• Title/Summary/Keyword: Anionic

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Study on the Effect of the Mg2+ Ion on the Behavior of Anionic Surfactants in Electrophoresis (전기 이동에서 Mg2+ 이온이 음이온 계면활성제의 거동에 미치는 영향)

  • Jeong, Hyuk
    • Analytical Science and Technology
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    • v.18 no.1
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    • pp.35-42
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    • 2005
  • This study reports the effect of $Mg^{2+}$ ions on the behavior of the anionic surfactant in electrophoresis. Intractions of $Mg^{2+}$ ions with carboxylates and sulfonates resulted large changes in their apparent mobilities. A comprehensive analysis of the electroosmotic and electrophoretic mobilities reveals that major cause for the variation of the apparent mobilities of anions arises from the electroosmotic mobilities.

Treatment of organic dye solutions by electrodialysis

  • Majewska-Nowak, Katarzyna M.
    • Membrane and Water Treatment
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    • v.4 no.3
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    • pp.203-214
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    • 2013
  • Laboratory tests were performed to determine the efficiency of dye solution desalination by electrodialysis. The study involved anionic dye and mineral salt recovery by obtaining two streams from a salt and dye mixture - dye-rich solution and salt solution. A standard anion-exchange and cation-exchange membranes or monovalent selective anion-exchange membranes were used in the ED stack. It was found that the separation efficiency was strongly dependent on the dye molecular weight. The best results for standard ion-exchange membranes were achieved for the desalination of Direct Black solution. Furthermore, the obtained results implied that the application of monovalent selective anion-exchange membranes improved the recovery of dye and salt solutions - the dye concentration in the diluate remained constant irrespective of the molecular weight of anionic dyes, whereas the salt recovery remained very high (99.5%).

The Surface Sizing Effect of Oxidized Starch on the Printability of Newspaper (국산 신문 용지에서 산화전분에 의한 표면 사이징 처리가 인쇄적성에 미치는 영향)

  • 하영백
    • Journal of the Korean Graphic Arts Communication Society
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    • v.15 no.2
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    • pp.25-40
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    • 1997
  • This research was carried out to investigated the effect of base paper and latex binder on printability and obtical properties of coated paper. Especially, it examined the effect of th pH of vase paper surface and functional groups of latices on the interactions between coating color components and on the structure of coated layer. It was found that the behavior of coating color containing amphoeric latex depends on the pH in the boundary region between coating color and base paper. Thus, the coating color formulated with amphoteric latex formed bulky coating layer by inducing stronger interaction between paper surface and coating components than the coating color with anionic latex. The coated paper with amphoteric latex showed better optical properties (i.e.gloss and optical) and printability (i.e. ink receptivity, wet ink receptivity, and ink set off) than the conventional anionic latex in the acidic and alkaline paper. However, dry pick strength of the coated paper was less decreased. This result indicated that amphoteric latex could also be applied practically to the alkaline paper.

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Synthesis of PMMA/Clay Nanocomposite via Emulsion Polymerization (유화중합을 이용한 PMMA/Clay 나노컴포지트의 제조)

  • Kim, Cheol-Woo;Wu, Jong-Pyo
    • Journal of the Korean Applied Science and Technology
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    • v.20 no.3
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    • pp.243-250
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    • 2003
  • Poly(methyl methacrylate)/clay nanocomposite particles with particle size of 275${\sim}$292 nm range were successfully prepared using emulsion polymerization. The content of montmorillonite based on the methyl methacrylate monomer was chosen as 30 wt.%. 2,2-azobis(isobuthylamidine hydrochloride) and n-dodecyltrimethylammonium chloride were used as an initiator and a surfactant in cationic emulsion system. Potassium persulfate and sodium lauryl sulfate were used as an initiator and a surfactant in anionic emulsion system. The evidence of intercalated /exfoliated structure of montmorillonite in the nanocomposite prepared in our experiment was confirmed by wide angle x-ray diffraction patterns of $d_{001}$ plane. Thermal behavior of nanocomposite was traced using DSC and TGA. It was found that the nanocomposite particle prepared by cationic emulsion system showed intercalated structured. We also found that the nanocomposite particle obtained from anionic emulsion system resulted in the fully exfoliated structure.

Living Anionic Polymerization of Isocyanates

  • Lee, Jae-Suk
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.198-198
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    • 2006
  • We have identified sodium benzanilide (Na-BA), sodium diphenyl amine (Na-DPA) and sodium deoxibenzoin (Na-DB) as very efficient initiators for the living anionic polymerization of HIC. It has a slow propagation rate with the additive function of chain end protection, offering in the process a perfect control over MW and MWD. The well-defined amphiphilic coil-rod, coil-rod-coil, and rod-coil-rod block-copolymers of PHIC and P2VP with controlled architecture have been synthesized for the first time with ${\sim}100\;%$ yields. The resulting block copolymers showed lamellar film, donuts, solid and hollow micelles, by simply varying the solvents and the block compositions.

