• Title/Summary/Keyword: AnCE

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Synthesis and Oxidation Behavior of Pd-Ir@CeO2 Core-shell Nanoparticles for Hydrogen Gas Sensor

  • Gi-Seung Shin;Dong-Seog Kim;Tuong Van Tran;Geun-Jae Oh;Seok-Yong Hong;Ho-Geun Song;Yeon-Tae Yu
    • Journal of Sensor Science and Technology
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    • v.33 no.5
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    • pp.288-297
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    • 2024
  • Currently, numerous studies are being conducted on metal oxide semiconductor (MOS) gas sensors for hydrogen detection, using Palladium (Pd) and Pd-based alloy nanoparticles (NPs) owing to their hydrogen absorption ability. Furthermore, several studies have reported that Pd-Iridium (Ir) alloys possess high hydrogen absorption capabilities in their bulk state. However, Ir growth is limited to above 2 nm and it does not mix extensively with other metals. Furthermore, as the hydrogen absorption capacity decreases with the reduction in particle size, it is necessary to synthesize nanoparticles of an appropriate size. Therefore, the synthesis of Pd-Ir alloy NPs larger than 10 nm is challenging. In this study, we report the synthesis of Pd-Ir NPs with an average diameter of 19 nm using a hydrothermal technique for the first time and fabricated Pd-Ir alloy NPs through calcination at 500℃ in Ar and air. To confirm alloy formation and oxidation behavior, X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS) were performed. In addition, we synthesized Pd-Ir@CeO2 core-shell nanoparticles (CSNPs) as hydrogen gas-sensing materials. The Pd-Ir core was partially oxidized during heat treatment at 500℃ in air, and Pd-Ir@CeO2 CSNPs were finally changed into Pd-Ir(alloy)/PdO-IrO2@CeO2 CSNPs, which exhibited higher sensitivity and selectivity toward H2 gas compared to totally oxidized PdO-IrO2@CeO2 CSNPs and pure CeO2 NPs. The enhanced gas-sensing performance was attributed to the hydrogen absorption effect of the Pd-Ir(alloy) NPs.

Embedded Operating Systems;Windows CE, Embedded Linux, pSOS, uC/OS

  • Park, Kwang-Hyun;Jeon, Jae-Wook
    • 제어로봇시스템학회:학술대회논문집
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    • 2003.10a
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    • pp.1976-1981
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    • 2003
  • Except a desktop computer and workstation, an embedded system is a system containing microprocessors. While a desktop computer and a workstation are designed for a general purpose, an embedded system is designed for a dedicated purpose. Thus, an embedded system must meet some constraints such as low power consumption, low cost, small size, real-time, or user-defined ones. A simple and low cost embedded system may be able to be designed without using embedded operating systems (OS). However, considered design time and effort, some embedded system had better be designed with using embedded OS. Under given constraints and purpose of some embedded systems, one embedded OS can save more time, cost, and effort in designing those embedded systems than others. This paper compares four embedded OSs, Windows CE, Embedded Linux, pSOS, and uC/OS. It analyzes several issues of embedded OS such as process scheduling, inter-process communication (IPC), memory management, and network support. Also, it describes the product of each embedded OS.

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An Implementation of a Visual Monitoring System Based on Windows CE 5.0 Using AdaBoost Face Detection Algorithm (Windows CE 5.0 기반의 AdaBoost 얼굴검출 알고리즘을 이용한 감시카메라 시스템 설계)

  • Lee, Ki-Hyun;Kwon, Han-Joon;Kim, Yong-Deak
    • Proceedings of the IEEK Conference
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    • 2008.06a
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    • pp.743-744
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    • 2008
  • By using DirectX technology, an improved Visual Monitoring System implemented in this paper. The proposed Visual Monitoring System is developed based on the S3C2440 processor. The Windows CE 5.0 is adopted as an operating system, and Visual Monitoring System transfer image 15 frame per second using UDP/IP and by using AdaBoost Algorithm, detect face region and save face image.

