• Title/Summary/Keyword: Anionic

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Studies on the Application of Starch for paper surface sizing(III) - The influence of surface sizing treatment with starch on the quality of uncoated printing paper - (종이 표면 사이즈 프레스용 전분의 적용에 관한 연구 -표면 사이즈용 전분이 백상지 품질에 미치는 영향 -)

  • 윤지영;이용규
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.34 no.2
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    • pp.1-12
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    • 2002
  • Starch dissolved in paper-mill wastes, either as a result of poor retention on the paper web or recycling of surface-treated broke, was a major pollutant Laboratory tests were performed by using different kinds of starch as a surface treatment. It was concluded that the use of cationic starch can positively affect the level of starch dissolved in liquid effluents. When cationically modified starches were used for surface sizing, the starch was tightly bound to the paper fibers, it was not removed during the repulping of broke. The result of mill trial in fine paper manufacture for the application of low-viscosity cationic starches used in size press reduced COD load in the effluents and increased One Pass Retention. It had been found that when cationic starch used as a surface sizing agent, more starch was retained on or near the surface of the sheet than with conventional oxidized starches. Thus surface strengths and quality were improved. In addition it is possible to maintain the desired level of starch penetration into the fiber net and improve porosity, opacity and brightness. In contrast, in most cases, dusting problems are notably eliminated. Cationic surface sized starch improved black and color ink-jet print quality in terms of feathering and optical density of the print image. These improved properties were believed to be due to a combination of fiber bonding and surface orientation more uniform starch concentration on the paper surface was resulted. Moreover cationic charges in the paper surface lend themselves excellently to fix ink jet ink anionic in nature.

A Study on the Analysis of Isothiazolinone Components by High Performance Liquid Chromatography (고성능액체크로마토그래피에 의한 Isothiazolinone Components의 분석에 관한 연구)

  • 김종규;이덕희
    • Journal of Environmental Health Sciences
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    • v.18 no.2
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    • pp.102-105
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    • 1992
  • Introduction : Isothiazolinone product is one of new preservatives used in cooling tower, paper mill, and general industrial waters.l) It is also effective in controlling bacteria and fungi in the manufacture and storage of dispersed pigments, such as kaolin clays, titanium dioxide, calcium carbonate and others\ulcorner Its broad-spectrum activity, excellent physical and chemical compatibility with anionic, nonionic and cationic surfactants and most organic and inorganic compounds and low toxicity at recommended use levels provide formulators with an effective, economical, and environmentally acceptable alternative to other commercial biocides. It dose not contain or generate formaldehyde and is easy to formulate (1.5% solution is supplied as an aqueous solution), so that it gains advantage over the other preservatives. The active ingredients of the isothiazolinone product are unchlorinated compound (2-methyl-4-isothiazolin-3-one) and chlorinated one (5-chloro-2-methyl-4-isothiazolin-3-one). Methods preferred for the analysis of preservatives are chromatographic methods, especially high performance liquid chromatograph (HPLC). Although several methods were satisfactory in respect to separation, no offical method has been published for the isothiazolinone components. This study was performed to search for an alternative method in order to show flexible operating conditions of HPLC and to reduce assay time.

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Effect of Dietary Cation-Anion Difference during Prepartum and Postpartum Periods on Performance, Blood and Urine Minerals Status of Holstein Dairy Cow

  • Razzaghi, A.;Aliarabi, H.;Tabatabaei, M.M.;Saki, A.A.;Valizadeh, R.;Zamani, P.
    • Asian-Australasian Journal of Animal Sciences
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    • v.25 no.4
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    • pp.486-495
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    • 2012
  • Twenty four periparturient cows were used to determine the effects of DCAD on acid-base balance, plasma and urine mineral concentrations, health status, and subsequent lactation performance. Each group of 12 cows received either a diet containing -100 DCAD or +100 DCAD for 21 d prepartum. Both anionic and cationic groups were divided into two groups, one received a +200 DCAD and the other +400 DCAD diet for 60 d postpartum. Prepartum reduction of DCAD decreased DMI, urinary and blood pH, urinary concentrations of Na or K and increased plasma and urinary Ca, Mg, Cl and S. Also cows fed -100 DCAD diet consumed the most dry matter in the first 60 d after calving. Postpartum +400 DCAD increased milk fat and total solid percentages, urinary and blood pH and urinary Na and K concentrations, but urinary Ca, P, Cl and S contents decreased. Greater DMI, FCM yields were observed in cows fed a diet of +400 DCAD than +200 DCAD. No case of milk fever occurred for any diets but feeding with a negative DCAD diet reduced placenta expulsion time. In conclusion, feeding negative DCAD in late gestation period and high DCAD in early lactation improves performance and productivity of dairy cows.

