment.

• Corrosion Science and Technology
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• v.21 no.4
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• pp.282-289
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• 2022

Aluminum 1000 series alloy, a pure aluminum with excellent workability and weldability, is mainly used in the ship field. Aluminum alloy can combine with oxygen in the atmosphere and form a natural oxide film with high corrosion resistance. However, its corrosion resistance and durability are decreased when it is exposed to a harsh environment for a long period of time. For solving this problem, a porous oxide film can be formed on the surface using an anodizing treatment method, a typical surface technique among various methods. In this study, aluminum 1050 alloy was anodized for 2 minutes, 6 minutes, and 10 minutes. The structure and shape of the oxide film were then analyzed to determine the corrosion resistance according to the thickness of the oxide film that changed depending on working condition using 15 wt% NaCl. After it was immersed in NaCl solution for 1, 5, and 10 days, corrosion damage was observed. Results confirmed that the thickness of the oxide film increased as the anodization time became longer. The depth of surface damage due to corrosion became deeper when the film was immersed in the 15 wt% NaCl solution for a longer period of time.

• Proceedings of the Korean Institute of Surface Engineering Conference
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• 2009.10a
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• pp.181-181
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• 2009

탄소섬유의 우수한 기계적, 화학적, 전기적 특성을 이용한 산업전반에 대한 연구가 활발히 수행되어 지고 있다. 본 연구에서는 탄소섬유를 supercapacitor의 전극과 복합체에 활용하기 위해서 탄소섬유상에 탄소나노튜브를 증착시키는 실험을 수행하였다. 균일하고 높은 증착 밀도의 탄소나노튜브를 증착시키기 위해서 본 연구에서는 기존의 CF 표면처리 방법- anodizing, plasma treatment, heat treatment등과 달리 간단한 wet-process방법을 이용해 CF 표면처리 및 catalyst증착공정을 동시에 수행하여 고밀도의 CNT를 증착하였다.

• Journal of the Korean Society for Heat Treatment
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• v.25 no.5
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• pp.227-232
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• 2012

Magnesium alloy have good physical properties such as good castability, good vibration absorption, high strength/weight ratios. Despite the desirable properties, the poor resistance of Mg alloy impedes their use in many various applications. Therefore, magnesium alloy require surface treatment to improve hardness, corrosion and wear resistance. Plasma Electrolytic Oxidation (PEO) is one the surface treatment methods to form oxide layer on Mg alloy in alkali electrolyte. In comparison with Anodizing, there is environmental process having higher hardness and faster deposition rate. In this study, the characteristics of oxide film were examined after coating the AZ31 Mg alloy through the PEO process. We changed concentration of sodium aluminate into $K_2ZrF_6$, KF base electrolyte. The morphologies of the coating layer were characterized by using scanning electron microscopy (SEM). Corrosion resistance also investigated by potentiodynamic polarization analysis. As a result, propertiy of oxide layer were changed by concentration of sodium aluminate. Increasing with concentration of sodium aluminate in electrolyte, the oxidation layer was denser and the pore size was smaller on the surface.

• Journal of the Korean institute of surface engineering
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• v.52 no.5
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• pp.275-281
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• 2019

Anodization is widely used to enhance the properties of aluminum, such as hardness, electric resistance, abrasion resistance, corrosion resistance etc. But these properties can be enhanced with additional process. According to the partial crystallization of oxide layer with post heat treatment, enhanced hardness can be expected with partial crystallization. In this study, post heat treatments were applied to the anodized aluminum alloys of Al6061 to achieve the partial crystallization, and crystallizations were evaluated with the reduced breakdown voltages. Interestingly, remarkable enhanced hardness (21~29%), abrasion resistance (26~62%), and reduced breakdown voltage (24~44%) were observed for the sulfuric acid anodized samples when we annealed the anodized samples with 1hour post heat treatment at $360^{\circ}C$. For the Al5052 alloys, a lot of cracks were observed when we applied the post heat treatment.