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Preparation and Luminescence Optimization of CeO2:Er/Yb Phosphor Prepared by Spray Pyrolysis (분무열분해법으로 CeO2:Er/Yb 형광체 제조 및 발광특성 최적화)

  • Jung, Kyeong Youl;Park, Jea Hoon;Song, Shin Ae
    • Applied Chemistry for Engineering
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    • v.26 no.3
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    • pp.319-325
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    • 2015
  • Submicron-sized $CeO_2:Er^{3+}/Yb^{3+}$ upconversion phosphor particles were synthesized by spray pyrolysis, and their luminescent properties were characterized by changing the concentration of $Er^{3+}$ and $Yb^{3+}$. $CeO_2:Er^{3+}/Yb^{3+}$ showed an intense green and red emission due to the $^4S_{3/2}$ or $^2H_{11/2}{\rightarrow}^4I_{15/2}$ and $^4F_{9/2}{\rightarrow}^4I_{15/2}$ transition of $Er^{3+}$ ions, respectively. In terms of the emission intensity, the optimal concentrations of Er and Yb were 1.0 % and 2.0%, respectively, and the concentration quenching was found to occur via the dipole-dipole interaction. Upconversion mechanism was discussed by using the dependency of emission intensities on pumping powers and considering the dominant depletion processes of intermediate energy levels for the red and green emission with changing the $Er^{3+}$ concentration. An energy transfer from $Yb^{3+}$ to $Er^{3+}$ in $CeO_2$ host was mainly involved in ground-state absorption (GSA), and non-radiative relaxation from $^4I_{11/2}$ to $^4I_{13/2}$ of $Er^{3+}$ was accelerated by the $Yb^{3+}$ co-doping. As a result, the $Yb^{3+}$ co-doping led to greatly enhance the upconversion intensity with increasing ratios of the red to green emission. Finally, it is revealed that the upconversion emission is achieved by two photon processes in which the linear decay dominates the depletion of intermediate energy levels for green and red emissions for $CeO_2:Er^{3+}/Yb^{3+}$ phosphor.

Explorative Corporate Entrepreneurship : Case Study on Samsung C-Lab (탐색적 사내 기업가정신 : 삼성전자 C-Lab 사례 연구)

  • Hwang, Seonho;Shin, Juneseuk
    • Journal of Korea Technology Innovation Society
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    • v.21 no.3
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    • pp.1101-1126
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    • 2018
  • As incipient organizations progress from formation to become larger entities, the procedures and rules that provided managerial and structural advantages in having established the organizations and promoting the growth impede the innovation and creativity vital to maintain the competitive advantage. Adopting Corporate Entrepreneurship (CE), large corporations have tried to overcome the dilemma and to sustain the innovation and creativity in order to effectively cope with harsh competitive realities. Recently, some advanced corporations are trying to enhance CE by setting up an internal venture program as a seed organization for CE. By making an in-depth analysis of the internal venture program, 'C-Lab' of Samsung that is promoting CE-related characteristics for enhancing CE, we attempt to shed light on (1) what kinds of environments should be built around the seed organization for CE (2) what are the major characteristics that should be promoted through the seed organization in relation to CE (3) What kinds of achievements can be made from the promoted characteristics (4) How the characteristics are spread over the entire organization. Based on the analysis, we suggest a generalized process in which CE can be enhanced. Since different approaches should be taken for managing the seed organization and spreading the characteristics depending on the strengths and weaknesses of a corporation, there must be the step, 'evaluation of corporate internal capabilities' in the process. We believe that each corporation can enhance CE by taking advantage of the process with reference to the C-Lab case study.