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Kinetic Modeling of Non-Isothermal Anionic Styrene-Butadiene Block Copolymerization And Its Industrial Applications

  • Park, Seung-Young;Yeon, Young-Joo;Lee, Jong-Ku
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.380-380
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    • 2006
  • Styrene-Butadiene diblock or styrene-butadiene-styrene triblock copolymers are industrially important materials for asphalt modification and adhesives. A kinetic modeling study on non-isothermal anionic styrene-butadiene diblock copolymerization system is presented. The model deals with the association/dissociation reaction of initiator and propagating ion pairs in its kinetic scheme. By comparing model calculation results with real plant data, it is possible to obtain useful ideas for more efficient plant operation. For example, the model clearly provides important relation between the reaction temperature profile and the conversion of monomers.

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Recycling of Wastepaper(Ⅷ)-Contamination of Process WAter by System Closure (고지재생연구(제 8보) -제지 공정수 폐쇄화에 따른 오여-)

  • 여성국;류정용;신종호;송봉근;오세균
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.31 no.4
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    • pp.1-7
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    • 1999
  • This study was carried out to simulate the change of various properties of recycled water when zero-discharge system was applied to a KOCC recycling process. contaminants such as chemical oxygen demand, anionic trash, and calcium hardness were gradually increased in the process water as the recycling was repeated . Especially, the increase of anionic trash and COD were closely related to the starch derived from corrugating adhesive in KOCC. Four kinds of water were compared in the preparation of handsheet to evaluate the performance of retention program. Waters used in this work were laboratory tab water, process water from Dong-II mill and the same one treated by UASB process, and closed white water prepared by KRICT. The result revealed that one the major factors fro reducing a retention power was the anioni trash accumulated in the recycled water.

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Comparison with Biodegradation of Anionic Surfactants (계면활성제의 생분해 비교)

  • 최대웅;이광현;김인효
    • Journal of Environmental Health Sciences
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    • v.21 no.4
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    • pp.37-43
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    • 1995
  • The course of biodegradation of anionic surfactants, Linear Alkylbenzene Sulfonates(LAS), Sodium Lauryl Ethoxylate Sulfonate(SLES), and Sodium Lauryl Sulfonates(SLS), which are mainly used to make detergents and shampoo, was investigated. The degree of biodegradation was studied as a function of concentration, volumetric flow rate, and temperature in Naktong River. MethyleneBlue Active Substances(MBAS), Total Dissolved Organic Carbon(TOC), and Chemical Oxygen Demand(COD) were measured to evaluate the degree of biodegradation. The degree of biodegradation of LAS was highly dependent upon the concentration and was increased as the concentration was decreased and that of SLES and SLS was almost constant at the concentration of less than 200 ppm, but was much increased as the volumetric flow rate was increased or the temperature was increased.

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Antioxidative Effect of Crude Anthocyanins in Water-in-Oil Microemulsion System

  • Oh, Ju-Kyoung;Kim, Seok-Joong;Imm, Jee-Young
    • Food Science and Biotechnology
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    • v.15 no.2
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    • pp.283-288
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    • 2006
  • Antioxidative ability of anthocyanins in water-in-oil microemulsion was examined. Microemulsion was prepared by solubilizing crude anthocyanins extracted from grape skin (Cambell early) in organic solvent (hexane) containing anionic surfactant [bis (2-ethylhexyl) sodium sulfosuccinate, AOT] and linolenic acid (10%, w/v). Lipid oxidation significantly decreased with increasing concentration of anthocyanins ($5-20\;{\mu}M$) at micellar phase, and increasing micelle size ($Wo=5-20\;{\mu}M$). At given micelle size (Wo=10), lipid oxidation decreased as number of micelles decreased. These results indicate antioxidative ability of anthocyanins is critically affected by water core and micelle structure formed by surfactant. Interactions between AOT and anthocyanins decreased antioxidative ability of anthocyanins. Antioxidative ability of anthocyanins significantly increased when ${\alpha}$-tocopherol was added into organic phase. This indicates of synergism between the two antioxidants.

Drainage and Shear Stability of Microparticle Retention Systems Based on Cationic Guar Gums and Colloidal Silicas (양이온성 구아검과 콜로이달 실리카를 이용한 마이크로파티클 보류시스템의 탈수 및 전단안정성)

  • Ham, Choong-Hyun;Lee, Hak-Lae
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.40 no.2
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    • pp.1-7
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    • 2008
  • The trend of using more hardwood and recycled fibers, and closing more tightly of the paper mill white water system has resulted in build-up of fines as well as organic and inorganic contaminants in the white water. This changes in papermaking wet end requires developing chemical additive system that provides good fiber retention and drainage in closed white water system. In this study the effect of charge densities and chemical characteristics of microparticle systems consisted of cationic guar gums and anionic colloidal silica sols on drainage and retention have been examined. Results showed that higher charge density of cationic guar gum and anionic colloidal silica sol gave better retention and drainage. Particularly highly structured silica gave greater retention efficiency.