• Corrosion Science and Technology
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• v.20 no.2
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• pp.45-51
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• 2021

In this work, we describe the effect of pulse anodizing duty ratio on the corrosion resistance of anodic films in magnesium AZ31B. The process involves the application of square pulse potential for a constant period with a duty ratio varying from 40, 60 and 80%. In several samples, a sealing treatment for 30 minutes was conducted after anodization in order to seal the pores available in the anodic layer. After anodizing, the surface morphology of the anodic layer was examined using a scanning electron microscope (SEM Hitachi SU3500). The corrosion characteristics of the sample were evaluated through an open circuit potential (OCP) and potentiodynamic polarization test using potentiogalvanostat. SEM observation shows that the increase of anodization duty ratio (α) results in a more uniform anodic layer, with fewer pores and cracks. The increase of duty ratio (α) decreases the OCP value from approximately -1.475 to about -1.6 Volt, and significantly improves the corrosion resistance of the anodic coating by 68%. The combination of anodization and sealing treatment produces an anodic coating with a very low corrosion rate of 4.4 mpy.

• International Journal of Precision Engineering and Manufacturing
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• v.4 no.4
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• pp.45-50
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• 2003

In order to investigate the effect of surface treatment (Anodizing) and rolling on AI 5083-H131 alloy, under hyper velocity impact, a ballistic testing was conducted. Ballistic resistance of these materials was measured by a protection ballistic limit ($V_{50}$)' a statistical velocity with 50% probability of penetration. Perforation behavior and ballistic tolerance, described by penetration modes, were respectfully observed, by $V_{50}$ test and Projectile Through Plates (PTP) test at velocities greater than $V_{50}$. PTP tests were conducted with 0$^{\circ}$ obliquity at room temperature using 5.56mm ball projectiles. $V_{50}$ tests with 0$^{\circ}$ obliquity were also done with projectiles that were able to achieve near or complete penetration during PTP tests. Resistance to penetration, and penetration modes of Al 5052-H34 alloy were compared to those of Al 5083-H 131 alloy.

• The Journal of Korean Academy of Prosthodontics
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• v.43 no.5
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• pp.684-693
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• 2005

Statement of problem: Ti-6Al-7Nb alloy is used instead of Ti-6Al-4V alloy that was known to have toxicity. Purpose: This study was performed to investigate the effect of electrolyte concentration on the surface characteristics of anodized and hydrothermally-treated Ti-6Al-7Nb alloy Materials and methods: Discs of Ti-6Al-7Nb alloy of 20 mm in diameter and 2 mm in thickness were polished sequentially from #300 to 1,000 SiC paper ultrasonically washed with acetone and distilled water for 5 min, and dried in an oven at $50^{\circ}C$ for 24 hours. Anodizing was performed at current density $30mA/cm^2$ up to 300 V in electrolyte solutions containing $\beta-glycerophosphate$ disodium salt hydrate $(\beta-GP)$ and calcium acetate (CA). Hydrothermal treatment was conducted by high pressure steam at $300^{\circ}C$ for 2 hours using a autoclave. All samples were soaked in the Hanks' solution with pH 7.4 at $36.5^{\circ}C$ for 30 days. Results and conclusion: The results obtained were summarized as follows: 1. After hydrothermal treatment, the precipitated HA crystals showed the dense fine needle shape. However, with increasing the concentration of electrolyte they showed the shape of thick and short rod. 2. When the dense fine needle shape crystals was appeared after hydrothermal treatment, the precipitation of HA crystals in Hanks' solution was highly accelerated. 3. The crystal structures of $TiO_2$ in anodic oxide film were composed of strong anatase peak and weak rutile peak as analyzed with thin-film X-ray diffractometery. 4. The Ca/P ratio of the precipitated HA layer was equivalent to that of HA crystal in Hanks' solution.