Effects of Sodium Sulfate and Surfactants on Papain Treatment of Wool Fabrics

  • Kim, In Young
    • Fashion & Textile Research Journal
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    • v.16 no.2
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    • pp.333-338
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    • 2014
  • This study identifies the effects of sodium sulfate and surfactants in the papain treatment of wool fabrics using L-cysteine and EDTA as activators. The research method involves the use of 2% L-cysteine and 7% EDTA as activators at optimal conditions, papain treatment of wool fabrics with the joint use of sodium sulfates and surfactants, and measurements of the weight loss rate, tensile strength, and whiteness. Results showed that for both 2% L-cysteine and 7% EDTA, the maximum papain activity appeared at 0.5% sodium sulfate concentration. In both cases, the papain activity was enhanced at sodium sulfate concentrations lower than 0.5%. In contrast, the papain activity declined at sodium sulfate concentrations higher than 0.5%. The joint use of EDTA with 0.5% sodium sulfate was proven to be very effective in improving the papain activity. The joint use of 2% L-cysteine with 0.5% sodium sulfate appeared slightly effective in improving the activity but resulted in excessive decrease in the tensile strength and whiteness, compared to improvement in the activity. The joint use of surfactants, in the case of L-cysteine, interrupted the papain activity and decreased the tensile strength regardless of the surfactant type and concentration. In the case of EDTA, however, the joint use with 0.1-5% non-ionic surfactants, 0.1-0.5% anionic surfactants, and 0.1% cationic surfactant appeared to improve the papain activity. The maximum papain activity was observed when 0.1% of surfactant was used, regardless of the surfactant type. The nonionic surfactant was the most effective in improving the papain activity.

Preparation and Characterization of Silicone and Fluorine-Oil-Based Ferrofluids

  • Kim, Jong-Hee;Park, Keun-Bae;Kim, Ki-Soo
    • Composites Research
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    • v.30 no.1
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    • pp.41-45
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    • 2017
  • Magnetite nanoparticles were synthesized by adding an ammonium hydroxide to a mixed solution of iron (II) and (III) chlorides. A silicon surfactant of ${\alpha},{\omega}$-(3-aminopropyl)polydimethylsiloxane was adsorbed on the particles as dispersant and a polydimethylsiloxane polymer was used to prepare ferrofluids of silicone oil base. Fluorinated surfactants of anionic ammoniated perfluoroalkyl sulfonamide and nonionic fluoroaliphatic polymeric esters were applied to the particles and a perfluoropolyether was used to prepare ferrofluids of fluorine oil base. The experimental conditions were used for preparing the ferrofluids with concentrations of 200, 300 and 400 mg/mL, and density, magnetization and viscosity of the products were characterized. The density values increased in proportion to the concentration, indicating 1.11-1.27 g/mL for silicone-oil-based fluids and 1.95-2.10 g/mL for fluorine-oil-based fluids in the range of 200-400 mg/mL. The saturation magnetization of the silicone-oil-based and fluorine-oil-based fluids indicated 14.7, 24.4, and 30.7 mT and 15.8, 23.3, and 33.7 mT for 200, 300, and 400 mg/mL, respectively, depending on the content of magnetic particles in the fluid. The viscosity of the silicone-oil-based ferrofluids was highly stable compared to that of the fluorine-oil-based with increasing temperatures. The ferrofluids are usually applied to seals and speakers with the silicone base and to seals with the fluorine base.

