• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.34 no.4
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• pp.7-15
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• 2002

It is of critical importance to understand the characteristics of papermaking additives and their reaction mechanisms to fully utilize the benefits they provide. Among the papermaking additives, retention aids play critical roles in improving productivity, product quality and process economy. Diverse research efforts to understand the reaction mechanisms between cationic polymers and anionic microparticles have been made since microparticle retention systems were introduced into the market. And it is most commonly accepted that flocs formed by the addition of cationic polymers are dispersed by shear force and the broken flocs are reflocculated instantly with the addition of microparticles. There are still many unanswered questions, however, on the reaction phenomena between cationic polymers and anionic microparticles. In this study, several cationic polymers including waxy maize starch, com starch and guar gum were used to investigate their retention efficiency when they were used along with anionic colloidal silica.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.42 no.3
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• pp.50-57
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• 2010

A mill trial was performed in a kraft paper mill in order to evaluate the possibility of utilizing dual polymer dry strength aids system consisting of cationic PVAm and anionic PAM. It was found that the cationic PVAm - anionic PAM dry strength additives can improve paper strength without significantly disturbing the stability of the kraft papermaking process when virgin UKP was used as a furnish. Tensile strength (25.3% in machine direction, 48.4% in cross machine direction), elongation of paper (31.6%, 15.6%) and tensile energy absorption (48%, 54%) were improved. Air permeability of the kraft paper was improved as well (22%). Tear strength was decreased with PVAm dry strength aids system, but it can be compensated with decreasing refining degree. In addition, the mill trial results indicate that highly air permeable kraft sack paper can be produced by the addition of PVAm dry strength agents at the stock with reduced freeness.

• Journal of the Korean Ceramic Society
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• v.32 no.8
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• pp.901-908
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• 1995

In aqueous slurry processing of silicon nitride, the interaction of dispersant and binder used as polymeric processing additives on the silicon nitride particle surface was studied to identify the effect of these processing polymeric additives on the ceramic powder processing. The adsoprtion isotherm study of anionic organic molecule as dispersant and nonionic organic molecules as binder of silicon nitricde was studied to investigate the effect of these processing organic additives on the physicochemical properties of silicon nitride particles. As anionic molecule adsorbed onto silicon nitrice surface, the IEP of silicon nitride shifted toward acidic pH and changed the stability of silicon nitride particle. However, the adsorption of binder as nonionic organic molecule onto silicon nitride surface did not changed the IEP but caused the decrease of electrostatic potentials of silicon nitride. These distinctive adsorption behaviors of organic additives on silicon nitride particles can be closely correlated to the stability of silicon nitride particles suspended in aqueous media.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.33 no.4
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• pp.1-6
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• 2001

Today's paper industry tries to use greater amount of high yield pulp and recycled fiber and to close mill water system, which results in higher fines content and buildup of organic and inorganic contaminants in white water system. Researches are being focused to develop chemical additives that provide good retention and drainage in a closed papermaking system. A microparticle retention system consisted of cationic guar gum and anionic colloidal silica so has been developed to meet the requirements for improving machine speed and product quality. The objective of this investigation was to determine the effects of the degree of cationic guar gums, charge density and structure of anionic colloidal silica sols, and the degree of system closure on the performances of this microparticle retention system. Cationic guar gums and anionic colloidal silica sols with higher charge densities showed better retention performance. Particularly, wider maximum in retention was obtained when structure colloidal silica was used suggesting as mechanism of microparticle bridging is functioning in this system.