Tuning of the ferromagnetic transition by impurity doping in Ru$Sr_2$EuCe$Cu_2$$O_z$ (불순물 치환을 통한 Ru$Sr_2$EuCe$Cu_2$$O_z$ 계의 강자성 천이온도의 조절특성)

  • Lee H. K;Kim Y. H;Kwon O. H
    • Progress in Superconductivity
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    • v.6 no.1
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    • pp.37-40
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    • 2004
  • We investigated the effects of impurity doping on the electrical transport and magnetic properties of TEX>$(Ru, Sn)(Sr, La)<_2$$EuCeCu_2$$O_{z}$ samples. We found that Sn substitution fur Ru causes a significant decrease of the volume fraction of ferromagnetic phase, as well as a decrease of the temperature where the ferromagnetic component is observed. La substitution for Sr leads to an increase of the magnetic ordering temperature with a moderate change of ferromagnetic component. The experimental results are discussed in conjunction with the structural data, transport properties and a possible change of oxygen content.

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Effects of Continuing Education for Healthcare Manager on Knowledge, Attitude, and Skills (건강관리사 계속교육이 사례관리자의 지식, 태도, 기술에 미치는 효과)

  • Yun, Soon Nyoung;Lim, Seung Joo;Park, Su Yeon
    • Korean Journal of Occupational Health Nursing
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    • v.21 no.3
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    • pp.184-191
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    • 2012
  • Purpose: This study was to examine the effects of 3 domains of continuing education (CE) for healthcare managers. Methods: A group of 20 healthcare managers, attending 3 levels of CE, were the subjects. The data were collected by structured questionnaires before and after each education. The data were analyzed by Friedman test, Wilcoxon Signed Ranked Test, and Bonferroni correction. Results: After completing CE, there was significant improvement on the scores of knowledge, attitude, and skills. Conclusion: This study suggests that CE for healthcare managers is an effective strategy to promote the competency of healthcare managers, who take care of the chronically ill patients.

Development of a Portable Device for Vibration Signal Analysis Based on Windows CE (Windows CE 기반 포터블 진동 신호분석기 개발)

  • 김동준;박광호;기창두
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 1997.10a
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    • pp.253-256
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    • 1997
  • In this study, we developed a portable device which monitors and analyzes a vibration signal happened to machines. This device is based on PDA which is smaller thant a palm of the hand, but it has powerful computing ability as much s a computer with 100MHz CPU and an operating system called Windows CE. As a preprocess for a diagnosis of a rotating machine, training artificial neural network based on PC is performed, and the device will diagnose the condition of a rotating machine using weight values as a result of the training ANN.

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Traffic Information and Path Guidance System is based on Windows CE Board using GPS and HSDPA (GPS와 HSDPA를 이용한 Windows CE 보드 기반의 교통량 수집 장치 및 경로 서비스에 관한 연구)

  • Kim, Tae-Min;Kim, Sun-Kyun;Lee, Jong-Su
    • Proceedings of the KIEE Conference
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    • 2007.04a
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    • pp.401-403
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    • 2007
  • This paper present the Traffic information system that based on embedded WinCE board which has GPSand HSDPA. This system is able to overcome the limit of area using the Internet service other system can't provide. When the embedded board receives the data which has geometric and vehicle speed information, it transmits the data to server via HSDPN/the Internet. The server receives and processes the data for the path services. By an algorithm the data that road information is applied is provided to user. The users will be able to arrive there destination faster.

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Partial Oxidation of Methane over CeO2 Catalyst

  • Rho, Hyun-Seog;Jun, Ki-Won;Baek, Seung-Chan;Park, Sang-Eon
    • Bulletin of the Korean Chemical Society
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    • v.23 no.6
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    • pp.799-803
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    • 2002
  • Partial oxidation of methane has been conducted over $CeO_2$and it has been found that $CeO_2$has an extraordinary catalytic activity in the reaction. Its activity was strongly dependent on the $CH_4/CO_2$ ratio. Total combustion was dominant with stoichiometric feed ratio$(CH_4/O_2=$ 2.0) but partial oxidation was achieved between the $CH_4/O_2$ ration of 3.8 4.3 and the period depended upon the feed composition. The proposed raaction mechanism it that oxygen vacancies in raduced deria are supplied with oxygen molecules from the reactant, and then activate adsorbed oxygen, followed by releasing activated axygen species reacting with methane to produce $H_2$ and CO.