Effects of Dietary Supplementation of Barodon, an Anionic Alkali Mineral Complex, on Growth Performance, Feed Utilization, Innate Immunity, Goblet Cell and Digestibility in Olive Flounder (Paralichthys olivaceus)

  • Shin, Chang-Hoon;Cha, Ji-Hoon;Rahimnejad, Samad;Jeong, Joon-Bum;Yoo, Byung-Woo;Lee, Bo-Kyeun;Ahn, Hyung-Jin;Choi, Soo-Il;Choi, Yun-Jeong;Park, Yong-Ho;Kim, Jeong-Dae;Lee, Kyeong-Jun
    • Asian-Australasian Journal of Animal Sciences
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    • v.27 no.3
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    • pp.383-390
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    • 2014
  • A 15-wk feeding trial was conducted to examine the supplemental effects of Barodon on growth performance, gastrointestinal histology, feed digestibility and innate immunity in olive founder. A basal commercial diet was used as a control and two other diets were prepared by spraying 0.1% or 0.2% of Barodon. Triplicate groups of fish (BW, 145 g) were fed one of the test diets to apparent satiation twice daily. At the end of the feeding trial, fish growth performance was not significantly affected by dietary treatments; however, feed utilization was significantly improved (linear and quadratic, p<0.05) by Barodon supplementation. Significantly higher (p<0.05) survival rates were obtained in fish fed Barodon containing diets. Hepatosomatic index increased significantly in Barodon treated groups. Also, the use of Barodon resulted in significant increase (linear and quadratic, p<0.05) of intestine length and number of goblet cells. Significantly higher (Quadratic, p<0.05) apparent digestibility coefficient of DM was obtained by supplementation of Barodon. Lysozyme and myeloperoxidase activities increased quadratically and linearly, respectively, in Barodon treated fish. Also, significantly higher (linear and quadratic, p<0.05) superoxide dismutase activity was found in Barodon fed fish. The findings in this study show that inclusion of Barodon in diets for olive flounder improves feed utilization and digestibility, and positively affects digestive tract histology and innate immunity.

Isolation and Characterization of a New ${\gamma}$-Polyglutamic Acid Producer, Bacillus mesentericus MJM1, from Korean Domestic Chungkukjang Bean Paste

  • ZHAO , XIN-QING;PARK, KWAN-HYONG;JIN, YING-YU;LEE, IN HYUNG;YANG, YOUNG-YELL;JOO-WON SUH,
    • Journal of Microbiology and Biotechnology
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    • v.15 no.1
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    • pp.59-65
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    • 2005
  • Poly-${\gamma}$-glutamic acid (PGA) is an unusual anionic polypeptide and has great potential as an environmentally and industrially significant biodegradable material. A new ${\gamma}$-PGA producer, Bacillus mesentericus MJM1, with high production capacity was isolated from Korean domestic Chungkuckjang bean paste. It produced ${\gamma}$-PGA at the level of 10 g/l in suitable media. The viscosities of 5% initially extracted mucin and purified ${\gamma}$-PGA solutions were 660 cps and 600 cps, respectively. The produced ${\gamma}$-PGA polymer consisted of 2,000 glutamic acid residues with even proportion of L and D types with molecular mass of about 200- 300 kDa. Bacillus mesentericus MJM1 displayed ${\gamma}$-glutamyltranspeptidase (${\gamma}$-GTP) activity that is known to play a key role in ${\gamma}$-PGA biosynthesis. The ${\gamma}$-GTP coding region was located on the plasmid of 5.8 kb. The plasmid, named pMMH1, is a rolling-circle replication (RCR) plasmid and additionally contained a replication origin and type I signal peptidase (sipP) coding region.

Isolation of an Acinetobacter junii SY-01 Strain Producing an Extracellular Lipase Enantioselectively Hydrolyzing Itraconazole Precursor, and Some Properties of the Lipase