• Applied Chemistry for Engineering
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• v.18 no.1
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• pp.64-70
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• 2007

Preparation and characterization of carbon-slurry fuel with high dispersion have been carried out. Carbon-slurry fuel was obtained by mixing Jet A-1 liquid fuel with appropriate carbon powders and additives. Dispersion of carbon in Jet A-1 was affected by various factors such as mixing temperature, characteristics of carbon powders, and type and amount of additives. Among these factors, the stability of the slurry fuel was most dependent on the type of additive. A variety of additives such as anionic, cationic, and nonionic additives was tested for the dispersion of carbon in Jet A-1. It was found that anionic additives based on sodium salts showed the highest dispersion of carbon-slurry fuels. The degree of dispersion could be monitored by measuring the luminosity.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.12 no.3
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• pp.251-257
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• 2000

District heating and cooling systems offer highly efficient energy utilization and maintenance by centralizing heat management. More pumping power, however, is required because the water has to travel long distance from heat source to the users. In the present study, a trace of drag reduction additives is added to the District Cooling system to achieve a significant drag reduction and save pumping power. Water-soluble polymers, surfactants, and environment-friendly degradable polymers are used as effective drag reducing additives. Time dependent percent drag reductions are compared for various additive solutions at 100 wppm concentration for different water velocity. Without as an anionic surfactant, copolymer was most effective in percent drag reduction. It is found that there exists an optimal condition when copolymer is mixed with SDS. An environment-friendly degradable polymer, xanthan gum, is found to be a significant drag reduction additive. Ice slurry systems, can give less pressure drops compared with chilled water system for certain condtions. Drag reduction additives were also effective for the ice slurry system.

• Bulletin of the Korean Chemical Society
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• v.32 no.4
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• pp.1361-1364
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• 2011

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.33 no.2
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• pp.1-7
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• 2001

Use of high yield pulp and recycled fiber as raw materials and water system closure result in higher fines content and buildup of organic and inorganic contaminants in white water. These are detrimental for the effectiveness of chemical additives including retention aids. Thus it is imperative to employ a retention systems that maintains its efficiency in closed papermaking system for reducing fresh water consumption. The performance of four different microparticle retention systems including cationic polyacrylamide (C-PAM)/bentonite, highly charged cationic starch (HCS)/silica, C-PAM/micropolymer, cationic guar gum (CGG)/silica was evaluated and compared at three different levels of papermaking system closure. Buildup of detrimental substances in a closed white water system increased cationic demand and finally reduced the performance of retention systems. Cationic starch and guar gums maintained their effectiveness in retention in closed white water systems contaminated with anionic trashes because of their structural rigidity and hydrogen bonding ability. Particularly, cationic guar gums, due its stiffness of molecular structure, appeared perform better than catinonic starch.

• Journal of the Korean Ceramic Society
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• v.39 no.11
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• pp.1090-1096
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• 2002

Six different composition of water-swellable bentonite rheology modifiers(WSB-1~WSB-6) were prepared by the compounding of peptizers and anionic surfactants as an additives with Bentonite(BEN) of montmorillonite group. Average particle size, particle morphology and water-swellability of WSB and the viscosity with additives were measured, respectively. And the rheological behavior of WSB were investigated using the rheometer. The viscosity of WSB-1 increased with decreasing both pH and average particle size of BEN, WSB-2 treated $Na_2CO_3$ as a peptizer showed the maximum viscosity. These results can be interpretated cause for rearrangment as the edge-to-face structure of BEN particles containing WSB. Also, WSB-4∼WSB-6 containing both peptizer and anionic surfactant was sol phase that their viscosity was not nearly with the shear rate, however, WSB-3 containing Tetrasodium Pyrophosphate(TSPP) as an anionic surfactant showed the thixotropy by the viscosity difference of 1000 times with the shear rate. From this result, the anions of TSPP can be explained to arrange in edge of BEN particles containing WSB-3.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.45 no.5
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• pp.23-29
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• 2013

Various properties of cotton handsheet were measured to solve the problem of deformation while storing guar gum(natural polymer) and to improve strength and retention by synthetic polymers(A-PAM, C-PAM, CMC). The results of this study were summarized as follow. The cotton handsheet with 0.2% of A-PAM showed the best tensile index and folding endurance. Retention of fines and fillers in pulp slurry with 0.2% and 0.3% of A-PAM were more excellent than that with guar gum.