  • Yoon, Moon-Young;Shin, Pyong-Kyun;Han, Ye-Sun;Lee, So-Ha;Park, Jung-Keug;Cheong, Chan-Seong
    • Journal of Microbiology and Biotechnology
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    • v.14 no.1
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    • pp.97-104
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    • 2004
  • Water-sludge bacteria were screened to find a lipase enantioselectively hydrolyzing itraconazole precursor, which is well known as the starting material of antifungal drug agents. A bacterial strain was isolated and identified as Acinetobacter junii SY-01. After the strain was cultivated, the enzyme was purified 39.4-fold using ultrafiltration and gel filtration through a Sephadex G-100 chromatographic column and the activity yield was 34.9%. The molecular weight of the enzyme was about 40 kDa, as measured by SDS-PAGE, and the optimum pH was 7.0- 9.0 and stable at pH 6.0- 9.0. The optimum temperature was 45- $5^{\circ}C$, and 73% of the enzymes activity remained after incubation at 70% for 1 h. Enzyme activity was enhanced by gall powder, sodium deoxycholate, a cationic detergent Tween 80, and a non-ionic detergent Triton X-100, but was markedly inhibited by metal ions such as $Hg^{2+},Cu^{2+},Ni^{2+}/,Ca^{2+}$, and an anionic-surfactant sodium dodecylsulfate. The $K_{m}$ values for (R)- and (S)-enantiomers of the itraconazole precursor were 0.385 and 21.83 mM, respectively, and the $V_{max} values ($\mu$Mㆍmin^{-1}.)$ were 6.73 and 6.49, respectively. The acetyl group among the different acyl moieties of itraconazole precursor showed the highest enantioselectivity for the hydrolysis by the Acinetobacter junii SY-01 lipase, and the lipase from Acinetobacter junii SY-01 displayed better enantioselectivity than that of commercially available lipases and esterases.

Variation Characteristics of TSP Ionic Compositions by Meteorological Phenomena in Jeju Island (기상현상에 따른 제주지역 TSP의 이온조성 변화 특성)

  • Ko, Hee-Jung;Kim, Won-Hyung;Lee, Seung-Hoon;Bu, Jun-Oh;Kang, Chang-Hee;Hu, Chul-Goo
    • Journal of Korean Society for Atmospheric Environment
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    • v.27 no.6
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    • pp.723-733
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    • 2011
  • The ionic compositions were analyzed from the TSP samples collected at Gosan site in Jeju Island between 2000 and 2008, in order to examine the characteristics of atmospheric aerosols in accordance with the meteorological conditions. For the Asian Dust influence on the ionic compositions, the concentration ratios of $NH_4{^+}$, nss-${SO_4}^{2-}$, $NO_3{^-}$, and $K^+$ were about 1.2~2.3 during Asian Dust over Non-Asian Dust periods, noticeably that of nss-$Ca^{2+}$ was 6.8. Meanwhile the concentrations of nss-${SO_4}^{2-}$, $NO_3{^-}$, and $NH_4{^+}$ have increased as 1.8~4.4 times during the haze event periods, and 1.0~1.6 times during the fog and mist events. The ion balance has resulted that the anionic concentrations are relatively lower than the cationic concentrations, and the discrepancy appears more decidedly as a strong Asian Dust effect. The ammonium ion balance has shown that it exists as a mixture of $NH_4HSO_4$ and $(NH_4)_2SO_4$. The concentration ratios of nss-${SO_4}^{2-}/NO_3{^-}$ for Asian Dust, haze, fog-mist, and non-event periods were respectively 1.8, 5.9, 4.6, and 2.9, which were higher values compared to those in urban areas of China as well as other domestic regions. Especially, the high ratios of sulfur oxides could be presumed by the fact that the longrange transport of air pollutants from Asia continent might affect the atmospheric aerosols of Jeju Island.

Polyarylate-Nylon 6 Block Copolymers : Synthesis and Its Miscibility in Binary Blends with Polyarylate or Nylon 6 Homopolymer (폴리아릴레이트-나일론 6 블록공중합체 : 합성 및 폴리아릴레이트 혹은 나일론 6 단일중합체와의 상용성)

  • Ahn, Tae-Oan;Lee, Suk-Min;Jeong, Han-Mo;Lee, Sang-Won
    • Applied Chemistry for Engineering
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    • v.4 no.2
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    • pp.349-357
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    • 1993
  • Polyarylate(PAR)-nylon 6 block copolymers of various block lengths were prepared by the anionic polymerization of ${\varepsilon}$-caprolactam using the polymeric activator from hydroxy-difuncrtional PAR and toluene diisocyanate. Phase separated morphology of PAR-nylon 6 block copolymer was suggerted from the thermal properties measured by differential scanning calorometry(d.s.c.). Partial miscbility between PAR block and nylon 6 block of the block copolymers was more evident at shorter length of constituent blocks. In binary blends of PAR-nylon 6 block copolymer with PAR or nylon 6 homopolymer, molecular-level mixing of homopolymers with corresponding blocks of block copolymer was supposed from the thermal properties measured by d.s.c..

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